(Z)-1,3-Dichloropropene

Base Information

• Chemical Name: (Z)-1,3-Dichloropropene
• CAS No.: 10061-01-5
• Molecular Formula: C3H4Cl2
• Molecular Weight: 110.971
• European Community (EC) Number: 233-195-8
• UNII: 411B9UAH6H
• UN Number: 2047
• DSSTox Substance ID: DTXSID1032305
• Metabolomics Workbench ID: 53652
• Nikkaji Number: J4.433D
• NSC Number: 6202
• Wikidata: Q27109091
• Mol file: 10061-01-5.mol

Synonyms:(Z)-1,3-Dichloro-1-propene;(Z)-1,3-Dichloropropene;10061-01-5;cis-1,3-Dichloro-1-propene;cis-1,3-Dichloropropene;cis-1,3-Dichloropropylene;cis-DCP;1-Propene, 1,3-dichloro-, (Z)-;1-Propene, 1,3-dichloro-, (1Z)-;(1Z)-1,3-dichloroprop-1-ene;(Z)-Dichloropropene;1,3-Dichloropropene, cis-;Propene, 1,3-dichloro-, (Z)-;CCRIS 227;(Z)-1,3-dichloroprop-1-ene;HSDB 1503;(1Z)-1,3-Dichloro-1-propene;EINECS 233-195-8;UNII-411B9UAH6H;BRN 1719557;cis-3-Chloroallyl Chloride;411B9UAH6H;DTXSID1032305;CHEBI:18809;EC 233-195-8;4-01-00-00743 (Beilstein Handbook Reference);.gamma.-Chloroallyl chloride;(1Z)-1,3-Dichloropropene;.alpha.,.gamma.-Dichloropropylene;CIS-TELONE;z-1,3-dichloropropene;cis-1,3-dichloro-propene;bmse000718;WLN: G2U1G;.alpha.-Chloroallyl chloride;SCHEMBL115639;1,3-Dichloro-1-propene (Z);DTXCID9012305;cis-1,3-Dichloropropene, 97%;NSC6202;?CIS-1,3-DICHLOROPROPENE;cis-1,3-Dichloropropene Standard;NSC-6202;Tox21_303973;(1Z)-1,3-Dichloro-1-propene #;MFCD00062949;(Z)-1,3-bis(chloranyl)prop-1-ene;1,3-DICHLOROPROPENE, (Z)-;1,3-DICHLOROPROPENE, (1Z)-;PROPENE,1,3-DICHLORO-,(Z)-;NCGC00357276-01;BS-43838;CAS-10061-01-5;1,3-DICHLOROPROPENE (Z)-FORM [MI];BOC-D-PHENYLALANINE4-NITROPHENYLESTER;cis-1,3-Dichloropropene, analytical standard;D2792;NS00082534;S0637;C06610;D78377;1-PROPENE,1,3-DICHLORO-,(Z)-(9 CI);A800242;W-108952;Q27109091;cis-1,3-Dichloropropene, vial of 1 g, analytical standard

Chemical Property of (Z)-1,3-Dichloropropene

Chemical Property:

• Appearance/Colour: colourless to amber liquid
• Vapor Pressure: 30.4mmHg at 25°C
• Melting Point: -50 °C
• Refractive Index: 1.456
• Boiling Point: 108.389 °C at 760 mmHg
• Flash Point: 27.778 °C
• PSA: 0.00000
• Density: 1.175 g/cm³
• LogP: 1.97770
• Storage Temp.: 0-6°C
• Solubility.: Chloroform (Soluble), Methanol (Slightly)
• Water Solubility.: 1.071g/L(30 oC)
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 109.9690055
• Heavy Atom Count: 5
• Complexity: 31.9
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99.9% ^*data from raw suppliers

CIS-1,3-DICHLORO-1-PROPENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T, N, F
• Hazard Codes: T,N,F
• Statements: 10-20/21-25-36/37/38-43-50/53-52/53-39/23/24/25-23/24/25-11-65-24/25-20
• Safety Statements: 36/37-45-60-61-16-7

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Fumigants
• Canonical SMILES: C(C=CCl)Cl
• Isomeric SMILES: C(/C=C\Cl)Cl
• Physical properties: Clear, colorless to amber-colored liquid with a pungent and irritating, chloroform-like odor. Evaporates quickly when spilled. The average least detectable odor threshold concentration in water at 60 °C for mixed isomers of 1,3-dichloropropylene was 0.12 mg/L (Alexander et al., 1982).
• Uses: The isomeric mixture is used as a soil fumigant and a nematocide.

Technology Process of (Z)-1,3-Dichloropropene

There total 8 articles about (Z)-1,3-Dichloropropene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,3-Dichloropropane (142-28-9) + 1-chloro-3-hydroxypropane (627-30-5) → glycidyl methyl ether (930-37-0) + 1,2-Epoxyhexane (1436-34-6) + 2,3-Dichloroprop-1-ene (78-88-6) + 2-chloroallyl alcohol (5976-47-6) + 1,2,2-trichloropropane (3175-23-3) + 1,2-Dichloropropane (26198-63-0,78-87-5) + cis-1,3-Dichloropropene (10061-01-5) + 1,2,3-trichloro-1-propene (13116-58-0) + (1Z)-1,2,3-trichloroprop-1-ene (96-19-5,13116-58-0,13116-57-9) + 1,3,3-trichloro-propene (2953-50-6) + 1t,3,3-trichloro-propene (2598-01-8) + chlorodibromomethane (124-48-1) + 1,1,2-trichloropropane (598-77-6) + 2,3-Dichloro-1-propanol (616-23-9) + 1,3-Dichloro-2-propanol (96-23-1) + 1,2,3-trichloropropane (96-18-4) + 3,3-dichloropropene (563-57-5) + 3,3-dichloroallyl chloride (2567-14-8) + acetaldehyde (75-07-0,9002-91-9) + allyl alcohol (107-18-6) + hydroxy-2-propanone (116-09-6) + chloroacetone (78-95-5) + cyclopentanone (120-92-3) + chlorobenzene (108-90-7) + isopropyl alcohol (67-63-0,8013-70-5) + 3-monochloro-1,2-propanediol (96-24-2) + acrolein (107-02-8,25068-14-8) + epichlorohydrin (106-89-8,24969-06-0,13403-37-7) + (E)-1,3-dichloro-prop-1-ene (10061-02-6)

Guidance literature:

With sodium hydroxide; water; at 45 - 62.4 ℃; under 112.511 - 750.075 Torr; Product distribution / selectivity;

Reference yield:

methanol (67-56-1) + 1,2,3-trichloropropane (96-18-4) → 2,3-Dichloroprop-1-ene (78-88-6) + 1,2-Dichlor-3-methoxy-propane (34680-34-7) + cis-1,3-Dichloropropene (10061-01-5) + 2-chloro-3-methoxypropene (32804-08-3) + cis-1-chloro-3-methoxypropene + (E)-1,3-dichloro-prop-1-ene (10061-02-6)

Guidance literature:

With aluminium; at 250 ℃; Product distribution; Mechanism; other temp.;

DOI:10.1246/bcsj.54.633

Reference yield:

chlorine (7782-50-5) + 3-chloroprop-1-ene (107-05-1) → 2,3-Dichloroprop-1-ene (78-88-6) + cis-1,3-Dichloropropene (10061-01-5) + 3,3-dichloropropene (563-57-5) + (E)-1,3-dichloro-prop-1-ene (10061-02-6)

Guidance literature:

at 510 ℃; nach Vorwaermen auf 100grad;

upstream raw materials:

3,3-dichloropropene

3-chloroprop-1-ene

methanol

1,2,3-trichloropropane

Downstream raw materials:

1-Chloro-3-acetoxypropene

Aethyl-3,3-bis--carbazat

(E)-N-(3-chloropropenyl)-N-ethyl-3-hydroxybenzylamine

(E)-N-(3-chloro-2-propenyl)-N-propyl-3-hydroxybenzylamine

Refernces

• 1、 -. "MANUFACTURE OF DICHLOROPROPANOL". Page/Page column 19-21. . Retrieved 2009/03/07.
• 2、 Shinoda, Kiyonori,Yasuda, Kensei. "The Copyrolysis of 1,2,3-Trichloropropane and Methanol on Activated Alumina". . p. 633 - 634. Retrieved 2007/10/02.