cas 76-24-4, ALLOXANTIN | Articles data ｜lookchem

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76-24-4

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Reduction of Vicinal Tricarbonyl Compounds by Reduced Nicotinamide Adenine Dinucleotide Model and Electron-Transport Systems
The reduction of vicinal tricarbonyl compounds such as alloxan (A) and ninhydrin (NY) with 1-benzyl-1,4-dihydronicotinamide (BNAH; NADH model) was investigated.In the reduction of A with BNAH, the radical anion (A-.Py+) of A as the 1-benzyl-3-carbamoylpyridinium salt and the dialuric acid (D) was obtained by one-electron and two-electron reduction,respectively.Similarly,hydrindantin (HDT) and 2-hydroxy-1,3-indandione (HID) were also afforded in the reduction of NY with BNAH.Further,the reductions of alloxantin (AT) and HDT with BNAH were performed to give D and HID,respectively.The reduction of lipoic acid (LA) and viologens (V2+) with BNAH, which could not be reduced without A or NY, proceeded smoothly in their presence,and they proved to be useful as mediators for catalytic reduction of LA and V2+.
Endo, Takeshi,Okawara, Makoto
p. 2663 - 2666
(2007/10/02)

Reduction of alloxan in aqueous solution. I. By hydrogen sulfide.
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TIPSON,CRETCHER
p. 399 - 404
(2007/10/04)

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Chemical Properties

Melting Point: 250 °C
Boiling Point: 428.53°C (rough estimate)
Density: 2.036 g/cm³
Refractive Index: 1.6640 (estimate)
Merck: 283
PSA: 191.00000
LogP: -3.50420

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