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10025-99-7

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10025-99-7 Usage

Chemical Properties

Red/Brown, Tetragonal Crystals

Uses

Different sources of media describe the Uses of 10025-99-7 differently. You can refer to the following data:
1. In photography, in acid toning baths.
2. Potassium tetrachloroplatinate solution is used in the preparation of platinum (Pt) nanoparticles. Ligands like ammonia or triphenyl phosphine can able to replace the chloride ligands to afford various derivatives. The replacement by ammonia results in the preparation of cisplatin, which is used in the cancer treatment. Further, it is used as catalyst in the hydroarylation reaction.

General Description

Potassium tetrachloroplatinate(II) is a ruby red crystalline solid and can be prepared by reacting potassium hexachloroplatinate (IV) with cuprous chloride.

Flammability and Explosibility

Nonflammable

Safety Profile

Human poison by ingestion. Poison experimentally by intraperitoneal route. Corrosive to human skin by intradermal route. Mutation data reported. Human systemic effects: eosinophha, gastritis, renal function tests depressed. When heated to decomposition it emits toxic fumes of Cland K2O. Used as a catalyst for hydroformulations, photocatalysts, and dissociation of water. See also PLATINUM COMPOUNDS.

Purification Methods

It forms crystals from aqueous 0.75M HCl (20mL/g) between 100o and 0o. Wash them with ice-cold water and dry.

Check Digit Verification of cas no

The CAS Registry Mumber 10025-99-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,0,0,2 and 5 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 10025-99:
(7*1)+(6*0)+(5*0)+(4*2)+(3*5)+(2*9)+(1*9)=57
57 % 10 = 7
So 10025-99-7 is a valid CAS Registry Number.
InChI:InChI=1/4ClH.Pt/h4*1H;/q;;;;+2/p-4

10025-99-7 Well-known Company Product Price

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  • Detail
  • Alfa Aesar

  • (43946)  Potassium tetrachloroplatinate(II), Premion?, 99.99% (metals basis), Pt 46.4% min   

  • 10025-99-7

  • 1g

  • 1425.0CNY

  • Detail
  • Alfa Aesar

  • (43946)  Potassium tetrachloroplatinate(II), Premion?, 99.99% (metals basis), Pt 46.4% min   

  • 10025-99-7

  • 5g

  • 5642.0CNY

  • Detail
  • Alfa Aesar

  • (11048)  Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min   

  • 10025-99-7

  • 1g

  • 936.0CNY

  • Detail
  • Alfa Aesar

  • (11048)  Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min   

  • 10025-99-7

  • 5g

  • 4156.0CNY

  • Detail
  • Alfa Aesar

  • (11048)  Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min   

  • 10025-99-7

  • 25g

  • 30593.0CNY

  • Detail
  • Aldrich

  • (323411)  Potassiumtetrachloroplatinate(II)  99.99% trace metals basis

  • 10025-99-7

  • 323411-250MG

  • 455.13CNY

  • Detail
  • Aldrich

  • (323411)  Potassiumtetrachloroplatinate(II)  99.99% trace metals basis

  • 10025-99-7

  • 323411-1G

  • 1,354.86CNY

  • Detail
  • Aldrich

  • (323411)  Potassiumtetrachloroplatinate(II)  99.99% trace metals basis

  • 10025-99-7

  • 323411-5G

  • 6,739.20CNY

  • Detail
  • Aldrich

  • (520853)  Potassiumtetrachloroplatinate(II)  ≥99.9% trace metals basis

  • 10025-99-7

  • 520853-1G

  • 868.14CNY

  • Detail
  • Aldrich

  • (520853)  Potassiumtetrachloroplatinate(II)  ≥99.9% trace metals basis

  • 10025-99-7

  • 520853-5G

  • 3,849.30CNY

  • Detail
  • Aldrich

  • (520853)  Potassiumtetrachloroplatinate(II)  ≥99.9% trace metals basis

  • 10025-99-7

  • 520853-25G

  • 17,366.31CNY

  • Detail
  • Aldrich

  • (206075)  Potassiumtetrachloroplatinate(II)  98%

  • 10025-99-7

  • 206075-1G

  • 1,242.54CNY

  • Detail

10025-99-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name dipotassium tetrachloroplatinate

1.2 Other means of identification

Product number -
Other names Potassium platinochloride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:10025-99-7 SDS

10025-99-7Synthetic route

potassium hexachloropalatinate(IV)

potassium hexachloropalatinate(IV)

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With potassium oxalate In water byproducts: KCl; 24-36 h refluxing of K2C2O4 and aq. K2(PtCl6) suspn. till there is no pptn. on cooling, addn. of K2C2O4*H2O, boiling for few h, filtration, vapn. in water bath to 1/3-1/4 of volume, cooling, careful further vapn.;; recrystn. from water; pure K2(PtCl4);;90%
With hydrazinium sulfate In water hydrazine sulfate (2.06 mmol) added to Pt compd. (4.12 mmol) in water, mixt. brought to boiling and heated on water bath for 40 min; filtered, filtrate treated with acetone/Et2O (1/1), solid sepd. and washed with acetone and Et2O; elem. anal.;86%
With potassium bisulfite; potassium chloride In not given byproducts: potassium sulfate; warming KCl containing K2(PtCl6) with KHSO3 soln.;;
dihydrogen hexachloroplatinate

dihydrogen hexachloroplatinate

potassium chloride

potassium chloride

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With sulfur dioxide In water introduction of SO2 into aq. H2(PtCl6) soln. at water bath temp. till there is no pptn. with NH4Cl soln., cooling, addn. of KCl soln. with stirring, storage for 24 hours;; sucking off, washing with small amt. of H2O, washing with alcohol till there is no acidic reaction, drying in darkness at ambient temp.;;93%
With sulfur dioxide In water byproducts: KHSO4, KCl; introduction of SO2 into aq. H2(PtCl6) soln. at water bath temp. till there is no pptn. with NH4Cl soln., cooling, addn. of KCl soln. with stirring, storage for 24 hours;; sucking off, washing with small amt. of H2O, washing with alcohol till there is no acidic reaction, drying in darkness at ambient temp.; K2(PtCl4) is contaminated with KHSO4 and KCl;;67%
With sulfur dioxide In not given recrystn. from H2O and HCl soln., drying at 80-90°C to constant weight;;
With sulfur dioxide In not given H2(PtCl6) from purest Pt;; sulfate free Pt(Cl4);;
potassium amminetrichloroplatinate

potassium amminetrichloroplatinate

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride byproducts: NH4Cl; heating with HCl-soln. for a longer period of time;;
With HCl In hydrogenchloride byproducts: NH4Cl; heating with HCl-soln. for a longer period of time;;
In hydrogenchloride
potassium platinum(IV) oxosulfite*H2O

potassium platinum(IV) oxosulfite*H2O

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrogenchloride In not given byproducts: K2{PtCl6}, SO2;
With hydrogenchloride In not given byproducts: K2SO4; neutralization of alcalic K2(Pt(SO3)2O)*H2O soln. with HCl soln.;;
With HCl In not given byproducts: K2SO4; neutralization of alcalic K2(Pt(SO3)2O)*H2O soln. with HCl soln.;;
With HCl In not given byproducts: K2{PtCl6}, SO2;
K(1+)*Pt(NHCH(COO)C3H5(OH))Cl2(1-)=K[Pt(NHCH(COO)C3H5(OH))Cl2]

K(1+)*Pt(NHCH(COO)C3H5(OH))Cl2(1-)=K[Pt(NHCH(COO)C3H5(OH))Cl2]

cesium chloride

cesium chloride

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Cs(1+)*Pt(NHCH(COO)C3H5(OH))Cl2(1-)=Cs[Pt(NHCH(COO)C3H5(OH))Cl2]

Cs(1+)*Pt(NHCH(COO)C3H5(OH))Cl2(1-)=Cs[Pt(NHCH(COO)C3H5(OH))Cl2]

Conditions
ConditionsYield
With cesium hydroxide In water byproducts: KCl; Pt-complex soln. evapn. almost to dryness, water/alcohol mixt. (1:1) addn., ppt. (KCl and K2PtCl4) filtration off, CsCl (better CsCl/CsOH) aq. soln. addn. to filtrate, pptn.; ppt. filtration off, washing (cold water, alcohol), drying (110°C); elem. anal.;A n/a
B 52%
potassium bis(oxalato)platinate(II) dihydrate

potassium bis(oxalato)platinate(II) dihydrate

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrogenchloride In water decompn. of aq. soln. of yellow K2(Pt(C2O4)2)*2H2O by excessive aq. HCl soln.;;
With HCl In water decompn. of aq. soln. of yellow K2(Pt(C2O4)2)*2H2O by excessive aq. HCl soln.;;
K{Pt(acetonitrile)Cl3}
114490-06-1

K{Pt(acetonitrile)Cl3}

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride heating with HCl-soln.;;
With HCl In hydrogenchloride heating with HCl-soln.;;
hydrogen chloroplatinate(II)

hydrogen chloroplatinate(II)

potassium chloride

potassium chloride

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
In water addn. of KCl to purified aq. H2(PtCl4) soln. (heating H2(PtCl6*6H2O), solving formed PtCl2 in aq. HCl soln., purifn. over Ba(PtCl4)), vapn.;; drying over H2SO4 or at 100°C;;
In water addn. of KCl to aq. H2(PtCl4) soln. (heating H2(PtCl6)*6H2O), solving formed PtCl2 in aq. HCl soln.), vaporization;;
K{Ptaca2Cl}

K{Ptaca2Cl}

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrogenchloride In not given addn. of HCl-soln.;;
dihydrogen hexachloroplatinate(IV) hexahydrate

dihydrogen hexachloroplatinate(IV) hexahydrate

potassium chloride

potassium chloride

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With barium carbonate In water byproducts: BaSO4, K2{PtCl6}; exact neutralization of H2(PtCl6)*6H2O soln. with BaCO3, reduction with BaS2O6 in aq. soln., addn. of KCl, filtration, crystn.;;
potassium (η2-allyltrimethylsilane)trichloroplatinate(II)
56112-08-4

potassium (η2-allyltrimethylsilane)trichloroplatinate(II)

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

K{PtprCl3}
12075-59-1

K{PtprCl3}

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride; acetone byproducts: KCl; several drops of 6 N HCl adding to Pt complex soln., allowing to stand for 24 h, additional drop of 6 N HCl adding to complete the reaction, after 12 h ppt. collecting by centrifugation, washing with acetone, filtrate evapg.; purified by pptn. with Et2O, identified by elem. anal.;
2K(1+)*Pt(NH2CH2CH2SO3)2Cl2(2-)*5H2O=K2(Pt(NH2CH2CH2SO3)2Cl2)*5H2O

2K(1+)*Pt(NH2CH2CH2SO3)2Cl2(2-)*5H2O=K2(Pt(NH2CH2CH2SO3)2Cl2)*5H2O

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrochloric acid In water byproducts: taurine; dild. HCl (80°C, 2 h);
2K(1+)*[Pt(H2NC2H4SO3)2Cl2](2-)*2H2O=K2[Pt(H2NC2H4SO3)2Cl2]*2H2O

2K(1+)*[Pt(H2NC2H4SO3)2Cl2](2-)*2H2O=K2[Pt(H2NC2H4SO3)2Cl2]*2H2O

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrochloric acid In water byproducts: taurine; dild. acid (80°C, 2 h);
potassium platinum(II) chloride*xH2O=Kaliumplatin(II)-chlorid*xH2O

potassium platinum(II) chloride*xH2O=Kaliumplatin(II)-chlorid*xH2O

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; storage over H2SO4 or heating at 100°C;;
In neat (no solvent) byproducts: H2O; storage over H2SO4 or heating at 100°C;;
potassium hexachloropalatinate(IV)

potassium hexachloropalatinate(IV)

potassium chloride

potassium chloride

platinum
7440-06-4

platinum

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
Kinetics; 850°C, powdered platinum;
In melt dissolution of Pt in melt;;
In melt dissolution of Pt in melt;;
platinum(II)-oxide hydrate

platinum(II)-oxide hydrate

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
With hydrogenchloride byproducts: H2O;
potassium nitrite
7758-09-0

potassium nitrite

cis-potassium platinum(II) dinitrochloride=cis-Kaliumplatin(II)-dinitrochlorid

cis-potassium platinum(II) dinitrochloride=cis-Kaliumplatin(II)-dinitrochlorid

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
In water
potassium hexachloropalatinate(IV)

potassium hexachloropalatinate(IV)

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

trans-diamminetetrachloroplatinum(IV)
16893-05-3, 16893-06-4, 16949-90-9

trans-diamminetetrachloroplatinum(IV)

Conditions
ConditionsYield
In water heating with K2(PtCl6);;
potassium trichloro(nicotinic acid)platinate(II)

potassium trichloro(nicotinic acid)platinate(II)

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

B

cis-dichlorobis(nicotinic acid)platinum(II)

cis-dichlorobis(nicotinic acid)platinum(II)

Conditions
ConditionsYield
In neat (no solvent) heating to 155°C; treatment with water;
[pyrazolium]2[PtCl4]

[pyrazolium]2[PtCl4]

potassium hydroxide

potassium hydroxide

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
In neat (no solvent, solid phase) byproducts: C3H4N2; ground;A n/a
B 1%
potassium chloride

potassium chloride

chlorine
7782-50-5

chlorine

platinum
7440-06-4

platinum

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
In neat (no solvent) Kinetics; Chlorine bubbled through the melt.;
diacetonitriledichloridopalladium(II)
21264-32-4, 13869-38-0, 13869-42-6

diacetonitriledichloridopalladium(II)

potassium chloride

potassium chloride

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

K{Pt(acetonitrile)Cl3}
114490-06-1

K{Pt(acetonitrile)Cl3}

Conditions
ConditionsYield
In water react. of Pt-complex and KCl in water (molar ratio 1:3);
potassium chloride

potassium chloride

chlorine
7782-50-5

chlorine

platinum
7440-06-4

platinum

A

potassium hexachloropalatinate(IV)

potassium hexachloropalatinate(IV)

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Conditions
ConditionsYield
In neat (no solvent) Kinetics; mixt. of Pt and KCl charged into a quartz cell which is placed in a resistance furnace, when KCl melted, Cl2 is bubbled through the melt at a temp. of 800-1000°C; x-ray diffraction;
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

potassium iodide
7681-11-0

potassium iodide

potassium tetraiodoplatinate

potassium tetraiodoplatinate

Conditions
ConditionsYield
In water at 50℃; for 0.0833333h; Darkness;100%
In water at 30℃; for 0.5h;
In water for 0.5h;
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

triphenylphosphine
603-35-0

triphenylphosphine

cis-dichlorobis(triphenylphosphine)platinum(II)
10199-34-5, 14056-88-3, 15604-36-1

cis-dichlorobis(triphenylphosphine)platinum(II)

Conditions
ConditionsYield
Ar atmosphere; procedure described by Brune et al., Chem. Ber. 117 (1984) 2791-2802;100%
In ethanol; water stirred in darkness at room temp. for 24 h; ppt. washed (water, ethanol, diethyl ether), washed (CHCl3), ppt. collected, soln. stored in light, ppt. collected; elem. anal.;98%
In dichloromethane other Radiation; N2; ligand (0.0921 mmol) and K2PtCl4 (0.0721 mmol) in DCM, sealed, microwave irradaited at 145°C for 50 min; soln. layered (Et2O), recrystd. (CHCl3/heptane), filtered off, dried;93.2%
In ethanol; water an aq. soln. of K2(PtCl4) is shaken with a hot alcoholic soln. of P(C6H5)3;; washing with H2O, alcohol and ether;;
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

4,4'-diethoxy-2,2'-bipyridine
53094-09-0

4,4'-diethoxy-2,2'-bipyridine

dichloro(4,4'-diethoxy-2,2'-bipyridine)platinum
257278-08-3

dichloro(4,4'-diethoxy-2,2'-bipyridine)platinum

Conditions
ConditionsYield
In water reflux (75 min); filtration, washing (H2O), drying (vac.), recrystn. (satd. hot DMF soln.); elem. anal.;100%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

dichlorobis(dimethyl sulfoxide)platinum(II)

dichlorobis(dimethyl sulfoxide)platinum(II)

Conditions
ConditionsYield
In water for 2h;100%
In water91%
In water at 20℃;90%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

Sodium thiosulfate pentahydrate

Sodium thiosulfate pentahydrate

thiourea
17356-08-0

thiourea

{Ptth3S2O3}

{Ptth3S2O3}

Conditions
ConditionsYield
In water addn. of a soln. of thiourea to a soln.-mixture of K2(PtCl4) and Na2S2O3*5H2O in a small amount of H2O after storing approx. 2 h at room temperature; pptn.;;100%
In water addn. of a soln. of thiourea to a soln.-mixture of K2(PtCl4) and Na2S2O3*5H2O in a small amount of H2O after storing approx. 2 h at room temperature; pptn.;;100%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

bromine
7726-95-6

bromine

2K(1+)*PtCl4Br2(2-)=K2{PtCl4Br2}

2K(1+)*PtCl4Br2(2-)=K2{PtCl4Br2}

Conditions
ConditionsYield
With tetrabutyl-ammonium chloride In dichloromethane addn. (TBA)Cl to Pt-compd. in 6 N HCl, extn. into CH2Cl2, washing org. phase (H2O), drying (Na2SO4), evapn. of solvent, dissolving residue in acetone, pptn. of TBA-complex (addn. Et2O, cooling), dissolving (CH2Cl2),addn. of Br2 in CH2Cl2 (room temp.); immediate layering of the soln. with Et2O, crystn. on standing in a refrigerator, washing with Et2O and drying in vac., pptn. of the K-complex by addn. of K-trichloroacetate in MeOH to the TBA-complex dissolved in CH2Cl2;100%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

trisodium tris(3-sulfophenyl)phosphine
63995-70-0

trisodium tris(3-sulfophenyl)phosphine

[Pt(tris(3-sulfonatophenyl)phosphane sodium salt)3Cl]Cl

[Pt(tris(3-sulfonatophenyl)phosphane sodium salt)3Cl]Cl

Conditions
ConditionsYield
In water-d2 at 25℃; for 0.25h; Inert atmosphere;100%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

tris(4-methyl-3-sulfonatophenyl)phosphane sodium salt

tris(4-methyl-3-sulfonatophenyl)phosphane sodium salt

[Pt(tris(4-methyl-3-sulfonatophenyl)phosphane sodium salt)3Cl]Cl

[Pt(tris(4-methyl-3-sulfonatophenyl)phosphane sodium salt)3Cl]Cl

Conditions
ConditionsYield
In water-d2 at 25℃; for 0.25h; Inert atmosphere;100%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

2-(3-(3-(pyridin-2-yl)phenoxy)phenyl)pyridine

2-(3-(3-(pyridin-2-yl)phenoxy)phenyl)pyridine

C22H14N2OPt

C22H14N2OPt

Conditions
ConditionsYield
With tetrabutylammomium bromide In 2-ethoxy-ethanol for 72h; Reflux;100%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

([1-benzyl-3-methyl]imidazolyl-2-ene)silver(I) bromide

([1-benzyl-3-methyl]imidazolyl-2-ene)silver(I) bromide

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

cis-(1-methyl-3-benzylimidazol-2-ylidene)PtBr2(DMSO)

cis-(1-methyl-3-benzylimidazol-2-ylidene)PtBr2(DMSO)

Conditions
ConditionsYield
at 60℃; for 24h;100%
potassium cyanide

potassium cyanide

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

C110H189N41O20S

C110H189N41O20S

[Pt(dpyTSCL-sC18)(CN)]

[Pt(dpyTSCL-sC18)(CN)]

Conditions
ConditionsYield
In water at 20℃; for 1h;100%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

C110H189N41O20S

C110H189N41O20S

[Pt(dpyTSCL-sC18)Cl]

[Pt(dpyTSCL-sC18)Cl]

Conditions
ConditionsYield
In water at 20℃; for 2h;100%
3,5-bis[(2-methoxy)ethylaminomethyl]pyrazole dihydrochloride

3,5-bis[(2-methoxy)ethylaminomethyl]pyrazole dihydrochloride

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

potassium iodide
7681-11-0

potassium iodide

μ-iodo(μ-1,1'-[(1H-pyrazole-1-ido-3,5-diyl)bis(methylene)]bis(2-methoxyethylamino))diiododiplatinum(II)
925430-87-1

μ-iodo(μ-1,1'-[(1H-pyrazole-1-ido-3,5-diyl)bis(methylene)]bis(2-methoxyethylamino))diiododiplatinum(II)

Conditions
ConditionsYield
With sodium hydroxide In water to stirred aq. soln. K2PtCl4 in water KI was added, soln. ligand in water and NaOH were added dropwise, stirred dor 28 h at room temp.; ppt. was filtered, washed with water and dried at 60°C in high vac.; elem. anal.;99.7%
hydrogenchloride
7647-01-0

hydrogenchloride

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

5,5'-dimethyl-2,2'-bipyridine
1762-34-1

5,5'-dimethyl-2,2'-bipyridine

dichlorido(5,5'-dimethyl-2,2'-bipyridine)platinum(II)
54806-35-8

dichlorido(5,5'-dimethyl-2,2'-bipyridine)platinum(II)

Conditions
ConditionsYield
In water elem. anal.;99.6%
2-phenylpyridine
1008-89-5

2-phenylpyridine

potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

κ2(N,C(2))-(2-phenylpyridine)-κ1(N)-(2-phenylpyridine)chloroplatinum(II)

κ2(N,C(2))-(2-phenylpyridine)-κ1(N)-(2-phenylpyridine)chloroplatinum(II)

Conditions
ConditionsYield
In 2-ethoxy-ethanol; water other Radiation; 2-phenylpyridine (2.2 mmol) treated with K2PtCl4 (1 mmol) in degassed soln. (N2) of 2-ethoxyethanol/H2O (3:1, v/v); irradiated with microwave radiation (250 W, 1 min, max. temp. 110°C); cooled; filtered off; recrystd. from CH2Cl2/EtOH; elem. anal.;99%
In 2-ethoxy-ethanol; water aq. degassed soln. of K2PtCl4 (1.2 mmol) (3 ml) added to degassed soln. of 2-phenylpyridine (2.4 mmol) in 2-ethoxyethanol (9 ml) under N2 (stirring); heated (80°C) overnight; cooled in ice bath; distd. H2O added; ppt. filtered off; washed with cold EtOH; dried (vac.); crystd. from CH2Cl2/EtOH;95%
In acetic acid suspn. ligand and K2(PtCl4) in AcOH was heated at 75°C for 15 h; soln. was cooled to room temp., evapd., residue was dissolved in CH2Cl2,washed with 2.5 M HCl, water, dried over MgSO4, soln. was concd., Et2O was added, ppt. was collected by filtration; elem. anal.;82%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

18-crown-6 ether
17455-13-9

18-crown-6 ether

(18-crown-6)potassium-tetrachloroplatinate(II)

(18-crown-6)potassium-tetrachloroplatinate(II)

Conditions
ConditionsYield
In dichloromethane Ar-atmosphere; strirring to dissoln. (2-3 h); concn. (vac.), pptn. on hexane addn., washing (hexane), drying (vac.); elem. anal.;99%
In dichloromethane excess of ligand, stirring (2 h, room temp.); concn. (vac.), layering (Et2O), filtn., washing (Et2O), drying (vac.); elem. anal.;99%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

(phenylthio)acetic acid sodium salt
1641-35-6

(phenylthio)acetic acid sodium salt

{Ptphthg2}

{Ptphthg2}

Conditions
ConditionsYield
In not given formation on mixing of hot solns. of K2(PtCl4) and Na-(phenylthio)acetate;;99%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

2,2'-Bipyrimidine
34671-83-5

2,2'-Bipyrimidine

dichloro-(2,2'-bipyrimidyl) platinum(II)
68976-09-0

dichloro-(2,2'-bipyrimidyl) platinum(II)

Conditions
ConditionsYield
With air In water at 20℃; Inert atmosphere;99%
In water at 20℃; for 12h;92%
In water at 20℃;89%
With 18-crown-6 ether In water ligand dissolved in min. amt. of H2O over 15 min; added to soln. of K2PtCl4 and 18-crown-6 in H2O; filtered; ppt. washed with min. amt. of cold H2O; dried at 100°C for 5-6 h; elem. anal.;60%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

tetramethylammonium tetrachloroplatinate(II)

tetramethylammonium tetrachloroplatinate(II)

Conditions
ConditionsYield
In water99%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

tetramethylammonium tetrachloroplatinate(II)

tetramethylammonium tetrachloroplatinate(II)

Conditions
ConditionsYield
In water passing K-salt through cation exchanger (Me4N-form);99%
potassium tetrachloroplatinate(II)
10025-99-7

potassium tetrachloroplatinate(II)

nicotinamide
98-92-0

nicotinamide

Pt(C5H4NCONH2)4(2+)*2Cl(1-) = [Pt(C5H4NCONH2)4]Cl2

Pt(C5H4NCONH2)4(2+)*2Cl(1-) = [Pt(C5H4NCONH2)4]Cl2

Conditions
ConditionsYield
In water99%

10025-99-7Relevant articles and documents

Synthesis and some physicochemical properties of the aqua complexes of covalent conjugates of platinum(II) with octacarboxy-substituted cobalt phthalocyanine

Dolotova,Kaliya

, p. 111 - 115 (2007)

Aqua complexes of the covalent conjugates of octacarboxy-substituted cobalt phthalocyanine with platinum, which are of interest as components of a catalytic system for cancer therapy, were synthesized. For the tetraplatinated product, elemental analysis data and the data from electronic absorption, IR, and mass spectra are given. Nauka/Interperiodica 2007.

Crystal structure, DNA-binding ability and cytotoxic activity of platinum(II) 2,2′-dipyridylamine complexes

Tu, Chao,Wu, Xuefeng,Liu, Qin,Wang, Xiaoyong,Xu, Qiang,Guo, Zijian

, p. 95 - 102 (2004)

Two platinum(II) complexes, [Pt(dpa)Cl2] (1) and [Pt(dpa)CBDCA] (2), where DPA=2,2′-dipyridylamine and CBDCA=1,1-cyclobutanedicarboxylate, were synthesized and characterized by elemental analysis, IR spectroscopy, ES-MS and X-ray diffraction. Intermolecular hydrogen bonds were observed in both complexes (N-H?Cl for complex 1 and N-H?O for complex 2), which may play a role in formation of hydrogen bonding in metal-DNA adducts. Complex 2 adopts a boat conformation so that the cyclobutane ring and bipyridyl groups are on the same side of the platinum square. The interactions of complexes 1 and 2 with DNA were studied by UV and Fluorescence Spectroscopy, which indicated that both complexes could interact with DNA through groove binding or intercalation. The in vitro cytotoxic activity against melanoma B16-BL6 cells and human Jurkat T-cells was also reported.

Coordination chemistry of platinum and palladium in the solid-state: Synthesis of imidazole and pyrazole complexes

Adams, Christopher J.,Haddow, Mairi F.,Hughes, Robert J.I.,Kurawa, Mukhtar A.,Orpen, A. Guy

, p. 3714 - 3724 (2010/06/17)

Solid-state reactions of palladium(ii) and platinum(ii) chloride complexes with imidazole (Him) and pyrazole (Hpz) or their hydrochloride salts are shown to produce metal complex salts and coordination compounds. Thus, K 2[MCl4] or MCl2 can be ground with imidazolium chloride ([H2im]Cl) to produce the salts [H2im] 2[MCl4] (M = Pd, 1; Pt, 5), which can then be dehydrochlorinated in the solid state to produce the coordination compounds trans-[PdCl2(Him)2] 3 or cis-[PtCl2(Him) 2] 6. The complex cis-[PdCl2(Him)2] 2 is produced when Pd(OAc)2 is ground with [H2im]Cl. Reaction of platinum chloride reagents with imidazole (Him) also produces cis-[PtCl 2(Him)2] 6, but reaction of imidazole with analogous palladium chloride reagents first produces [Pd(Him)4]Cl24 which then slowly converts to trans-[PdCl2(Him)2] 3. Grinding pyrazolium chloride with K2[MCl4] produces [H2pz]2[MCl4] (M = Pd, 7; Pt, 10), which may also be dehydrochlorinated in the solid state to produce the coordination compounds trans-[PdCl2(Hpz)2] 8 or cis-[PtCl 2(Hpz)2] 11. Grinding K2[PdCl4] or PdCl2 with pyrazole gives [Pd(Hpz)4]Cl29, which is then slowly converted into trans-[PdCl2(Hpz)2] 8. Grinding PtCl2 with Hpz generates [Pt(Hpz)4]Cl 212, but using K2PtCl4 as the metal source does not generate the same product. The single-crystal structures of 8, a new polymorph of 11 and [H2pz]2[PtCl6] ·2H2O (isolated as a decomposition product) are reported for the first time, and the structures of 5 and 10 have been solved ab ibitio from XRPD data.

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