DISPROPORTIONATION KINETICS OF N-CHLOROMETHYLAMINE AND N-CHLOROETHYLAMINE
The kinetics of disproportionation of N-Cl-methylamine and N-Cl-ethylamine in water were studied at acid pH.Its disproportionation and protonation constants and the coefficients of absorption of N,N-dichloramines are calculated and the mechanism of its disproportionation is discussed.
Antelo, J. M.,Arce, F.,Parajo, M.,Rodriguez, P.
p. 1031 - 1036
(2007/10/02)
Vacuum Gas/Solid N-Chlorination: Preparative Scale Synthesis of Volatile N-Chloramines
A simple method for the preparative scale synthesis of volatile chloramines free from impurities starting from the corresponding primary or secondary amine using N-chlorosuccinimide as chlorinating agent is described.
Guillemin, J. C.,Denis, J. M.
p. 1131 - 1133
(2007/10/02)
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