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1-NONEN-3-OL is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 21964-44-3 Structure
  • Basic information

    1. Product Name: 1-NONEN-3-OL
    2. Synonyms: 1-Nonene-3-ol;1-Vinylheptanol;Non-1-en-3-ol;nonene-1-ol-3;N-HEXYLVINYLCARBINOL;1-NONEN-3-OL;HEXYL VINYL CARBINOL;1-NONEN-3-OL 98%
    3. CAS NO:21964-44-3
    4. Molecular Formula: C9H18O
    5. Molecular Weight: 142.24
    6. EINECS: 244-686-1
    7. Product Categories: N/A
    8. Mol File: 21964-44-3.mol
  • Chemical Properties

    1. Melting Point: -7°C (estimate)
    2. Boiling Point: 192-194 °C
    3. Flash Point: 84 °C
    4. Appearance: /
    5. Density: 0.83
    6. Vapor Pressure: 0.124mmHg at 25°C
    7. Refractive Index: 1.438-1.444
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. PKA: 14.63±0.20(Predicted)
    11. BRN: 1745976
    12. CAS DataBase Reference: 1-NONEN-3-OL(CAS DataBase Reference)
    13. NIST Chemistry Reference: 1-NONEN-3-OL(21964-44-3)
    14. EPA Substance Registry System: 1-NONEN-3-OL(21964-44-3)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: 24/25
    4. WGK Germany:
    5. RTECS:
    6. TSCA: Yes
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 21964-44-3(Hazardous Substances Data)

21964-44-3 Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 4112, 1984 DOI: 10.1021/jo00196a002Tetrahedron Letters, 22, p. 2135, 1981 DOI: 10.1016/S0040-4039(01)93298-8

Check Digit Verification of cas no

The CAS Registry Mumber 21964-44-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,1,9,6 and 4 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 21964-44:
(7*2)+(6*1)+(5*9)+(4*6)+(3*4)+(2*4)+(1*4)=113
113 % 10 = 3
So 21964-44-3 is a valid CAS Registry Number.
InChI:InChI=1/C9H18O/c1-3-5-6-7-8-9(10)4-2/h4,9-10H,2-3,5-8H2,1H3/t9-/m1/s1

21964-44-3 Well-known Company Product Price

  • Brand
  • (Code)Product description
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  • Detail
  • Alfa Aesar

  • (L06889)  1-Nonen-3-ol, 98%   

  • 21964-44-3

  • 5g

  • 327.0CNY

  • Detail
  • Alfa Aesar

  • (L06889)  1-Nonen-3-ol, 98%   

  • 21964-44-3

  • 25g

  • 1204.0CNY

  • Detail

21964-44-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-NONEN-3-OL

1.2 Other means of identification

Product number -
Other names 1-Nonen-3-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:21964-44-3 SDS

21964-44-3Relevant articles and documents

Radical reactions of epoxy esters induced by titanocene chloride

Fernández-Mateos,Herrero Teijón,Rabanedo Clemente,Rubio González

, p. 7755 - 7758 (2006)

The reductive radical cyclizations of several epoxy esters have been achieved using titanocene chloride. The tether length from the initial radical to the carbonyl acceptor is the key of the reactions. We obtained products from radical cyclization onto carbonyl formate and products from formate and hydrogen elimination. The stereochemical outcome of the 5-exo radical cyclization of two diastereomers is reported. A radical cascade cyclization of an unsaturated epoxy formate is also described.

Annulation-retro-Claisen cascade of bifunctional peroxides for the synthesis of lactone natural products

Hu, Lin,Li, Jialin,Li, Xuemin,Xu, Qianlan

supporting information, p. 274 - 277 (2022/01/03)

A new and highly efficient annulation-retro-Claisen cascade, which involves the [4 + 1] or [5 + 1] annulation of α-benzoylacetates with bielectrophilic peroxides and a subsequent debenzoylation process under mild basic conditions, has been developed for the rapid construction of valuable tetrahydrofuran- and dihydropyran-2-carboxylates in good yields. By employing the new reaction, the unified total synthesis of γ- and δ-lactone natural products such as (±)-tanikolide, (±)-goniothalamins, (±)-7-epi-goniodiol, and (±)-plakolide A has been accomplished in 4-7 steps.

β-Borylation of conjugated carbonyl compounds with silylborane or bis(pinacolato)diboron catalyzed by Au nanoparticles

Fragkiadakis, Michael,Kidonakis, Marios,Stratakis, Manolis

supporting information, p. 8921 - 8927 (2020/11/23)

Conjugated aldehydes and ketones undergo reaction with Me2PhSiBpin (pin: pinacolato) catalyzed by Au nanoparticles supported on TiO2 forming exclusively the β-borylation products, via the intermediate formation of the labile silaboration adducts. This chemoselectivity pathway is complementary to the so far known analogous reaction catalyzed by other metals, where β-silylation occurs instead. β-Borylation also occurs with pinBBpin under identical reaction conditions in a variety of conjugated carbonyl compounds, including esters and amides which are unreactive in their attempted Au-catalyzed silaboration. This journal is

Silica-coated Fe3O4 magnetic nanoparticles-supported sulfonic acid as a highly active and reusable catalyst in chemoselective deprotection of tert-butyldimethylsilyl (TBDMS) ethers

Hossein Javadi, Sayed,Zareyee, Daryoush,Monfared, Azam,Didehban, Khadijeh,Mirshokraee, Sayed Ahmmad

supporting information, p. 7 - 12 (2019/11/03)

Anchored propyl sulfonic acid on the surface of silica-coated magnetic nanoparticles (Fe3O4@SiO2@PrSO3H) was successfully employed in the deprotection of TBDMS ethers. The prepared magnetically separable nanocatalyst exhibited efficient catalytic activity with high conversion and selectivity in cleavage of TBDMS ethers. TBDMS ethers are efficiently cleaved to the corresponding hydroxyl compounds in methanol solution containing 2 mol% magnetic nano-catalysts. Good to excellent yields of products, simple work-up and product separation, selective cleavage of TBDMS ethers in the presence of TBDPS ethers, easy recycling of the catalyst with external magnet with no loss in its activity (7 reaction cycles) are important features of this new protocol.

Ruthenium-Catalyzed Direct Dehydrogenative Cross-Coupling of Allyl Alcohols and Acrylates: Application to Total Synthesis of Hydroxy β-Sanshool, ZP-Amide I, and Chondrillin

Dethe, Dattatraya H.,Nagabhushana, C. B.

supporting information, (2020/02/15)

Ru-catalyzed oxidative coupling of allyl alcohols and activated olefins has been developed by C(allyl)-H activation of allyl alcohols providing efficient and direct access to synthetically useful α,β-unsaturated enone intermediates. Synthetic utility of this method was demonstrated by its application to synthesis of bioactive natural products such as Hydroxy-β-sanshool, ZP-amide I, Chondrillin, Plakorin, and (+)-cis-Solamin A.

Enantioselective addition of selenosulfonates to α,β-unsaturated ketones

Luo, Shilong,Zhang, Nan,Wang, Zhen,Yan, Hailong

supporting information, p. 2893 - 2901 (2018/05/03)

An organo-catalyzed enantioselective addition of selenosulfonates to α,β-unsaturated ketones was developed for the first time. With a chiral squaramide as an efficient catalyst, the desired α-selenylated ketones were obtained in a good yields with high enantioselectivity up to 89% ee, and good results could be obtained on a gram scale. The products could also be efficiently transformed into useful building blocks with a propenylic stereocenter; the strategy presented in this study may find further applications in organic synthesis.

Iron-Catalyzed Grignard Cross-Couplings with Allylic Methyl Ethers or Allylic Trimethylsilyl Ethers

Seto, Chika,Otsuka, Takeshi,Takeuchi, Yoshiki,Tabuchi, Daichi,Nagano, Takashi

supporting information, p. 1211 - 1214 (2018/03/26)

We have found that cross-coupling between aryl Grignard reagents and allylic methyl ethers proceeded well in the presence of a catalytic amounts of Fe(acac) 3 to afford the corresponding allylic substitution products in good yields. Under the same conditions, allylic trimethylsilyl ethers also reacted with Grignard reagents to give the corresponding cross-coupling products.

One-Pot Transformation of Simple Furans into Octahydroindole Scaffolds

Kalaitzakis, Dimitris,Triantafyllakis, Myron,Ioannou, Georgios I.,Vassilikogiannakis, Georgios

supporting information, p. 4020 - 4023 (2017/03/27)

A highly efficient and general singlet-oxygen-initiated one-pot transformation of readily accessible furans into octahydroindole scaffolds has been developed.

Highly efficient kinetic resolution of allylic alcohols with terminal double bond

Marques, Francisco A.,Oliveira, Marcos A.,Frensch, Gustavo,Sales Maia, Beatriz Helena L. N.,Barison, Andersson,Lenz, Cesar A.,Guerrero Jr., Palimecio G.

experimental part, p. 696 - 700 (2012/06/04)

In this study, the lipase-catalyzed kinetic resolution (Novozyme 435) was employed to prepare chiral allylic alcohols and acetates with terminal double bonds in enantiomeric excesses ranging from 94 to >99 %.

Titanocene-promoted eliminations on epoxy alcohols and epoxy esters

Fernandez-Mateos, Alfonso,Madrazo, Soledad Encinas,Teijon, Pablo Herrero,Gonzalez, Rosa Rubio

experimental part, p. 856 - 861 (2010/04/05)

The reaction of a series of 2,3-epoxy alcohols and the corresponding formates, acetates, and benzoates promoted by Cp2TiCl has been studied. The different outcome of the reaction of epoxy derivatives has been rationalized in terms of mechanistically biased processes. After homolytic oxirane cleavage, four main types of reaction were found: dehydroxylation, decarboxylation, dehydrogenation, and deoxygenation. The reaction products varied according to the substitution pattern. The radical nature of these eliminations is demonstrated.

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