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2-Iodopropane

  • Name 2-Iodopropane
  • EINECS200-859-3
  • CAS No. 75-30-9
  • Density1.747 g/cm3
  • PSA0.00000
  • LogP1.82980
  • SolubilityN/A
  • Melting Point-90 °C
  • FormulaC3H7I
  • Boiling Point91.3 °C at 760 mmHg
  • Molecular Weight169.993
  • Flash Point42.2 °C
  • Transport InformationUN 2392 3/PG 3
  • AppearanceColorless liquid
  • Safety36/37
  • Risk Codes10-22
  • Molecular Structure
    Molecular Structure of 75-30-9 (Isopropyl iodide)
  • Hazard SymbolsHarmfulXn
  • SynonymsHarmfulXn
  • Article Data106

2-Iodopropane Synthetic route

67-63-0

isopropyl alcohol

75-30-9

2-iodo-propane

Conditions
ConditionsYield
With iodoform; sodium iodide In N,N-dimethyl-formamide for 3h; Catalytic behavior; Irradiation;91%
With acetyl iodide at 80 - 90℃; for 1.5h;24%
With iodine; aluminium
26591-86-6

(i-C3H7)3SbI2

A

75-30-9

2-iodo-propane

B

73300-45-5

tri(isopropyl)antimony

C

81492-14-0

diisopropylantimony iodide

Conditions
ConditionsYield
under Ar, decomposed at 135°C for 30 min; distd., not separated from triisopropyl stibine; elem. anal.;A 89%
B n/a
C n/a
420-26-8

2-propylfluoride

75-30-9

2-iodo-propane

Conditions
ConditionsYield
With 2-fluoro-2-(piperidin-1-yl)-4-(2,3,5,6-tetrafluoropyridin-4-yl)-5-(2,4,6-triisopropylphenyl)-1,3-dithiole In 1,4-dioxane at 45℃; for 14h; Schlenk technique; Inert atmosphere;74%
78-83-1

2-methyl-propan-1-ol

A

75-30-9

2-iodo-propane

B

78-84-2

isobutyraldehyde

Conditions
ConditionsYield
With N-iodo-succinimide In chlorobenzene for 3h; Irradiation;A 51%
B 18%
74-98-6

propane

75-30-9

2-iodo-propane

Conditions
ConditionsYield
With CCl4*2AlI3 In dichloromethane at -20℃; for 1.5h;50%
137116-57-5

5'-O-(4,4'-dimethoxytrityl)-2-N-<2-<(tert-butyldiphenylsilyloxy)methyl>benzoyl>guanosine

18162-48-6

tert-butyldimethylsilyl chloride

A

75-30-9

2-iodo-propane

B

137116-54-2

5'-O-(4,4'-dimethoxytrityl)-3'-O-(tert-butyldimethylsilyl)-2-N-<2-<(tert-butyldiphenylsilyloxy)methyl>benzoyl>guanosine

Conditions
ConditionsYield
With pyridine; silver nitrate In tetrahydrofuranA 42%
B 16%
57-55-6

propylene glycol

75-30-9

2-iodo-propane

Conditions
ConditionsYield
With water; hydrogen iodide
75-30-9

2-iodo-propane

Conditions
ConditionsYield
With hydrogen iodide
With ascaridole; hydrogen iodide
With hydrogen iodide; diphenylamine
With hydrogen iodide

A

75-30-9

2-iodo-propane

B

107-08-4

1-iodo-propane

Conditions
ConditionsYield
With hydrogen iodide; diphenylamine
556-56-9

allyl iodid

75-30-9

2-iodo-propane

Conditions
ConditionsYield
With hydrogen iodide

2-Iodopropane Chemical Properties

The Molecular formula of  ISOPROPYL IODIDE(75-30-9): C3H7I
The Molecular Weight of  ISOPROPYL IODIDE(75-30-9): 169.99
The Molecular Structure of  ISOPROPYL IODIDE(75-30-9):
EINECS: 200-859-3
Melting point: -90 °C
Boiling Point: 91.3 °C at 760 mmHg 
Flash Point: 42.2 °C 
Index of Refraction: 1.505 
Molar Refractivity: 28.87 cm
Molar Volume: 97.2 cm
Polarizability: 11.44 10-24 cm
Surface Tension: 27.5 dyne/cm 
Density: 1.747 g/cm
Enthalpy of Vaporization: 30.68 kJ/mol 
Vapour Pressure: 61.4 mmHg at 25°C 
storage temp.: Store at RT.
Sensitive: Light Sensitive
Stability: Stable, but may discolour on exposure to light. Air sensitive. Incompatible with strong bases, strong oxidizing agents.
Appearance: Colorless liquid
Merck: 14,5214
BRN: 1098244
IUPAC Name: 2-iodopropane
Synonyms: 2-iodo-propan;2-Propyljodid;Isopropyl iodine;Isopropyliodid;i-Propyl iodide;iso-C3H7I;2-Jodpropan;2-propyliodide;

2-Iodopropane Uses

ISOPROPYL IODIDE(75-30-9) is used as a solvent, also used in medicine and organic synthesis.

2-Iodopropane Toxicity Data With Reference

The Toxicity Information of  ISOPROPYL IODIDE(75-30-9):
1.   

ihl-rat LC50:320,000 mg/m3/30M

   FAVUAI    Fiziologicheski Aktivnye Veshchestva. Physiologically Active Substances. 7 (1975),35.
2.   

ipr-mus LD50:1300 mg/kg

   34ZIAG    Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY.: Academic Press, Inc.,1969,756.

2-Iodopropane Consensus Reports

Reported in EPA TSCA Inventory.

2-Iodopropane Safety Profile

Moderately toxic by intraperitoneal route. Mildly toxic by inhalation. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of I. See also IODIDES.
The Hazard Codes of ISOPROPYL IODIDE(75-30-9):  Xn
HazardClass: 3
The Risk Statements information of ISOPROPYL IODIDE(75-30-9):
10:  Flammable 
22:  Harmful if swallowed 
The Safety Statements information of ISOPROPYL IODIDE(75-30-9):
36/37:  Wear suitable protective clothing and gloves 
RIDADR: UN 2392 3/PG 3
WGK Germany: 3
RTECS: TZ4200000
F: 8
PackingGroup: III
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