10519-97-8

Basic information

• Product Name: ALLYLAMINOTRIMETHYLSILANE
• Synonyms: 1,1,1-trimethyl-N-2-propenyl-Silanamine;N-TRIMETHYLSILYLALLYLAMINE;ALLYLAMINOTRIMETHYLSILANE;Allylaminotrimethylsilane(N-Trimethylsilylallylamine);(2-Propenylamino)trimethylsilane;Allyl(trimethylsilyl)amine;N-Allyltrimethylsilylamine;Trimethyl(allylamino)silane
• CAS NO: 10519-97-8
• Molecular Formula: C₆H₁₅NSi
• Molecular Weight: 129.28
• Product Categories: Nitrogen Compounds;Organic Building Blocks;Protected Amines
• Mol File: 10519-97-8.mol

Chemical Properties

• Melting Point: <0℃
• Boiling Point: 110-112 °C
• Flash Point: 10 °C
• Appearance: clear colorless to light yellow liquid
• Density: 0,77 g/cm3
• Vapor Pressure: 36.6mmHg at 25°C
• Refractive Index: 1.411-1.416
• Storage Temp.: Flammables area
• PKA: 12.33±0.70(Predicted)
• CAS DataBase Reference: ALLYLAMINOTRIMETHYLSILANE(CAS DataBase Reference)
• NIST Chemistry Reference: ALLYLAMINOTRIMETHYLSILANE(10519-97-8)
• EPA Substance Registry System: ALLYLAMINOTRIMETHYLSILANE(10519-97-8)

Safety Data

• Hazard Codes: C-F,C
• Statements: 34-11
• Safety Statements: 45-36/37/39-25-16-26-23
• RIDADR: 2924
• TSCA: No
• Hazardous Substances Data: 10519-97-8(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
ALLYLAMINOTRIMETHYLSILANE is used as a precursor for the synthesis of silicon carbonitride films, which are known for their exceptional properties such as high-temperature stability, hardness, and chemical inertness. These films find applications in various industries, including aerospace, automotive, and electronics.
Used as an Intermediate in Synthesis:
ALLYLAMINOTRIMETHYLSILANE is also used as an intermediate in the synthesis of Z-3-(Tributylstannyl)-2-propen-1-amine (T773980), a compound with potential applications in the development of new materials and pharmaceuticals.

InChI:InChI=1/C6H15NSi/c1-5-6-7-8(2,3)4/h5,7H,1,6H2,2-4H3

Upstream product

• 107-11-9 1-amino-2-propene 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 2469-55-8 1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane 
• 919-30-2 3-aminopropyltriethoxysilane 
• 7688-51-9 N,N-bis(trimethylsilyl)allylamine 
• 20152-18-5 1,4-bis(3-aminopropyldimethylsilyl)benzene 
• 26028-43-3 1,3,5-triallylhexahydro-1,3,5-triazine 
• 107-46-0 Hexamethyldisiloxane 
• 50487-71-3 4-methyl-N-(2-propenyl)benzenesulfonamide 

Relevant articles and documents

Synthesis of oligosiloxanes with 3-aminopropyl groups and their testing as surfactants in the preparation of polymer microspheres

Polydimethyl-co-methyl(3-aminopropyl)siloxanes differing in the content of amino groups and molecular weight were synthesized by two pathways, namely, by hydrosilylation of oligodimethyl-co-methylhydrоsiloxane with N-(trimethylsilyl)allylamine (TMSAA) and by copolymerization of octamethylcyclotetrasiloxane with methyl(3-aminopropyl)cyclosiloxanes. The colloid-chemical properties of the synthesized oligomers were studied. The oligosiloxanes possess high surface activity and can reduce the interfacial tension in the interface surfactant solution in toluene–water to 6.7–4.2 mJ m2. Aggregatively stable polystyrene suspensions with particle of 0.5 and 0.8 μm in diameter were obtained in the presence of the synthesized oligomers.

Dianion aggregates derived from lithiation of N-silyl allylamine

Three different N-silyl-protected allylamines, i.e., N-TMS, N-TBDMS, and N-TIPS allylamine, were lihtiated by reaction with excess n-butyllithium. Crystallization of the resulting dianions and X-ray structure determination yields three uniquely different aggregates.

IMPROVED PROCESS FOR PRODUCING BIS-(AMINOALKYL)-POLYSILOXANES

Bis(aminoalkyl)siloxane dimers or oligomers are prepared by a process utilizing hydrosilation of an olefinic amine with tetraorganodisiloxane or with bis(dialkylhydrogen)siloxane oligomers to generate high purity bis(aminoalkyl)disiloxane or bis(aminoalkyl)siloxane oligomers at high conversion yield, which may then be subsequently equilibrated to higher molecular weight bis(aminoalkyl)polysiloxanes.

N-silyl-tethered radical cyclizations: a new synthesis of gamma-amino alcohols.

[reaction: see text] Various allylic and propargylic amines bearing a protecting group (PG) have been employed in N-silyl-tethered radical cyclizations. The resulting silapyrrolidine adducts could be smoothly oxidized, creating access to gamma-amino alcoh

Novel method for preparing bis(trimethylsilyl) amines via treatment with trimethylsilylamines and methyl iodide

A convenient method for the synthesis of N,N-bis(trimethylsilyl)alkylamines has been reported. N-(Trimethylsilyl)diethylamine incorporated with a stoichiometric amount of methyl iodide was effective to convert primary amines, especially aromatic amines, and their monotrimethylsilyl derivatives into the corresponding N,N-bis(trimethylsilyl)amine derivatives in high yields. In the case of N-trimethylsilyl derivatives of aliphatic primary amines, a half-amount of silylamines served as a silylation agent against another half-amount of silylamines in the presence of 0.5 equivalent of methyl iodide to give N,N-bis(trimethylsilyl)alkylamines in good yield. Allyl iodide, allyl bromide and benzyl bromide were also effective to promote the silylation activity of silylamines.

Synthese und Ligandeneigenschaften von 2-Methyl-1-trimethylsilyl- und 2-Methyl-Δ3-1,2-azaborolin

2-Methyl-1-trimethylsilyl-Δ3-1,2-azaboroline (1), synthesized from LiCH=CH-CH2-NLi and CH3BBr2 can be transformed to 2-methyl-Δ3-1,2-azaboroline (2) by elimination of the trimethylsilyl group with etheral HCl. 2 dimerises at room temperature via N -> B-coordination to 2. 1 and 2 react with Fe(CO)5 to the azaborolinyl complexes di-μ-carbonyl-biscarbonyl-(2-methyl-1-trimethylsilyl-η-1,2-azaborolinyl)iron>(Fe - Fe) (3) and di-μ-carbonyl-bis(Fe - Fe) (4), resp.The IR, 1H-NMR, 11B-NMR, and mass spectra of the compounds are discussed.