10061-01-5 Usage
Uses
Used in Agricultural Industry:
CIS-1,3-DICHLOROPROPENE is used as a soil fumigant for controlling pests and diseases in the soil, as well as a nematocide to eliminate nematodes (roundworms) that can damage crops. Its application helps improve the health and productivity of agricultural lands.
Used in Chemical Industry:
CIS-1,3-DICHLOROPROPENE is used as an intermediate in the synthesis of various chemicals, taking advantage of its reactive nature and versatility in chemical reactions. This contributes to the production of a wide range of products in the chemical industry.
Air & Water Reactions
Highly flammable. Insoluble in water.
Reactivity Profile
CIS-1,3-DICHLOROPROPENE may be sensitive to light. Reacts with aluminum, aluminum alloys, other active metals and some metal salts and halogens. Can react vigorously with oxidizing materials.
Fire Hazard
Flash point data for CIS-1,3-DICHLOROPROPENE are not available, however literature sources indicate that CIS-1,3-DICHLOROPROPENE is flammable.
Safety Profile
Confirmed carcinogen
with experimental neoplastigenic data.
Human mutation data reported. A
dangerous fire hazard when exposed to heat,
flame, or oxidzers. When heated to
decomposition it emits toxic fumes of Cl-.
See also CHLORINATED
HYDROCARBONS , ALIPHATIC .
Potential Exposure
Used as a soil fumigant prior to
planting crops, such as cotton, sugar beet, potatoes; used in
combinations with dichloropropanes as a soil fumigant.
Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.
Environmental Fate
Biological. cis-1,3-Dichloropropylene was reported to hydrolyze to 3-chloro-2-propen-
1-ol and can be biologically oxidized to 3-chloropropenoic acid, which is further oxidized
to formylacetic acid. Decarboxylation of this compound yields carbon dioxide (Connors
et al., 1990). The isomeric mixture showed significant degradation with gradual adaptation
in a static-culture flask-screening test (settled domestic wastewater inoculum) conducted
at 25°C. At concentrations of 5 and 10 mg/L, percent losses after 4 weeks of incubation were 85 and 84, respectively. Ten days into the incubation study, 7–19% was lost due to
volatilization (Tabak et al., 1981).
Soil. Hydrolyzes in wet soil forming cis-3-chloroallyl alcohol (Castro and Belser,
1966).
Chemical/Physical. Hydrolyzes in distilled water at 25°C forming 2-chloro-3-propenol
and hydrochloric acid. The half-life was 1 day (Milano et al., 1988; Kollig, 1993).
Chloroacetaldehyde, formyl chloride and chloroacetic acid were formed from the ozonation
of dichloropropylene at about 23°C and 730 mmHg. Chloroacetaldehyde and formyl
chloride also formed from the reaction of dichloropropylene with hydroxyl radicals (Tuazon
et al., 1984).
The evaporation half-life of cis-1,3-dichloropropylene (1 mg/L) from water at 25°C
using a shallow-pitch propeller stirrer at 200 rpm at an average depth of 6.5 cm is 29.6
minutes (Dilling, 1977).
Emits chlorinated acids when incinerated. Incomplete combustion may release toxic
phosgene (Sittig, 1985).
Solubility in organics
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance,
1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene,
and trichloroethylene.
Solubility in water
Miscible with acetone, benzene, carbon tetrachloride, heptane, methanol (Worthing and Hance,
1991), methylene chloride, chloroform, 1,1,2,2-tetrachloroethane, 1,1,1,2-tetrachloroethane, tetrachloroethylene,
and trichloroethylene.
Shipping
UN2047 Dichloropropene, Hazard Class: 3;
Labels: 3-Flammable liquid.
Incompatibilities
Vapor may form explosive mixture
with air. Incompatible with oxidizers (chlorates, nitrates,
peroxides, permanganates, perchlorates, chlorine, bromine,
fluorine, etc.); contact may cause fires or explosions. Keep
away from alkaline materials, strong bases, strong acids,
oxoacids, and epoxides. May accumulate static electrical
charges, and may cause ignition of its vapors. Incompatible
with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials;
halogens, or corrosives. Note: Epichlorohydrin may be
added as a stabilizer.
Waste Disposal
Incineration, preferably
after mixing with another combustible fuel. Care must be
exercised to assure complete combustion to prevent the
formation of phosgene. An acid scrubber is necessary to
remove the halo acids produced. In accordance with
40CFR165, follow recommendations for the disposal of
pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting
your local or federal environmental control agency, or by
contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on
acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with
EPA regulations governing storage, transportation, treatment, and waste disposal.
Check Digit Verification of cas no
The CAS Registry Mumber 10061-01-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,6 and 1 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 10061-01:
(7*1)+(6*0)+(5*0)+(4*6)+(3*1)+(2*0)+(1*1)=35
35 % 10 = 5
So 10061-01-5 is a valid CAS Registry Number.
InChI:InChI=1/C3H4Cl2/c4-2-1-3-5/h1-2H,3H2/b2-1-
10061-01-5Relevant articles and documents
MANUFACTURE OF DICHLOROPROPANOL
-
Page/Page column 19-21, (2009/03/07)
Manufacture of dichloropropanol Process for manufacturing dichloropropa nol wherein a glycerol-based product comprising at least one diol containi ng at least 3 carbon atoms other than 1,2- propanediol, is reacted with a chlorinati ng agent, and of products derived from dichloropropanol such as ep ichlorohydrin and epoxy resins. No figure.
The Copyrolysis of 1,2,3-Trichloropropane and Methanol on Activated Alumina
Shinoda, Kiyonori,Yasuda, Kensei
, p. 633 - 634 (2007/10/02)
The copyrolysis of 1,2,3-trichloropropane and methanol gave 1,2-dichloro-3-methoxypropane as well as dichloropropenes and their derivatives.The formation of 1,2-dichloro-3-methoxypropane is also described.
