13674-84-5 Usage
Chemical Properties
Tris(2-chloro-1-methylethyl) phosphate is clear colorless oily liquid with high water solubility and low lipophilicity (as indicated by logKOW). This substance ismanufactured as a reactionmixture, which contains four isomers. It is the primary isomer in the mixture at 50–85% weight/weight (w/w), followed by bis(1- chloro-2-propyl)-2-chloropropyl phosphate [15–40% (w/w); CASRN: 76025-08-6], bis(2-chloropropyl)-1-chloro-2-propyl phosphate [<15% (w/w); CASRN: 76649-15-5], and tris(2- chloropropyl) phosphate [<1% (w/w); CASRN: 6145-73-9] (EURAR, 2008).
Uses
Different sources of media describe the Uses of 13674-84-5 differently. You can refer to the following data:
1. Tris(1-chloro-2-propyl) Phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA and phenolics and epoxy resin.
2. Tris(1-chloro-2-propyl) Phosphate is a flame retardant of low hydrolytic stability, used in polyurethane (PU) rigid and flexible foam, PVC, EVA, phenolics and epoxy resin.
General Description
Clear colorless viscous liquid. Tris(2-chloroisopropyl) Phosphate(TCPP), mixture of isomers is suitable for use in environmental and food residue analysis. It is a mixture of isomers, composition may vary, typical composition: main isomer tris(1-chloro-2-propyl) phosphate 66%, minor components: bis(1-chloro-2-propyl) (2-chloropropyl) phosphate and (1-chloro-2-propyl) bis(2-chloropropyl) phosphate.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Phosphoric acid tris(2-chloro-1-methylethyl) ester may hydrolyze under acidic or alkaline conditions.
Health Hazard
ACUTE/CHRONIC HAZARDS: When heated to decomposition Phosphoric acid tris(2-chloro-1-methylethyl) ester emits very toxic fumes.
Fire Hazard
Phosphoric acid tris(2-chloro-1-methylethyl) ester is probably combustible.
Check Digit Verification of cas no
The CAS Registry Mumber 13674-84-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,6,7 and 4 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 13674-84:
(7*1)+(6*3)+(5*6)+(4*7)+(3*4)+(2*8)+(1*4)=115
115 % 10 = 5
So 13674-84-5 is a valid CAS Registry Number.
InChI:InChI=1/C9H18Cl3O4P/c1-7(4-10)14-17(13,15-8(2)5-11)16-9(3)6-12/h7-9H,4-6H2,1-3H3
13674-84-5Relevant articles and documents
A three - (2 - chloroisopropyl) phosphate ester preparation method
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Paragraph 0031-0038, (2017/08/25)
The invention relates to a preparation method of tri(2-chloroisopropyl)phosphate (TCPP). The TCPP is prepared by reacting dehydrated epoxypropane and phosphorus oxychloride. The invention particularly relates to a preparation method of TCPP with low TCPP ether impurity content and high product yield. The method comprises the following steps: before adding the epoxypropane to react, adding a dehydrating agent into the epoxypropane or passing the epoxypropane through a dehydrating-agent-filled dehydration tower to perform deep dehydration on the epoxypropane until the water content in the epoxypropane is less than 100 ppm, and reacting with the phosphorus oxychloride to obtain the TCPP. The TCPP ether content in the TCPP product is less than 1000 ppm. Compared with the TCPP obtained in the prior art, the method greatly lowers the TCPP ether content in the product and enhances the product yield.
Preparation of phosphorus-containing propoxylation products by using aluminium trichloride
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Page/Page column 3, (2008/12/07)
The invention describes a process for preparing propoxylated, phosphorus-containing compounds using aluminium chloride catalyst.
