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3-Methoxyphenyloxytrimethylsilane is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 33285-71-1 Structure
  • Basic information

    1. Product Name: 3-Methoxyphenyloxytrimethylsilane
    2. Synonyms: 3-Methoxyphenyloxytrimethylsilane
    3. CAS NO:33285-71-1
    4. Molecular Formula: C10H16O2Si
    5. Molecular Weight: 0
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 33285-71-1.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: /
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 3-Methoxyphenyloxytrimethylsilane(CAS DataBase Reference)
    10. NIST Chemistry Reference: 3-Methoxyphenyloxytrimethylsilane(33285-71-1)
    11. EPA Substance Registry System: 3-Methoxyphenyloxytrimethylsilane(33285-71-1)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 33285-71-1(Hazardous Substances Data)

33285-71-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 33285-71-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,3,2,8 and 5 respectively; the second part has 2 digits, 7 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 33285-71:
(7*3)+(6*3)+(5*2)+(4*8)+(3*5)+(2*7)+(1*1)=111
111 % 10 = 1
So 33285-71-1 is a valid CAS Registry Number.

33285-71-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-methoxy-3-(trimethylsiloxy)benzene

1.2 Other means of identification

Product number -
Other names m-Anisyl-trimethylsilyloxid

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:33285-71-1 SDS

33285-71-1Relevant articles and documents

Regioselectivity of Hydroxyl Radical Reactions with Arenes in Nonaqueous Solutions

Moores, Lee C.,Kaur, Devinder,Smith, Mathew D.,Poole, James S.

, p. 3260 - 3269 (2019/03/11)

The regioselectivity of hydroxyl radical addition to arenes was studied using a novel analytical method capable of trapping radicals formed after the first elementary step of reaction, without alteration of the product distributions by secondary oxidation processes. Product analyses of these reactions indicate a preference for o- over p-substitution for electron donating groups, with both favored over m-addition. The observed distributions are qualitatively similar to those observed for the addition of other carbon-centered radicals, although the magnitude of the regioselectivity observed is greater for hydroxyl. The data, reproduced by high accuracy CBS-QB3 computational methods, indicate that both polar and radical stabilization effects play a role in the observed regioselectivities. The application and potential limitations of the analytical method used are discussed.

Synthesis of o-Aryloxy Triarylsulfonium Salts via Aryne Insertion into Diaryl Sulfoxides

Li, Xiaojin,Sun, Yan,Huang, Xin,Zhang, Lei,Kong, Lichun,Peng, Bo

supporting information, p. 838 - 841 (2017/02/26)

The aryne insertion into "S-O" bond has been validated recently. This technology is elusively applied to the synthesis of thioethers. In contrast to the reported cases, the reaction described furnished o-aryloxy triarylsulfonium salts, in lieu of thioethe

Total Syntheses of Aporphine Alkaloids via Benzyne Chemistry: An Approach to the Formation of Aporphine Cores

Rossini, Allan F. C.,Muraca, Ana Carolina A.,Casagrande, Gleison A.,Raminelli, Cristiano

, p. 10033 - 10040 (2015/11/03)

Total syntheses of lysicamine, (±)-nuciferine, (±)-nornuciferine, (±)-zanthoxyphylline iodide, (±)-O-methylisothebaine, and (±)-trimethoxynoraporphine were accomplished by an approach that involves the formation of aporphine cores through reactions betwee

Catalyst-free silylation of alcohols and phenols by promoting HMDS in CH3NO2 as solvent

Kadam, Santosh T.,Kim, Sung Soo

supporting information; experimental part, p. 94 - 98 (2010/05/18)

An uncatalyzed method for the silylation of alcohols and phenols with HMDS in CH3NO2 at rt is developed. A diverse range of aromatic and aliphatic alcohols as well as phenols undergo the silylation in very short reaction time with ex

Nafion SAC-13: heterogeneous and reusable catalyst for the activation of HMDS for efficient and selective O-silylation reactions under solvent-free condition

Rajagopal, Gurusamy,Lee, Hanbin,Kim, Sung Soo

experimental part, p. 4735 - 4741 (2009/10/09)

Nafion SAC-13 effectively activates hexamethyldisilazane (HMDS) for the efficient and selective silylation of alcohols. Primary, secondary, and tertiary alcohols and phenols are efficiently converted to their corresponding silylethers in short reaction ti

Mild and efficient silylation of alcohols and phenols with HMDS using Bi(OTf)3 under solvent-free condition

Kadam, Santosh T.,Kim, Sung Soo

experimental part, p. 2562 - 2566 (2009/12/24)

A very efficient and mild silylation of alcohols and phenols with hexamethyldisilazane (HMDS) at rt is developed using Bi(OTf)3 as the catalyst. Primary, secondary and tertiary alcohols as well as phenols are excellently converted into correspo

Simple and practical protocol for the silylation of phenol derivatives using reusable NaHSO4 dispread on silica gel under neutral conditions

Khalili, Mahideh S.,Ghafuri, Hossein,Mojahedi-Jahromi, Samaneh,Hashemi, Mohammed M.

, p. 175 - 179 (2007/10/03)

A simple and mild procedure for the trimethylsilylation of a wide variety of phenols with hexamethyldisilazane (HMDS) on the surface of silica gel dispersed with NaHSO4 at r.t. in a few minutes with excellent yields under neutral conditions is

Silica sulfuric acid as a reusable catalyst for efficient and simple silylation of hydroxyl groups using hexamethyldisilazane (HMDS)

Ghafuri, Hossein,Eftekhari-Sis, Bagher,Hashemi, Mohammed M.

, p. 1645 - 1651 (2008/02/08)

At room temperature, alcohols and phenols are efficiently protected with hexamethyldisilazane (HMDS) in the presence of silica sulfuric acid in good to excellent yields. The catalyst can be recycled for subsequent reactions without any appreciable loss of efficiency. Copyright Taylor and Francis Group, LLC.

Electrophilic Hydroxylation with Bis(trimethylsilyl)peroxide. A Synthon for the Hydroxyl Cation

Taddei, Maurizio,Ricci, Alfredo

, p. 633 - 635 (2007/10/02)

The regiospecific introduction of an hydroxy group in aromatic and aliphatic compounds can be performed in good yields by electrophilic hydroxylation of their organometallic derivatives with bis(trimethylsilyl)peroxide.

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