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CAS

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1801-77-0

DICHLOROETHOXYOXOVANADIUM (V), also known as vanadium(V) oxydichloroethoxide, is a coordination complex of vanadium(V) with two ethoxy (OEt) groups and two chloride (Cl) ions, represented by the chemical formula V(OEt)Cl2. DICHLOROETHOXYOXOVANADIUM (V) is recognized for its role in catalysis and its potential applications in medicine.

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  • 1801-77-0 Structure

  • Basic information

    1. Product Name: DICHLOROETHOXYOXOVANADIUM (V)
    2. Synonyms: DICHLOROETHOXYOXOVANADIUM (V);Triethoxyoxovanadium dichloride;Dichloridevanadic acid ethyl ester;Dichloroethoxyoxovanadium
    3. CAS NO:1801-77-0
    4. Molecular Formula: C2H5Cl2O2V
    5. Molecular Weight: 182.91
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 1801-77-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: DICHLOROETHOXYOXOVANADIUM (V)(CAS DataBase Reference)
    10. NIST Chemistry Reference: DICHLOROETHOXYOXOVANADIUM (V)(1801-77-0)
    11. EPA Substance Registry System: DICHLOROETHOXYOXOVANADIUM (V)(1801-77-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 1801-77-0(Hazardous Substances Data)

1801-77-0 Usage

Uses

Used in Organic Synthesis:
DICHLOROETHOXYOXOVANADIUM (V) is used as a catalyst for the production of specialty chemicals and pharmaceuticals, facilitating various organic synthesis processes due to its unique catalytic properties.
Used in Chemical Reactions:
DICHLOROETHOXYOXOVANADIUM (V) serves as a reagent in a range of chemical reactions, contributing to the advancement of chemical research and the development of new compounds.
Used in Research:
DICHLOROETHOXYOXOVANADIUM (V) is utilized as a research tool in the study of vanadium chemistry, aiding scientists in understanding the behavior and applications of vanadium compounds.
Used in Medical Applications:
DICHLOROETHOXYOXOVANADIUM (V) is being investigated for its potential applications in medicine, particularly in the treatment of diabetes and cancer, due to its demonstrated biological activity.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, DICHLOROETHOXYOXOVANADIUM (V) is used as a catalyst and reagent to enhance the synthesis of various drugs, improving the efficiency and effectiveness of drug production processes.

Check Digit Verification of cas no

The CAS Registry Mumber 1801-77-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,8,0 and 1 respectively; the second part has 2 digits, 7 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1801-77:
(6*1)+(5*8)+(4*0)+(3*1)+(2*7)+(1*7)=70
70 % 10 = 0
So 1801-77-0 is a valid CAS Registry Number.

1801-77-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 2,2-dichloroethanol,oxovanadium(2+)

1.2 Other means of identification

Product number -
Other names dichloroethoxyvanadium

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:1801-77-0 SDS

1801-77-0Relevant articles and documents

Enantioselective radical cross-coupling reactions of silyl enol ethers using chiral oxovanadium

Kurihara, Masaaki,Hayashi, Taeko,Miyata, Naoki

, p. 1324 - 1325 (2001)

Asymmetric induction was observed in radical cross-coupling reactions of silyl enol ethers using chiral oxovanadium generated in situ from 8-phenylmenthol and vanadium oxytrichloride in the presence of MS4A (molecular sieves-4A).

Oxo- and imido-alkoxide vanadium complexes as precatalysts for the guanylation of aromatic amines

Romero-Fernandez, Javier,Carrillo-Hermosilla, Fernando,Antinolo, Antonio,Alonso-Moreno, Carlos,Rodriguez, Ana M.,Lopez-Solera, Isabel,Otero, Antonio

, p. 6419 - 6425 (2010/09/06)

Vanadium oxo-alkoxide complexes [V(O)(Cl)3-x(OR)x] (x = 1, R = Me (1), Et (2), n-Pr (3); x = 2, R = Me (4), Et (5), n-Pr (6)) were obtained by a clean reaction between [V(O)Cl3] and different excesses of ROSiMe3

High valence vanadium complex promoted selective rearrangement of epoxides to aldehydes or ketones

Martinez, Fernando,Campo, Carmen del,Llama, Emilio F.

, p. 1749 - 1752 (2008/10/08)

High valence vanadium complexes induce the selective ring opening of epoxides. The monosubstituted epoxides are isomerized with complete regioselectivity each forming a single carbonyl compound exclusively. Likewise a highly regioselective isomerization of 1,1-disubstituted or 1,1,2-trisubstituted epoxides was observed in all reactions.

Oxovanadium(V)-Induced Ring-Opening Oxygenation of Cyclic Ketones in Alcohol

Hirao, Toshikazu,Mori, Makoto,Ohshiro, Yoshiki

, p. 2399 - 2400 (2007/10/02)

Cyclic ketones underwent ring-opening oxygenation on treatment with VO(OEt)Cl2 in alcohol under oxygen to give the corresponding keto ester or diesters depending on the substituent at 2-position.This system was applicable to a catalytic reaction.

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