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2,3-Dimethylbromobenzene

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Name

2,3-Dimethylbromobenzene

EINECS 209-398-2
CAS No. 576-23-8 Density 1.339 g/cm3
PSA 0.00000 LogP 3.06590
Solubility Not miscible or difficult to mix in water. Melting Point -20.49°C (estimate)
Formula C8H9Br Boiling Point 211 °C at 760 mmHg
Molecular Weight 185.063 Flash Point 84 °C
Transport Information N/A Appearance Clear colourless to light yellow liquid
Safety 26-36/37/39-24/25 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 576-23-8 (2,3-Dimethylbromobenzene) Hazard Symbols IrritantXi
Synonyms

o-Xylene,3-bromo- (6CI,7CI,8CI);1-Bromo-2,3-dimethylbenzene;

Article Data 29

2,3-Dimethylbromobenzene Synthetic route

95-47-6

o-xylene

A

583-71-1

4-bromo-o-xylene

B

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With bromine; acetic acidA 82%
B 18%
With bromine; iodine In dichloromethane at -10 - 20℃; for 7.58333h;A 75%
B 15%
With hydrogenchloride; sodium hypochlorite; sodium bromide In water at 29.85℃; for 8h; Product distribution; Further Variations:; Temperatures;A 24.6%
B 68.5%
87-59-2

2,3-Dimethylaniline

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With nitrogen(II) oxide; copper(ll) bromide In acetonitrile at -78 - 25℃;73%
With hydrogen bromide diazotization;40%
With hydrogen bromide Diazotization.Erwaermen der Diazoniumsalz-Loesung mit Kupfer-Pulver;
526-75-0

2,3-Dimethylphenol

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With bromine; triphenylphosphine In acetonitrile60%
With bromine; triphenylphosphine In acetonitrile at 25℃; for 48h;41.1%
593-53-3

Methyl fluoride

95-46-5

2-methylphenyl bromide

A

576-22-7

2-Bromo-m-xylene

B

553-94-6

4-bromo-m-xylene

C

583-70-0

1-bromo-2,4-dimethylbenzene

D

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With oxygen at 40℃; under 720 Torr; Mechanism; Irradiation;A n/a
B n/a
C 13.7%
D 32.8%
22364-25-6

4-bromo-2,3-dimethylaniline

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With hydrogen bromide; sodium nitrite anschliessend Behandeln mit Natriumhypophosphit und wss. Bromwasserstoffsaeure;
75366-04-0

2-methyl-1H-cyclopropabenzene

A

576-22-7

2-Bromo-m-xylene

B

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With bromine; tri-n-butyl-tin hydride Product distribution; Mechanism; multistep reaction; reaction regioselectivity; a series of reagents;
92-52-4

biphenyl

61024-97-3

3-bromo-5-tert-butyl-o-xylene

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With aluminium trichloride In tetrachloromethane; nitromethane
95-47-6

o-xylene

A

583-71-1

4-bromo-o-xylene

B

576-23-8

2,3-dimethylbromobenzene

C

89-92-9

2-methylbenzyl bromide

D

91-13-4

α,α'-dibromo-o-xylene

Conditions
ConditionsYield
With bromine In water for 0.333333h; Ambient temperature; Irradiation;A 3 % Chromat.
B 2 % Chromat.
C 16 % Chromat.
D 79 % Chromat.
3-bromo-1.2-dimethyl-benzene-sulfonic acid-(4)

3-bromo-1.2-dimethyl-benzene-sulfonic acid-(4)

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With steam; sulfuric acid
6-bromo-1.2-dimethyl-benzene-sulfonic acid-(4)

6-bromo-1.2-dimethyl-benzene-sulfonic acid-(4)

576-23-8

2,3-dimethylbromobenzene

Conditions
ConditionsYield
With steam; sulfuric acid

2,3-Dimethylbromobenzene Chemical Properties

IUPAC Name: 1-Bromo-2,3-dimethylbenzene
Synonyms of 2,3-Dimethylbromobenzene (CAS NO.576-23-8): 3-Bromo-1,2-dimethylbenzene ; 3-Bromo-o-xylene  
CAS NO: 576-23-8
The Molecular Formula: C8H9Br
The Molecular Weight: 185.06
Molecular Structure :
EINECS: 209-398-2 
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: Å2
Index of Refraction: 1.543
Molar Refractivity: 43.59 cm3
Molar Volume: 138.1 cm3
Surface Tension: 33.7 dyne/cm
Density: 1.339 g/cm3
Flash Point: 84 °C
Enthalpy of Vaporization: 42.91 kJ/mol
Boiling Point: 211 °C at 760 mmHg
Vapour Pressure: 0.27 mmHg at 25°C
Appearance: Clear colourless to light yellow liquid
Product Categories of 2,3-Dimethylbromobenzene (CAS NO.576-23-8): Aromatic Hydrocarbons (substituted) & Derivatives;Halogen toluene;Benzene derivates;Bromine Compounds
SMILES: Cc1cccc(Br)c1C
InChI: InChI=1/C8H9Br/c1-6-4-3-5-8(9)7(6)2/h3-5H,1-2H3
InChIKey: WLPXNBYWDDYJTN-UHFFFAOYAR
Std. InChI: InChI=1S/C8H9Br/c1-6-4-3-5-8(9)7(6)2/h3-5H,1-2H3
Std. InChIKey: WLPXNBYWDDYJTN-UHFFFAOYSA-N

2,3-Dimethylbromobenzene Safety Profile

Safety Information about 2,3-Dimethylbromobenzene (CAS NO.576-23-8):
Hazard Codes: IrritantXi
Risk Statements: 36/37/38 
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39-24/25
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S24/25: Avoid contact with skin and eyes. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
RIDADR: UN 2810 6.1/PG 3
WGK Germany: 3
Hazard Note: Irritant

2,3-Dimethylbromobenzene Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Combustible liquid.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Keep 2,3-Dimethylbromobenzene (CAS NO.576-23-8) away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container.

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