4316-58-9

Basic information

• Product Name: Tris(4-bromophenyl)amine
• Synonyms: TRIS(4-BROMOPHENYL)AMINE;TRIS(4-BROMOPHENYL)AMIN;4,4',4"-Tribromotriphenylamine;TRI(4-BROMOPHENYL)AMINE;4,4',4''-Nitrilotris(1-bromobenzene);N,N-Bis(4-bromophenyl)-4-bromoaniline;4-bromo-N,N-bis(4-bromophenyl)aniline;4-broManyl-N,N-bis(4-broMophenyl)aniline
• CAS NO: 4316-58-9
• Molecular Formula: C₁₈H₁₂Br₃N
• Molecular Weight: 482.01
• EINECS: 1592732-453-0
• Product Categories: Electronic Chemicals;Acid Anhydrides, etc. (Reagents for Conducting Polymer Research);Fluorenes, etc. (reagent for high-performance polymer research);Functional Materials;Reagent for High-Performance Polymer Research;Reagents for Conducting Polymer Research;White to light yellow crystalline powder;White powder;Amines;C11 to C38;Nitrogen Compounds
• Mol File: 4316-58-9.mol

Chemical Properties

• Melting Point: 141-143 °C(lit.)
• Boiling Point: 514.9 °C at 760 mmHg
• Flash Point: 100°C
• Appearance: pale green powder
• Density: 1.79 g/cm³
• Vapor Pressure: 1.03E-10mmHg at 25°C
• Refractive Index: 1.692
• Storage Temp.: Refrigerator
• Solubility: Soluble in toluene.
• PKA: -4.91±0.50(Predicted)
• Stability: Stable. Incompatible with strong oxidizing agents.
• CAS DataBase Reference: Tris(4-bromophenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: Tris(4-bromophenyl)amine(4316-58-9)
• EPA Substance Registry System: Tris(4-bromophenyl)amine(4316-58-9)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• WGK Germany: 3
• Hazardous Substances Data: 4316-58-9(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
Tris(4-bromophenyl)amine is used as a key intermediate in the synthesis of porous luminescent covalent-organic polymers (COPs). Its unique structure and chemical properties make it a valuable component in the development of advanced materials with potential applications in various industries.
Used in Material Science:
In the Material Science industry, Tris(4-bromophenyl)amine is used as a building block for the creation of novel materials with specific properties. Its incorporation into COPs can lead to the development of materials with enhanced luminescence, which can be utilized in various applications such as sensors, optoelectronics, and other advanced technologies.
Used in Pharmaceutical Research:
Due to its unique chemical structure, Tris(4-bromophenyl)amine may also find applications in the pharmaceutical industry as a starting material for the development of new drugs or drug candidates. Its potential interactions with biological targets can be explored for the treatment of various diseases and conditions.

InChI:InChI=1/C18H12Br3N/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

Upstream product

• 603-34-9 N,N-diphenylaminobenzene 
• 3310-62-1 2,3-diazabicyclo[2.2.2]oct-2-ene 
• 78065-12-0 tris(4-bromophenyl)ammoniumyl hexafluoroantimonate 
• 3282-32-4 2-diazo-acetophenone 
• 71-50-1 acetate 
• 10442-39-4 tetra-n-butylammonium cyanide 
• 10534-59-5 tetrabutylammonium acetate 
• 83026-08-8 Caprinsaeure-4-methoxybenzylester 
• 83026-07-7 Decanoic acid 2,4-dimethoxy-benzyl ester 
• 108-88-3 toluene 
• 589-87-7 1,4-bromoiodobenzene 
• 106-40-1 4-bromo-aniline 
• 34283-63-1 tetrabutylammonium pelargonate 
• 51012-12-5 Tetrabutylammonium hydrogen diacetate 

Downstream Products

• 135761-35-2 tris<4-trimethylsilyl)phenyl>amine 
• 135761-42-1 tris(4-pentafluoroethylphenyl)amine 
• 118996-38-6 4,4’,4’’-tricarboxyltriphenylamine 
• 2229-07-4 methyl radical 
• 124-38-9 carbon dioxide 
• 91-20-3 naphthalene 
• 103273-57-0 trans-2,3-Dibrom-1,2,3,4-tetrahydronaphthalin 
• 134567-86-5 trans-2-Brom-3-chlor-1,2,3,4-tetrahydronaphthalin 
• 113664-28-1 4-cyano-4′,4′′-dibromotriphenylamine 
• 113678-54-9 (2-cyano-4-bromophenyl)-bis(4-bromophenyl)amine 
• 105864-92-4 (2-acetoxy-4-bromophenyl)-bis(4-bromophenyl)amine 
• 5489-72-5 Tris(2,4-dibromophenyl)amine 
• 73087-83-9 3,6-dibromo-9-(4-bromophenyl)-9H-carbazole 
• 67974-40-7 tris(4-bromophenyl)ammoniumyl hexafluorophosphate 

Relevant articles and documents

Donor-acceptor star-shaped conjugated macroelectrolytes: Synthesis, light-harvesting properties, and self-assembly-induced f?rster resonance energy transfer

A novel series of donor-acceptor star-shaped conjugated macroelectrolytes (CMEs), denoted as 4FTs, including anionic carboxylic acid sodium groups (4FNaT), neutral diethanolamine groups (4FNOHT), and cationic ammonium groups (4FNBrT), were designed, synth

Enhanced Electron Transfer Reactivity of a Nonheme Iron(IV)-Imido Complex as Compared to the Iron(IV)-Oxo Analogue

Reactions of N,N-dimethylaniline (DMA) with nonheme iron(IV)-oxo and iron(IV)-tosylimido complexes occur via different mechanisms, such as an N-demethylation of DMA by a nonheme iron(IV)-oxo complex or an electron transfer dimerization of DMA by a nonheme iron(IV)-tosylimido complex. The change in the reaction mechanism results from the greatly enhanced electron transfer reactivity of the iron(IV)-tosylimido complex, such as the much more positive one-electron reduction potential and the smaller reorganization energy during electron transfer, as compared to the electron transfer properties of the corresponding iron(IV)-oxo complex.

One-pot synthesis of star-shaped conjugated oligomers based on 3-hexylthiophene, pyrene and triphenylamine as TNT chemosensors

Star-shaped conjugated oligomer T3HTP containing pyrene, 3-hexylthiophene and triphenylamine, has been successfully synthesized via a simple one-pot sequential direct arylation process. The chemical structure and optical properties of T3HTP oligomer were

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This paper describes the synthesis of a triphenylamine-substituted alternating conjugated polyfluorene (PFAD) containing a pendant terminal di(2-picolyl)amine (DPA) group through the Heck coupling reaction. We examined the effect of DPA units on the senso

Photochemical Co-Oxidation of Sulfides and Phosphines with Tris(p-bromophenyl)amine. A Mechanistic Study

The photochemistry of tris(p-bromophenyl)amine was investigated in a nitrogen- and oxygen-flushed solution under laser flash photolysis conditions. The detected intermediates were the corresponding amine radical cation ("Magic Blue") and the N-phenyl-4a,4b-dihydrocarbazole radical cation that, under an oxygen atmosphere, is converted to the corresponding hydroperoxyl radical. The role of the last species was supported by the smooth co-oxidation of sulfides to sulfoxides. On the other hand, co-oxidation of nucleophilic triarylphosphines to triarylphosphine oxides arose from an electron transfer between the photogenerated "Magic Blue" and phosphine that prevented the amine cyclization. In this case, intermediate Ar3POO?+ was found to play a key role in phosphine oxide formation.

Synthesis and optoelectronic properties of thermally cross-linkable hole-transporting poly(fluorene-co-triphenylamine)

This paper describes the synthesis of a new thermally cross-linkable hole-transporting poly(fluorene-co-triphenylamine) (PFTV) by Suzuki coupling reaction and its application in polymer light-emitting diodes (PLEDs). The characteristics of PFTV were analy

Minimization of Carrier Losses for Efficient Perovskite Solar Cells through Structural Modification of Triphenylamine Derivatives

Three hole transport materials (HTMs) based on a substituted triphenylamine moiety have been synthesized and successfully employed in triple-cation mixed-halide PSCs, reaching efficiencies of 19.4 %. The efficiencies, comparable to those obtained using spiro-OMeTAD, point them out as promising candidates for easily attainable and cost-effective alternatives for PSCs, given their facile synthesis from commercially available materials. Interestingly, although all these HTMs show similar chemical and physical properties, they provide different carrier recombination kinetics. Our results demonstrate that is feasible through the molecular design of the HTM to minimize carrier losses and, thus, increase the solar cell efficiencies.

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