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Cas Database

Name	2-(Aminomethyl)piperidine	EINECS	245-371-1
CAS No.	22990-77-8	Density	0.897 g/cm³
PSA	38.05000	LogP	1.11630
Solubility	N/A	Melting Point	N/A
Formula	C₆H₁₄N₂	Boiling Point	176.9 °C at 760 mmHg
Molecular Weight	114.191	Flash Point	66.7 °C
Transport Information	UN 2735	Appearance	Colorless clear liquid.
Safety	26-36/37/39-45	Risk Codes	34
Molecular Structure		Hazard Symbols	C
Synonyms	Piperidine,2-(aminomethyl)- (6CI,7CI,8CI);	Article Data	12

2-(Aminomethyl)piperidine Synthetic route

: 3731-51-9
(2-aminomethylpyridine)

: 22990-77-8
C-piperidin-2-yl-methylamine

Conditions

Conditions	Yield
With hydrogenchloride; hydrogen; platinum(IV) oxide In ethanol; water for 2.5h; Ambient temperature;	28.1%
With acetic acid; platinum Hydrogenation;
With hydrogen; Ra-Ni at 160 - 200℃; under 135014 - 150015 Torr; Product distribution / selectivity;
With hydrogen; Ni-Fe-6606 at 160℃; under 150015 Torr; Product distribution / selectivity;

(+-)-6-oxo-piperidine-2-carboxylic acid amide: (+-)-6-oxo-piperidine-2-carboxylic acid amide

: 22990-77-8
C-piperidin-2-yl-methylamine

Conditions

Conditions	Yield
With tetrahydrofuran; lithium aluminium tetrahydride

(+-)-<1-acetyl-<2>piperidyl>-acetone oxime: (+-)-<1-acetyl-<2>piperidyl>-acetone oxime

: 22990-77-8
C-piperidin-2-yl-methylamine

Conditions

Conditions	Yield
With hydrogenchloride; diethyl ether; phosphorus pentachloride

(+-)-N-<2>piperidylmethyl-acetamide: (+-)-N-<2>piperidylmethyl-acetamide

: 22990-77-8
C-piperidin-2-yl-methylamine

Conditions

Conditions	Yield
With hydrogenchloride

: 7647-01-0
hydrogenchloride

: (1-acetyl-[2]piperidyl)-acetone oxime

: 60-29-7
diethyl ether

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 7732-18-5
water

: 22990-77-8
C-piperidin-2-yl-methylamine

...Expand

: 100-70-9
2-Cyanopyridine

: 22990-77-8
C-piperidin-2-yl-methylamine

Conditions

Conditions	Yield
With ammonia; hydrogen; Ni-5584 In ethanol at 180℃; under 135014 Torr; for 6h; Product distribution / selectivity;

2-(Aminomethyl)piperidine Chemical Properties

Molecular Formula: C₆H₁₄N₂

Formula Weight: 114.19
bp of 2-PIPERIDYLMETHYLAMINE (22990-77-8): 63-66^°C/12mm
Density: 0.897 g/cm³
refractive index : 1.4850
Fp of 2-PIPERIDYLMETHYLAMINE (22990-77-8): 63-66^°C/12mm
Vapour Pressure: 1.07 mmHg at 25^°C
Specific Gravity(20/4^°C): 0.941
Solubility: ≥100g/100g Water at 25^°C
Appearance of 2-PIPERIDYLMETHYLAMINE (22990-77-8): Colorless clear liquid.

2-(Aminomethyl)piperidine Toxicity Data With Reference

LD₅₀ Oral Mouse (mg/kg): 1440

2-(Aminomethyl)piperidine Safety Profile

Safety: DANGER: CORROSIVE, burns skin and eyes
Hazard Codes : C (Corrosive)
Risk Statements : 34 (Causes burns)
Safety Statements : 26-36/37/39-45 (In case of contact with eyes, rinse immediately with plenty of water and seek medical advice; Wear suitable protective clothing, gloves and eye/face protection; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible))
RIDADR : 2735
HazardClass : 8
PackingGroup : III

2-(Aminomethyl)piperidine Standards and Recommendations

Purity of 2-PIPERIDYLMETHYLAMINE (22990-77-8) (GC%): 99.0 min.
Moisture (%): 0.1 max.

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