1623-99-0

Basic information

• Product Name: phenylsodium25%soln.inheptane
• Synonyms: phenylsodium25%soln.inheptane;SodiuM, phenyl-(6CI,8CI,9CI)
• CAS NO: 1623-99-0
• Molecular Formula: C₆H₅*Na
• Molecular Weight: 100.10
• Mol File: 1623-99-0.mol

Chemical Properties

• Melting Point: 105 °C (decomp)
• Appearance: /
• CAS DataBase Reference: phenylsodium25%soln.inheptane(CAS DataBase Reference)
• NIST Chemistry Reference: phenylsodium25%soln.inheptane(1623-99-0)
• EPA Substance Registry System: phenylsodium25%soln.inheptane(1623-99-0)

Safety Data

• Hazardous Substances Data: 1623-99-0(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
Phenylsodium 25% solution in heptane is used as a strong base for facilitating various organic reactions, such as deprotonations, coupling reactions, and the synthesis of complex organic molecules. Its high reactivity allows for the formation of new chemical bonds and the modification of existing ones.
Used in Laboratory Research:
In the field of academic research, phenylsodium 25% solution in heptane is employed as a reagent for studying the properties and behavior of various organic compounds. It aids in understanding reaction mechanisms and exploring new synthetic pathways.
Used in Industrial Chemical Processes:
Phenylsodium 25% solution in heptane is utilized in the chemical industry for large-scale organic transformations, where a strong base is required. Its use can lead to increased efficiency and yield in the production of various chemicals and pharmaceuticals.
Used in the Production of Specialty Chemicals:
phenylsodium25%soln.inheptane is also employed in the synthesis of specialty chemicals, such as pharmaceutical intermediates, agrochemicals, and advanced materials, where specific reaction conditions and a strong base are needed to achieve desired outcomes.

Upstream product

• 108-86-1 bromobenzene 
• 1822-71-5 n-pentylsodium 
• 108-90-7 chlorobenzene 
• 101-84-8 diphenylether 
• 90-43-7 2-Phenylphenol 
• 587-85-9 diphenylmercury(II) 
• 18356-02-0 methyl sodium 
• 71-43-2 benzene 
• 676-54-0 ethyl sodium 
• 108-88-3 toluene 
• 3525-44-8 butylsodium 
• 595-89-1 Tetraphenyllead 
• 90-12-0 1-Methylnaphthalene 
• 7440-23-5 sodium 

Downstream Products

• 60-12-8 2-phenylethanol 
• 855638-82-3 4-benzyl-1-methyl-piperidine-4-carbonitrile 
• 92040-00-1 (1-methylpiperidin-4-yl)(phenyl)methanone 
• 112864-70-7 4-cyano-1-methyl-quinuclidinium; chloride 
• 100-41-4 ethylbenzene 
• 74-85-1 ethene 
• 71-43-2 benzene 
• 217-59-4 triphenylene 
• 76-84-6 triphenylmethyl alcohol 
• 19813-37-7 (1-phenyl-1H-tetrazol-5-yl)-acetic acid 
• 2432-11-3 (1,1';3',1''-terphenyl)-2'-ol 
• 90-43-7 2-Phenylphenol 
• 41694-77-3 6-phenyl-7H-benzo[de]anthracen-7-one 
• 99180-47-9 2-(1-cyclohexyl-1H-tetrazol-5-yl)-propionic acid 

Relevant articles and documents

Method of preparation of methyl-benzyl-ketone

A process for producing phenylacetic acid is provided. The process includes combining sodium, chlorobenzene, toluene, and a catalyst to form a suspension. This suspension is mixed to form phenylsodium. Upon boiling, the suspension forms benzylsodium. The suspension is then carbonized and acidified to form phenylacetic acid.

Method for producing alkyl-bridged ligand systems and transition metal compounds

The invention relates to a method for producing highly substituted alkyl-bridged ligand systems on the basis of indene derivatives and transition metal compounds. Said alkyl-bridged ligand systems can be obtained in high yields using this method.

Process for the preparation of benzyl-metal compounds and process for the preparation of 4-phenyl-1-butenes by the use of the same

There is disclosed a method of preparing benzyl metal compounds represented by general formula (2), comprising reacting a phenyl metal compound represented by general formula (1) with toluene, in the presence of a catalytic amount of amine. According to this method, benzyl metal compounds can be prepared at a high yield, and in an industrially advantageous manner. Further, there is also disclosed a method of preparing 4-phenyl-1-butenes, comprising reacting the benzyl metal compound obtained in the method, with an allyl halide. STR1 wherein M represents an alkali metal, STR2 wherein M has the same meaning as the above.

Tetrahydroquinoline derivatives

The invention relates to new tetrahydroquinoline derivatives which are intermediates useful in the preparation of anti-ulcer agents. The new derivatives have formula (I) STR1 wherein M is sodium, potassium or lithium, R1, R2, R3, R4, R5 and R6 are the same or different and represent hydrogen, or a lower alkyl, or a phenyl radical, and any of R4, R5 and R6 may be a gem-di-lower alkyl radical.

Alkali metal-containing, organometallic products

An alkali metal-containing, organometallic product, which is hydrocarbon-soluble, is prepared by reacting an organo-alkali metal reactant in which the alkali metal atom is bonded to a carbon atom, e.g. cyclohexyl-lithium, with a di(organooxy)-alkaline earth metal reactant, e.g. di-n-butoxy-magnesium, in an organic solvent at about -20° to +120°C. The organo-alkali metal reactant can be prepared by reacting an organo halide with an alkali metal, and this can be done in situ, i.e. in the presence of the di(organooxy)-alkaline earth metal reactant. The organometallic product has approximately the same chemical reactivity as the organo-alkali metal reactant from which it is prepared, but is more soluble in hydrocarbon solvents.