460-73-1

Basic information

• Product Name: 1,1,1,3,3-Pentafluoropropane
• Synonyms: HFC-245FA;Pentafluoropropane;1,1,1,3,3-PENTAFLUOROPROPANE;HCF-245FA;1,1,1,3,3-PENTAFLUOROPROPANE 97%;FC-245fa;1,1,3,3,3-Pentafluoropropane;Propane, 1,1,1,3,3-pentafluoro-
• CAS NO: 460-73-1
• Molecular Formula: C₃H₃F₅
• Molecular Weight: 134.05
• Product Categories: Industrial/Fine Chemicals;refrigerants
• Mol File: 460-73-1.mol

Chemical Properties

• Melting Point: -102.1°C
• Boiling Point: 15,3°C
• Appearance: /
• Density: 1.32
• Vapor Pressure: 758mmHg at 25°C
• Refractive Index: 1.2803 (estimate)
• Stability: Stable.
• CAS DataBase Reference: 1,1,1,3,3-Pentafluoropropane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1,1,3,3-Pentafluoropropane(460-73-1)
• EPA Substance Registry System: 1,1,1,3,3-Pentafluoropropane(460-73-1)

Safety Data

• Statements: R12:Extremely flammable.
• Safety Statements: 3/7-9-23
• RIDADR: 3163
• HazardClass: 2.2
• Hazardous Substances Data: 460-73-1(Hazardous Substances Data)

Usage

Uses

Used in Foam Industry:
1,1,1,3,3-Pentafluoropropane is used as a foam-blowing agent for the production of various types of foam, such as polyurethane and polystyrene. It is chosen for this application due to its ability to act as a blowing agent, which helps create the desired cellular structure in the foam.
Used in Refrigeration Industry:
1,1,1,3,3-Pentafluoropropane is used as a refrigerant in various cooling systems, including air conditioning and refrigeration units. It is selected for this purpose because of its thermodynamic properties, which allow for efficient heat transfer and cooling performance.
Used in Environmentally Friendly Applications:
1,1,1,3,3-Pentafluoropropane is used as an environmentally friendly alternative to fully halogenated chlorofluorocarbons (CFCs) in various industries. It is chosen for this application because it has a lower global warming potential (GWP) and ozone depletion potential (ODP) compared to CFCs, making it a more sustainable choice for reducing the environmental impact of refrigeration and foam production processes.

InChI:InChI=1/C3H2ClF5/c4-2(5,6)1-3(7,8)9/h1H2

Upstream product

• 690-27-7 2H-pentafluoropropene 
• 102687-65-0 trans-1-chloro-3,3,3-trifluoropropene 
• 431-71-0 1,1,1,3,3-pentafluoro-2-propanone 
• 23153-23-3 1,1,1,3,3-pentachloropropane 
• 2730-43-0 1-chloro-3,3,3-trifluoropropene 
• 1599-41-3 2,2,3-trichloro-1,1,1,3,3-pentafluoropropane 
• 139754-78-2 1,3-dichloro-1,1,3-trifluoropropane 
• 99728-16-2 (Z)-1-chloro-3,3,3-trifluoro-1-propene 
• 460-36-6 1,1,1,4-tetrafluoropropane 
• 690-39-1 1,1,1,3,3,3-hexafluoropropane 
• 460-96-8 bis(trifluoromethyl)phosphine 
• 338-75-0 2,3-dichloro-1,1,1-trifluoropropane 
• 677-21-4 1,1,1-trifluoropropylene 
• 74-87-3 methylene chloride 

Downstream Products

• 1645-83-6 1,3,3,3-tetrafluoro-propene 
• 75-90-1 2,2,2-Trifluoroacetaldehyde 
• 1718-18-9 Bis(trifluoromethyl)trioxide 
• 76-05-1 trifluoroacetic acid 
• 149846-93-5 1-phenyl-4,4,4-trifluorobut-2-yn-1-ol 
• 85694-32-2 1-phenyl-4,4,4-trifluoro-1-butyn-3-one 
• 33730-49-3 PPh₂(CCCF₃) 
• 1599-41-3 2,2,3-trichloro-1,1,1,3,3-pentafluoropropane 
• 354-58-5 1,1,1-Trichloro-2,2,2-trifluoroethane 
• 460-92-4 1-chloro-1,1,3,3,3-pentafluoropropane 
• 75-88-7 1,1,1-trifluoro-2-chloroethane 
• 431-86-7 1,1,1,3,3-pentafluoro-2,3-dichloropropane 
• 29118-24-9 trans-1,3,3,3-tetrafluoropropene 
• 29118-25-0 (Z)-1,3,3,3-tetrafluoropropene 

Relevant articles and documents

Versatile Reaction Pathways of 1,1,3,3,3-Pentafluoropropene at Rh(I) Complexes [Rh(E)(PEt3)3] (E=H, GePh3, Si(OEt)3, F, Cl): C-F versus C-H Bond Activation Steps

The reaction of the rhodium(I) complexes [Rh(E)(PEt3)3] (E=GePh3 (1), H (6), F (7)) with 1,1,3,3,3-pentafluoropropene afforded the defluorinative germylation products Z/E-2-(triphenylgermyl)-1,3,3,3-tetrafluoropropene and

Preparation method of Z-1-halogen-3, 3, 3-trifluoropropene

The invention discloses a preparation method of Z-1-halogen-3, 3, 3-trifluoropropene. The preparation method comprises the following steps: in the presence of a block catalyst, E-1-halogen-3, 3, 3-trifluoropropene is subjected to a gas phase isomerization reaction in a tubular reactor to obtain Z-1-halogen-3, 3, 3-trifluoropropene, and halogen is fluorine or chlorine. According to the preparation method, 1, 1, 1, 3, 3-pentachloropropane is used as an initial raw material, Z-1-chloro-3, 3, 3-trifluoropropene or Z-1, 3, 3, 3-tetrafluoropropene secondary product is prepared through a gas-phase fluorination reaction and an isomerization reaction, the materials which are not completely reacted are independently circulated through a gas-phase independent circulation process so that the initial raw materials can be almost completely converted into the target product, and finally, the target product is extracted from a process system, and thus liquid waste and waste gas are not generated, and green production is realized.

A structural, mechanistic, and kinetic study of the dehydrofluorination of 1,1,1,3,3-pentafluoropropane in the absence of catalyst

The catalyst-free dehydrofluorination of 1,1,1,3,3-pentafluoropropane (HFC-245fa) was investigated both experimentally and theoretically to elucidate the mechanism and kinetics of the reaction. The experimental results demonstrated easier generation of E-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) than HFO-1234ze(Z) under the same reaction conditions within a temperature range of 500–700 °C. When analyzing the geometry, energetics, and kinetic modeling of the reaction at the B3LYP/6?311++G (d,p) level of theory, it was found that the thermodynamic stability of HFO-1234ze(E) is relatively higher than its isomer (HFO-1234ze(Z). Besides, the rate constants of HFO-1234ze(E) were always larger than those of HFO-1234ze(Z) at 400–2000 K, which agreed well with the higher selectivity of HFO-1234ze(E) in the synthetic experiment results. Our theoretical demonstration provides a reference to investigate the mechanism and kinetics of other analogous reactions.

METHOD FOR CO-PRODUCING LOW-CARBON FOAMING AGENTS

The invention discloses a method for co-operating low-carbon foaming agents, comprising: preheating 1,1,1,3,3-pentachloropropane and hydrogen fluoride and then introducing into a reactor to have a reaction in the presence of a catalyst to obtain a reaction product, and separating and purifying to obtain the following low-carbon foaming agent products: trans-1,3,3,3-tetrafluoropropene, cis-1,3,3,3-tetrafluoropropene, 1,1,1,3,3-pentafluoropropane, trans-1-chloro-3,3,3-trifluoropropene, cis-1-chloro-3,3,3-trifluoropropene. The invention has the advantages of simple process, environmental friendliness, high production efficiency and low cost.

METHOD FOR CO-PRODUCING VARIOUS ALKENYL HALIDES AND HYDROFLUOROALKANES

Disclosed is a method for co-producing various alkenyl halides and hydrofluoroalkanes: cis-1-chloro-3,3,3-trifluoropropene is introduced into a first reactor to carry out an isomerization reaction in the presence of a first catalyst, and the reaction product is rectified to obtain a product trans-1-chloro-3,3,3-trifluoropropene; and 30-70 wt % of trans-1-chloro-3,3,3-trifluoropropene and hydrogen fluoride are mixed and then introduced into a second reactor to carry out a reaction in the presence of a second catalyst to obtain a second reactor reaction product; the second reactor reaction product is introduced into a phase separator for separation, and the obtained organic phase is rectified to obtain the products trans-1,3,3,3-tetrafluoropropene, cis-1,3,3,3-tetrafluoropropene and 1,1,1,3,3-pentafluoropropane. The invention has the advantages of simple process, high efficiency, high operation flexibility, less investment and low energy consumption.

Method for Producing Trans-1-Chloro-3,3,3-Trifluoropropene

The present invention provides a method for efficiently producing 1-chloro-3,3,3-trifluoropropene from a low-reactivity intermediate product. More specifically, provided is a method for producing trans-1-chloro-3,3,3-trifluoropropene, characterized by reacting a halogenated C3 hydrocarbon compound represented by the following general formula (1) with hydrogen fluoride in a gas phase in the presence of a solid catalyst and chlorine [in-line-formulae]C3HXClYFZ ??(1)[/in-line-formulae] wherein X is 2 or 3; when X=2, Y is an integer of 1 to 4, Z is an integer of 0 to 3, and Y+Z=4; and, when X=3, Y is an integer of 1 to 5, Z is an integer of 0 to 4, and Y+Z=5; provided that the general formula (1) represents any halogenated C3 hydrocarbon compound other than trans-1-chloro-3,3,3-trifluoropropene.

METHOD FOR PRODUCING FLUOROCARBON USING HYDROHALOFLUOROPROPENE

PROBLEM TO BE SOLVED: To provide a method for selectively producing fluorocarbon by efficiently isomerizing a hydrofluoropropene isomer (isomer 1) under the reduction of catalytic performance to produce a corresponding hydrohalofluoropropene isomer (isomer 2) and using the same. SOLUTION: Provided is a method for producing 3,3,3-trifluoropropene by contacting a 1-halogeno-3,3,3-trifluoropropene isomer with a moisture concentration of 100 ppm or lower (isomer 1) in a vapor phase so as to be isomerized to produce a corresponding 1-halogeno-3,3,3-trifluoropropene isomer (isomer 2), and subjecting the 1-halogeno-3,3,3-trifluoropropene isomer (isomer 2) to dehalogenation. SELECTED DRAWING: Figure 1 COPYRIGHT: (C)2018,JPOandINPIT

METHOD FOR PRODUCING AND PURIFYING 2,3,3,3-TETRAFLUOROPROPENE

The invention relates to a process for producing 2,3,3,3-tetrafluoropropene performed using a starting composition, comprising the steps of placing the starting composition in contact with HF, in the presence of a catalyst, to produce a composition A comprising 2,3,3,3-tetrafluoropropene (1234yf), intermediate products B consisting of 2-chloro-3,3,3-trifluoropropene (1233xf), 1,1,1,2,2-pentafluoropropane (245cb), and side products C consisting of E-1-chloro-3,3,3-trifluoro-1-propene (1233zdE), trans-1,3,3,3-tetrafluoro-1-propene (1234zeE) and 1,1,1,3,3-pentafluoropropane (245fa); recovery of said composition A and purification thereof to form and recover a first stream comprising 2,3,3,3-tetrafluoropropene (1234yf) and one or more streams comprising 2-chloro-3,3,3-trifluoropropene (1233xf) and/or 1,1,1,2,2-pentafluoropropane (245cb); recycling into step a) of said one or more streams comprising 2-chloro-3,3,3-trifluoropropene (1233xf) and/or 1,1,1,2,2-pentafluoropropane (245cb).

Process for catalytic conversion of mixtures of HCFO-1233zd(Z) and HCFC-244fa into HCFO-1233zd(E)

A method for conversion of a composition containing HCFO-1233zd(Z) and HCFC-244fa to form HCFO-1233zd(E) by reacting a mixture including HCFO-1233zd(Z) and HCFC-244fa in a vapor phase in the presence of a catalyst to simultaneously isomerize HCFO-1233zd(Z) to form HCFO-1233zd(E) and dehydrohalogenate HCFC-244fa to form HCFO-1233zd(E). The catalyst may be a chromium-based catalyst such as chromium trifluoride, chromium oxyfluoride, or chromium oxide, for example.

PROCESS FOR THE CO-PRODUCTION OF OF 2,3,3,3-TETRAFLUOROPROPENE AND 1,3,3,3-TETRAFLUOROPROPENE

The present invention provides a method of producing 2,3,3,3-tetrafluoropropene (HFO- 1234yf), wherein the method comprises two or more reaction steps, at least one of said reaction steps comprising the production of 1,3,3,3-tetrafluoropropene (HFO-1234ze) and/or one or more HFO-1234ze precursors from one or more HFO-1234yf precursors, wherein at least a portion of the HFO-1234ze is recovered.