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Cas Database

Name	Benzyl Methacrylate	EINECS	219-674-4
CAS No.	2495-37-6	Density	1.036 g/cm³
PSA	26.30000	LogP	2.30590
Solubility	Insoluble in water.	Melting Point	<25 °C
Formula	C₁₁H₁₂O₂	Boiling Point	247.033 °C at 760 mmHg
Molecular Weight	176.215	Flash Point	124.13 °C
Transport Information	N/A	Appearance	colourless liquid
Safety	26	Risk Codes	36/37/38
Molecular Structure		Hazard Symbols	Xi
Synonyms	Methacrylicacid, benzyl ester (6CI,7CI,8CI);Acryester BZ;Benzyl 2-methyl-2-propenoate;Benzyl 2-methylacrylate;Benzyl methacrylate;BzMA;Fancryl FA-BZM;Light EsterBZ;NSC 20970;Phenylmethyl 2-methyl-2-propenoate;	Article Data	41

Benzyl Methacrylate Synthetic route

: 79-41-4
poly(methacrylic acid)

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
tetrachlorobis(tetrahydrofuran)hafnium(IV) In benzene for 40h; Heating;	99%
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 4h;	90%
toluene-4-sulfonic acid In benzene for 15h; Heating;	85%

: 80-62-6
methacrylic acid methyl ester

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With C2H3O3(1-)*C37H78N(1+) In hexane at 90℃; for 2h; Reagent/catalyst; Molecular sieve;	97%
With lanthanum (III) nitrate * water; 1,1,1-trioctyl-1-methylphosphonium methylcarbonate In hexane for 10h; Molecular sieve; Reflux;	80%

: 920-46-7
Methacryloyl chloride

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With triethylamine at 0℃; Inert atmosphere; Microwave irradiation;	96%
With triethylamine In dichloromethane at 0℃;	62%
With triethylamine In dichloromethane at 0℃; Inert atmosphere;	50%

: 81171-49-5
(1-Benzyloxy-2-chloro-2-methyl-cyclopropoxy)-trimethyl-silane

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With triethylamine In methanol for 6h; Heating;	91%
With triethylamine In methanol for 12h; Heating; Yield given;

: 1426060-15-2
benzyl 3-(dimethylamino)-2-methylpropanoate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine; triethylamine In isopropyl alcohol at 20℃; for 0.25h; Eschenmoser Methylenation;	90%

: 65-85-0
benzoic acid

: 75107-16-3
2-bromoisobutyric acid,benzyl ester

A: C18H18O4

B: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With silver(l) oxide In water; acetonitrile at 100℃; for 24h;	A 89% B n/a

: 100-44-7
benzyl chloride

: 920-46-7
Methacryloyl chloride

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With dmap; caesium carbonate at 50℃; for 24h; Concentration;	89%

: 4245-37-8
vinyl methacrylate

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With TBA7[γ-HGeW10O36] In acetonitrile at 39.84℃; for 0.0166667h;	83%

: 63613-50-3
benzyl 2-(tripheny l-λ5phosphanylidene)propanoate

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
With carbon dioxide; potassium tert-butylate In N,N-dimethyl-formamide at 100℃; under 760.051 Torr; for 12h;	83%

: 463-49-0
1,2-propanediene

: 201230-82-2
carbon monoxide

: 100-51-6
benzyl alcohol

: 2495-37-6
benzyl methacrylate

Conditions

Conditions	Yield
dodecacarbonyl-triangulo-triruthenium at 80℃; under 22800 Torr; for 5h;	73%

Benzyl Methacrylate Chemical Properties

Molecular Formula: C₁₁H₁₂O₂
Formula Weight: 176.21
bp: 95-98 ^°C 4 mm Hg(lit.)
density: 1.04 g/mL at 25 ^°C(lit.)
refractive index: n20/D 1.512(lit.)
Fp: 225^°F
Sensitive: Light Sensitive
PHYSICAL STATE: clear liquid
SOLUBILITY IN WATER: Insoluble
STABILITY Of Benzyl Methacrylate: Polymerization will occur under light and HEAT

Benzyl Methacrylate Uses

Benzyl Methacrylate can be used as funtional monomer for polymers, coatings, Adhesives. Textile treatment agent, LUBRICATING OIL .

Benzyl Methacrylate Toxicity Data With Reference

Oral rat LD₅₀: 3600 mg/kg

Benzyl Methacrylate Safety Profile

Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 26
WGK Germany : 1

Benzyl Methacrylate Standards and Recommendations

PURITY (G.C): 98.0% min
COLOR, APHA: 30 max
SPECIFIC GRAVITY: 1.035 - 1.045
WATER: 0.1% max
FREE ACID:0.05% max (Methacrlic acid)
INHIBITOR: 200ppm max (Monomethyl Ether Hydroquinone)

Benzyl Methacrylate Specification

PACKING OF Benzyl Methacrylate: 200kgs in drum

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