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Cas Database

Name	4-Fluoro-3-phenoxybenzaldehyde	EINECS	269-856-2
CAS No.	68359-57-9	Density	1.229 g/cm³
PSA	26.30000	LogP	3.43050
Solubility	N/A	Melting Point	N/A
Formula	C₁₃H₉FO₂	Boiling Point	320 °C at 760 mmHg
Molecular Weight	216.212	Flash Point	142.5 °C
Transport Information	UN 3082 9/PG 3	Appearance	Light yellowish liquid.
Safety	61	Risk Codes	22-51/53
Molecular Structure		Hazard Symbols	Xn; N
Synonyms	3-Phenoxy-4-fluorobenzaldehyde;4-Fluoro-3-phenoxybenzaldehyde;	Article Data	6

4-Fluoro-3-phenoxybenzaldehyde Synthetic route

: 68359-37-5
cyfluthrin

A: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

B: 55701-05-8
3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid

Conditions

Conditions	Yield
With sodium hydroxide In methanol for 2h; Heating;

: 68359-55-7
4-fluoro-3-phenoxybenzyl bromide

: 108-03-2
1-Nitropropane

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

Conditions

Conditions	Yield
In ethanol

: 77771-05-2
4-fluoro-3-phenoxy-benzaldehyde ethyleneacetal

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

Conditions

Conditions	Yield
With hydrogenchloride In ethanol; water; toluene

: cis-α-cyano-3-phenoxy-4-fluoro-benzyl 2,2-dimethyl-3-(2-chloro-vinyl)cyclopropanecarboxylate

A: 541-47-9
3-Methylbutenoic acid

B: 60310-82-9
3-(2-chloro-vinyl)-2,2-dimethylcyclopropanecarboxylic acid

C: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

D: C8H11ClO

E: 76783-44-3
2-(4-fluoro-3-phenoxyphenyl)-2-hydroxyethanenitrile

F: 77279-89-1
4-fluoro-3-phenoxy benzoic acid

Conditions

Conditions	Yield
In hexane for 17h; UV-irradiation;

...Expand

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

: 77279-89-1
4-fluoro-3-phenoxy benzoic acid

Conditions

Conditions	Yield
With dihydrogen peroxide; acetic acid In ethanol for 4h; Heating;	100%
With potassium permanganate In water for 2h; Heating;	65%
With dihydrogen peroxide; acetic acid at 60 - 80℃; for 2h;

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

: 68359-53-5
4-fluoro-3-phenoxyphenylmethanol

Conditions

Conditions	Yield
With formic acid; C20H29ClIrN4(1+)*Cl(1-) In ethanol; water at 80℃; for 0.25h; chemoselective reaction;	98%
With sodium hydroxide In diethyl ether; water
With sodium hydroxide In diethyl ether; water
With sodium hydroxide In diethyl ether; water

: potassium cyanide

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

: C9H9Br2Cl2F3O

: C23H18Br2ClF4NO2

Conditions

Conditions	Yield
With tetrabutylammomium bromide In water; benzene at 15 - 20℃; for 10h;	95%

: 773837-37-9
sodium cyanide

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

: cis-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

: cis-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

Conditions

Conditions	Yield
With triethylamine In water; toluene at 20℃; for 4h;	95%

: potassium cyanide

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

: (1R)-trans-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylic acid chloride

: (1R)-trans-α-cyano-4-fluoro-3-phenoxybenzyl-2,2-dimethyl-3-(2-chloropropenyl)cyclopropanecarboxylate

Conditions

Conditions	Yield
With pyridine In cyclohexane; water at 20℃; for 4h;	93%

: 17176-77-1
Dibenzyl phosphite

: 68359-57-9
4-fluoro-3-phenoxybenzaldehyde

: dibenzyl α-hydroxy(4-fluoro-3-phenoxy)benzylphosphonate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 14h;	92%

4-Fluoro-3-phenoxybenzaldehyde Chemical Properties

IUPAC Name: 4-Fluoro-3-phenoxybenzaldehyde
Following is the structure of Benzaldehyde,4-fluoro-3-phenoxy- (CAS NO.68359-57-9):

Empirical Formula: C₁₃H₉FO₂
Molecular Weight: 216.2078
EINECS: 269-856-2
Index of Refraction: 1.591
Molar Refractivity: 59.44 cm³
Molar Volume: 175.8 cm³
Polarizability: 23.56 10^-24cm³
Surface Tension: 43 dyne/cm
Density: 1.229 g/cm³
Flash Point: 142.5 °C
Enthalpy of Vaporization: 56.16 kJ/mol
Boiling Point: 320 °C at 760 mmHg
Vapour Pressure: 0.000327 mmHg at 25 °C
Product Categories: Aromatic Aldehydes & Derivatives (substituted);Aldehydes;C10 to C21;Carbonyl Compounds
Canonical SMILES: C1=CC=C(C=C1)OC2=C(C=CC(=C2)C=O)F
InChI: InChI=1S/C13H9FO2/c14-12-7-6-10(9-15)8-13(12)16-11-4-2-1-3-5-11/h1-9H
InChIKey: JDICMOLUAHZVDS-UHFFFAOYSA-N

4-Fluoro-3-phenoxybenzaldehyde Safety Profile

Hazard Codes: Harmful Xn, Dangerous N
Risk Statements: 22-51/53
R22:Harmful if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 61
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR UN: 3082 9/PG 3
WGK Germany: 2
Hazard Note: Harmful

4-Fluoro-3-phenoxybenzaldehyde Specification

Benzaldehyde,4-fluoro-3-phenoxy- , its cas register number 68359-57-9. It also can be called 3-(Phenoxy)-4-fluoro-benzaldehyde ; and 4-Fluoro-3-phenoxybenzaldehyde .

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