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7688-51-9

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7688-51-9 Usage

Uses

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare: Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions. Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride. Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

Check Digit Verification of cas no

The CAS Registry Mumber 7688-51-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,6,8 and 8 respectively; the second part has 2 digits, 5 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 7688-51:
(6*7)+(5*6)+(4*8)+(3*8)+(2*5)+(1*1)=139
139 % 10 = 9
So 7688-51-9 is a valid CAS Registry Number.
InChI:InChI=1/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3

7688-51-9 Well-known Company Product Price

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  • Aldrich

  • (578932)  N-Allyl-N,N-bis(trimethylsilyl)amine  97%

  • 7688-51-9

  • 578932-5G

  • 1,526.85CNY

  • Detail

7688-51-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name N,N-bis(trimethylsilyl)prop-2-en-1-amine

1.2 Other means of identification

Product number -
Other names N-Allyl-N,N-bis(trimethylsilyl)amine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7688-51-9 SDS

7688-51-9Relevant articles and documents

Lithium and potassium bis(trimethylsilyl)amide: Utilizing non-nucleophilic bases as nitrogen sources

Bruening, Joerg

, p. 3187 - 3188 (1997)

Lithium and potassium bis(trimethylsilyl)amides are successfully utilized as nitrogen sources in palladium(0) catalyzed aminations of allylchloride.

Synthesis of bifunctional disiloxanes: Via subsequent hydrosilylation of alkenes and alkynes

Szyling, Jakub,Januszewski, Rafa?,Jankowska, Kamila,Walkowiak, J?drzej,Kownacki, Ireneusz,Franczyk, Adrian

supporting information, p. 4504 - 4507 (2021/05/17)

The first protocol for the synthesis of unsymmetrical bifunctional 1,1,3,3-tetramethyldisiloxane derivatives via subsequent hydrosilylation of alkenes and alkynes is presented. The methodology described has vast functional group tolerance and is extremely efficient towards the formation of novel disiloxane-based building blocks.

METHOD FOR PRODUCING SILANE COMPOUND HAVING BIS-SILYLAMINO GROUP

-

Paragraph 0028, (2018/06/30)

PROBLEM TO BE SOLVED: To provide a method for producing a silane compound having a bis-silylamino group efficiently, stably, and in good yield. SOLUTION: A method for producing a silane compound having a bis-silylamino group represented by the formula (3) includes reacting a compound represented by the formula (2): HSiR8nX3-n (2) with a compound represented by the formula (1) in the presence of a platinum compound where the compound represented by the formula (1) having a content of a compound represented by the formula (4) of not greater than 5.0 mass% is used. In the formulae, R1 is a C1-18 bivalent hydrocarbon group, R1' is a C3-20 bivalent hydrocarbon group, R2-R8 and R9 are each independently a substituted or unsubstituted C1-20 monovalent hydrocarbon group, X is a halogen or OR9, and n is an integer of 0-2. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPOandINPIT

Discovery of (S)-3′-hydroxyblebbistatin and (S)-3′-aminoblebbistatin: polar myosin II inhibitors with superior research tool properties

Verhasselt, Sigrid,Roman, Bart I.,De Wever, Olivier,Van Hecke, Kristof,Van Deun, Rik,Bracke, Marc E.,Stevens, Christian V.

supporting information, p. 2104 - 2118 (2017/03/11)

In search of myosin II inhibitors with superior research tool properties, a chemical optimization campaign of the blebbistatin scaffold was conducted in this paper. (S)-Blebbistatin is the best known small-molecule inhibitor of myosin II ATPase activity. Unfortunately, as a research tool this compound has several deficiencies: it is photolabile and (photo)toxic, has low water solubility, and its (fluorescent) precipitates interfere in (fluorescence) readouts. In view of obtaining tool compounds with improved properties, both enantiomers of a series of D-ring modified polar analogs were prepared. We identified (S)-3′-hydroxyblebbistatin (S)-2 and (S)-3′-aminoblebbistatin (S)-3 as two myosin II inhibitors with a 30-fold higher water solubility than (S)-blebbistatin. These molecules furthermore do not cause interference in (fluorescence) readouts. (S)-2 and (S)-3 thus are superior alternatives to (S)-blebbistatin as research tools to study myosin II.

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