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1,1,2-Trichloropropane
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Name

1,1,2-Trichloropropane

 EINECS N/A
CAS No. 598-77-6 Density 1.305g/cm3
PSA 0.00000 LogP 2.41740
Solubility N/A Melting Point -36.84°C (estimate)
Formula C3H5 Cl3 Boiling Point 125.3°Cat760mmHg
Molecular Weight 147.432 Flash Point 44.3°C
Transport Information N/A Appearance N/A
Safety Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC. Risk Codes R20/21/22; R36/37/38
Molecular Structure Molecular Structure of 598-77-6 (1,1,2-Trichloropropane) Hazard Symbols N/A
Synonyms

1,1,2-Trichloropropane

 

1,1,2-Trichloropropane Synthetic route

26198-63-0, 78-87-5

1,2-Dichloropropane

598-77-6

1,1,2-trichloropropane

Conditions
ConditionsYield
With aluminum (III) chloride; sulfuryl dichloride at 60℃; for 1h; Reagent/catalyst; Solvent; Inert atmosphere;33%
With chlorine im Sonnenlichte;
With antimonypentachloride
26198-63-0, 78-87-5

1,2-Dichloropropane

A

3175-23-3

1,2,2-trichloropropane

B

13116-60-4

1,1,2,2-tetrachloropropane

C

598-77-6

1,1,2-trichloropropane

D

96-18-4

1,2,3-trichloropropane

E

13116-53-5

1,2,2,3-tetrachloropropane

F

18495-30-2

1,1,2,3-tetrachloropropane

Conditions
ConditionsYield
With sulfuryl dichloride at 55 - 60℃;A 18%
B 13.2%
C 8.9%
D 20.3%
E 10.1%
F 15.6%
With sulfuryl dichloride; 2,2'-azobis(isobutyronitrile) at 55 - 60℃;A 19.7%
B 17.8%
C 6.5%
D 14.8%
E 11.8%
F 15.6%
With sulfuryl dichloride at 55 - 60℃; Product distribution / selectivity;
With chlorine; dimethyl 2,2'-azobis(isobutyrate) In tetrachloromethane at 70℃; under 8517.48 Torr; for 32h; Product distribution / selectivity; Inert atmosphere;
...Expand
187737-37-7

propene

598-77-6

1,1,2-trichloropropane

Conditions
ConditionsYield
With chlorine at 52 - 65℃; im Dunkeln;
26198-63-0, 78-87-5

1,2-Dichloropropane

A

598-77-6

1,1,2-trichloropropane

B

96-18-4

1,2,3-trichloropropane

Conditions
ConditionsYield
With Iodine monochloride at 160℃;
With iron(III) chloride; chlorine at 100℃; under 7224.57 Torr; for 5h; Product distribution / selectivity; Inert atmosphere;
With aluminum (III) chloride; sulfuryl dichloride; iodine at 55 - 60℃; Reagent/catalyst;
With aluminum (III) chloride; sulfuryl dichloride at 55 - 60℃; for 0.5h;
With aluminum (III) chloride; chlorine In tetrachloromethane at 60℃; for 1h; Inert atmosphere; Overall yield = 22 %;
540-54-5

1-Chloropropane

598-77-6

1,1,2-trichloropropane

Conditions
ConditionsYield
With chlorine
With antimonypentachloride
78-99-9

1,1-dichloropropane

598-77-6

1,1,2-trichloropropane

Conditions
ConditionsYield
With chlorine im Sonnenlichte;
With chlorine
With antimonypentachloride
26198-63-0, 78-87-5

1,2-Dichloropropane

7647-18-9

antimonypentachloride

598-77-6

1,1,2-trichloropropane

67-66-3

chloroform

78-99-9

1,1-dichloropropane

7647-18-9

antimonypentachloride

598-77-6

1,1,2-trichloropropane

26198-63-0, 78-87-5

1,2-Dichloropropane

7782-50-5

chlorine

iron

iron

598-77-6

1,1,2-trichloropropane

Conditions
ConditionsYield
bei Siedetemperatur; 1.2-dichloro-propane;
7446-70-0

aluminium trichloride

26198-63-0, 78-87-5

1,2-Dichloropropane

7782-50-5

chlorine

A

3175-23-3

1,2,2-trichloropropane

B

598-77-6

1,1,2-trichloropropane

1,1,2-Trichloropropane Chemical Properties

IUPAC Name: 1,1,2-Trichloropropane
Synonyms: 1,1,2-Trichloropropane ;propane, 1,1,2-trichloro-
CAS NO:598-77-6
Molecular Formula of 1,1,2-Trichloropropane(CAS NO.598-77-6):C3H5Cl3
Molecular Weight of 1,1,2-Trichloropropane(CAS NO.598-77-6):147.43
Molecular Structure of 1,1,2-Trichloropropane(CAS NO.598-77-6):
EINECS: 209-951-8
Index of Refraction:1.45
Surface Tension: 28.7 dyne/cm
Density: 1.305 g/cm3
Flash Point: 44.3 °C
Enthalpy of Vaporization: 34.82 kJ/mol
Boiling Point: 125.3 °C at 760 mmHg
Vapour Pressure: 14.8 mmHg at 25°C

1,1,2-Trichloropropane Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rabbit LD50 skin 14100uL/kg (14.1mL/kg)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.
rat LC50 inhalation 2000ppm/4H (2000ppm)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.
rat LD50 oral 1230mg/kg (1230mg/kg)   AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.

1,1,2-Trichloropropane Consensus Reports

Reported in EPA TSCA Inventory.

1,1,2-Trichloropropane Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation and skin contact. A skin and severe eye irritant. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Risk Statements 20/21/22-36/37/38
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
RTECS TZ8925000

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