13289-97-9 Usage
Description
BORANE-N,N-DIETHYLANILINE COMPLEX is a clear colorless to amber liquid that serves as a versatile reagent in various chemical reactions and synthesis processes. It is known for its ability to selectively reduce prochiral enone intermediates, borylate aryl halides, and reduce a wide range of compounds, including ketones, acids, esters, amides, and nitriles. Additionally, it plays a crucial role in the synthesis of various compounds, such as chromanol derivatives, allyl alcohols, and pinacolboranes.
Uses
Used in Pharmaceutical Industry:
BORANE-N,N-DIETHYLANILINE COMPLEX is used as a reactant for the diastereoselective reduction of prochiral enone intermediates, which are essential in the synthesis of various pharmaceutical compounds. Its ability to selectively reduce these intermediates contributes to the development of more effective and targeted drugs.
Used in Chemical Synthesis:
BORANE-N,N-DIETHYLANILINE COMPLEX is used as a reactant for the borylation of aryl halides, a process that is crucial in the synthesis of various organic compounds. This application is particularly important in the development of new materials and chemicals with specific properties and applications.
Used in Enantioselective Reductions:
BORANE-N,N-DIETHYLANILINE COMPLEX is used as a reactant in investigations of borane source on enantioselectivity in enantiopure oxazaborolidine-catalyzed asymmetric borane reduction of ketones. This application is vital in the development of enantiomerically pure compounds, which are essential in various industries, including pharmaceuticals and agrochemicals.
Used in the Synthesis of Chromanol Derivatives:
BORANE-N,N-DIETHYLANILINE COMPLEX is used as a reactant for the synthesis of chromanol derivatives, which serve as CETP inhibitors for the treatment of cardiovascular disease. Its role in the synthesis of these compounds contributes to the development of more effective treatments for heart-related conditions.
Used in the Synthesis of Allylic Alcohols:
BORANE-N,N-DIETHYLANILINE COMPLEX is used as a reactant for the synthesis of allyl alcohols via enantioselective reductions. These compounds are essential in the production of various chemicals and materials, including pharmaceuticals, fragrances, and agrochemicals.
Used in the Synthesis of Pinacolboranes:
BORANE-N,N-DIETHYLANILINE COMPLEX is used as a reactant for the synthesis of pinacolboranes, which are crucial in the one-pot synthesis of unsymmetrical biaryls. These biaryls are important building blocks in the development of various organic compounds and materials with specific properties and applications.
Check Digit Verification of cas no
The CAS Registry Mumber 13289-97-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,2,8 and 9 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 13289-97:
(7*1)+(6*3)+(5*2)+(4*8)+(3*9)+(2*9)+(1*7)=119
119 % 10 = 9
So 13289-97-9 is a valid CAS Registry Number.
InChI:InChI=1/C10H15N/c1-3-11(4-2)10-8-6-5-7-9-10/h5-9H,3-4H2,1-2H3/p+1
13289-97-9Relevant articles and documents
Reductive dechlorination of BCl3 for efficient ammonia borane regeneration
Tan, Yingbin,Zhang, Lijun,Chen, Xiaowei,Yu, Xuebin
supporting information, p. 753 - 757 (2015/02/19)
This paper reports a complete ammonia borane (AB) regeneration process in which Bu3SnH was utilized as a reductant for the reductive dechlorination of BCl3, and Et2PhN was selected as a 'helper ligand' to generate Et2PhN·BH3, which gives rise to a high yield of AB by a base-exchange reaction at ambient temperature.
A SIMPLE CONVENIENT METHOD FOR THE GENERATION OF DIBORANE FROM NaBH4 AND I2
Narayana, C.,Periasamy, M.
, p. 145 - 148 (2007/10/02)
Treatment of NaBH4 with I2 in diglyme yields diborane which can be utilized conveniently for the preparation of a borane-N,N-diethylaniline complex and other borane-Lewis base complexes.
