Welcome to LookChem.com Sign In|Join Free

Cas Database

542-59-6

542-59-6

Identification

Synonyms:1,2-Ethanediol,monoacetate (9CI); Ethylene glycol, monoacetate (7CI,8CI); 2-Acetoxyethanol;2-Hydroxyethyl acetate; Ethylenediol monoacetate; Glycol monoacetate;Monoacetyl ethylene glycol; NSC 9234; b-Hydroxyethyl acetate

Post Buying Request Now
Entrust LookChem procurement to find high-quality suppliers faster

Safety information and MSDS view more

  • Hazard Codes:T

  • Signal Word:Danger

  • Hazard Statement:H318 Causes serious eye damage

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician. SYMPTOMS: This compound may cause eye irritation. ACUTE/CHRONIC HAZARDS: When heated to decomposition this compound emits acrid smoke and fumes.

  • Fire-fighting measures: Suitable extinguishing media Fires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. This chemical is combustible. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:TCI Chemical
  • Product Description:2-Hydroxyethyl Acetate >60.0%(GC)
  • Packaging:25mL
  • Price:$ 76
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:TCI Chemical
  • Product Description:2-Hydroxyethyl Acetate >60.0%(GC)
  • Packaging:500mL
  • Price:$ 343
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Labseeker
  • Product Description:2-acetoxyethanol 50
  • Packaging:500g
  • Price:$ 200
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:Crysdot
  • Product Description:2-Hydroxyethyl Acetate 95+%
  • Packaging:500g
  • Price:$ 515
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:2-HYDROXY ETHYL ACETATE 95.00%
  • Packaging:25G
  • Price:$ 640
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:2-HYDROXY ETHYL ACETATE 95.00%
  • Packaging:1G
  • Price:$ 409.6
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:AK Scientific
  • Product Description:2-Hydroxyethyl Acetate
  • Packaging:25g
  • Price:$ 81
  • Delivery:In stock
  • Buy Now
  • Manufacture/Brand:AK Scientific
  • Product Description:2-Hydroxyethyl Acetate
  • Packaging:1g
  • Price:$ 14
  • Delivery:In stock
  • Buy Now

Relevant articles and documentsAll total 64 Articles be found

Evidence for the HOOO- anion in the ozonation of 1,3-dioxolanes: Hemiortho esters as the primary products

Plesnicar, Bozo,Cerkovnik, Janez,Tuttle, Tell,Kraka, Elfi,Cremer, Dieter

, p. 11260 - 11261 (2002)

Low-temperature ozonation (-78 °C) of 2-methyl-1,3-dioxolane (1a) in acetone-d6, methyl acetate, and tert-butyl methyl ether produced both the corresponding acetal hydrotrioxide (3a, ROOOH) and the hemiortho ester (2a, ROH) in molar ratio 1:5. Both intermediates were fully characterized by 1H, 13C, and 17O NMR spectroscopy, and they both decomposed to the corresponding hydroxy ester at higher temperatures. The mechanism involving the HOOO- anion formed by the abstraction of the hydride ion by ozone to form an ion pair, R+ -OOOH, with its subsequent collapse to either the corresponding hemiortho ester (ROH) or the acetal hydrotrioxide (ROOOH) was proposed. This mechanism is supported by the PISA/B3LYP/6-311++G(3df,3pd) calculations. Copyright

The Mechanism of Formation of Ethylene Glycol Monoacetate from Ethylene in the System MeCO2H + LiNO3 + Pd(OAc)2

Kuznetsova, Nina I.,Likholobov, Vladimir A.,Fedotov, Martin A.,Yermakov, Yurii I.

, p. 973 - 974 (1982)

A 17O n.m.r. study has shown that formation of ethylene glycol monoacetate from ethylene in acetic acid solution containing LiNO3 and Pd(OAc)2 is accompanied by oxygen atom transfer from the oxidant to the carbonyl group of the product.

MECHANISM FOR FORMATION OF ETHYLENE GLYCOL MONOACETATE FROM ETHYLENE IN ACETIC ACID SOLUTION CONTAINING LITHIUM NITRATE AND PALLADIUM ACETATE

Kuznetsova, N. I.,Likholobov, V. A.,Fedotov, M. A.,Ermakov, Yu. I.

, p. 2475 - 2477 (1982)

-

Poly(Ethylene Glycol) Dimethacrylates with Cleavable Ketal Sites: Precursors for Cleavable PEG-Hydrogels

Pohlit, Hannah,Leibig, Daniel,Frey, Holger

, (2017)

The authors introduce poly(ethylene glycol) (PEG) based macromonomers containing acid-labile ketal moieties as well as terminal methacrylate units that are amenable to radical polymerization. The synthesis of PEGs of different molecular weights (ranging from 2000 to 13 000 g mol?1 with polydispersities 1H NMR kinetic studies in deuterated phosphate buffer. Hydrogels containing 0, 5, or 10 wt% of PEG-ketal-DMA and 100, 95, or 90 wt% of PEG-DMA, respectively, are synthesized and disintegration of the gels is investigated in buffer at different pH values. Visible disintegration of the gels appears at pH 5 for hydrogels containing PEG-ketal-DMA, whereas no visible degradation is observed at all at neutral pH or for PEG hydrogels without PEG-ketal-DMA. (Figure presented.).

Catalytic Hydrogenation of Thioesters, Thiocarbamates, and Thioamides

Luo, Jie,Rauch, Michael,Avram, Liat,Ben-David, Yehoshoa,Milstein, David

supporting information, p. 21628 - 21633 (2021/01/11)

Direct hydrogenation of thioesters with H2 provides a facile and waste-free method to access alcohols and thiols. However, no report of this reaction is documented, possibly because of the incompatibility of the generated thiol with typical hydrogenation catalysts. Here, we report an efficient and selective hydrogenation of thioesters. The reaction is catalyzed by an acridine-based ruthenium complex without additives. Various thioesters were fully hydrogenated to the corresponding alcohols and thiols with excellent tolerance for amide, ester, and carboxylic acid groups. Thiocarbamates and thioamides also undergo hydrogenation under similar conditions, substantially extending the application of hydrogenation of organosulfur compounds.

A Reversible Liquid-to-Liquid Organic Hydrogen Carrier System Based on Ethylene Glycol and Ethanol

Zhou, Quan-Quan,Zou, You-Quan,Ben-David, Yehoshoa,Milstein, David

, p. 15487 - 15490 (2020/10/02)

Liquid organic hydrogen carriers (LOHCs) are powerful systems for the efficient unloading and loading molecular hydrogen. Herein, a liquid-to-liquid organic hydrogen carrier system based on reversible dehydrogenative coupling of ethylene glycol (EG) with ethanol catalysed by ruthenium pincer complexes is reported. Noticeable advantages of the current LOHC system is that both reactants (hydrogen-rich components) and the produced esters (hydrogen-lean components) are liquids at room temperature, and the dehydrogenation process can be performed under solvent and base-free conditions. Moreover, the hydrogenation reaction proceeds under low hydrogen pressure (5 bar), and the LOHC system has a relatively high theoretical gravimetric hydrogen storage capacity (HSC>5.0 wt %), presenting an attractive hydrogen storage system.

THIAZOLIDINONE COMPOUNDS AND USE THEREOF

-

Paragraph 1284-1285, (2017/09/21)

A pharmaceutical composition containing a compound of Formula (I) for treating an opioid receptor-associated condition. Also disclosed is a method for treating an opioid receptor-associated condition using such a compound. Further disclosed are two sets of thiazolidinone compounds of formula (I): (i) compounds each having an enantiomeric excess greater than 90% and (ii) compounds each being substituted with deuterium.

Synthesis of Mannosylglycerate Derivatives as Immunostimulating Agents

Hamon, Nadège,Mouline, Caroline C.,Travert, Marion

, p. 4803 - 4819 (2017/09/07)

Mannosylglycerate (MG) is a compatible solute extracted from some red algae and bacteria. Thanks to its ability to protect proteins and stabilise enzymes, MG has been widely studied for its uses against neurodegenerative diseases, and also in biotechnology. More recently, its immunostimulating properties against chronic lymphocytic leukaemia have been investigated. In this paper, we report the synthesis of MG derivatives, and a preliminary biological study on their capacity to behave as immunostimulating agents. We investigated their toxicity against peripheral blood mononuclear cells from healthy donors and their ability to increase the phagocytosis of opsonised bacteria by polynuclear neutrophils. This resulted in the discovery of two new molecules as potential immunostimulating agents.

Process route upstream and downstream products

Process route

carbon monoxide
201230-82-2

carbon monoxide

acetic acid
64-19-7,77671-22-8

acetic acid

acetic acid methyl ester
79-20-9

acetic acid methyl ester

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

ethylidene diacetate
542-10-9

ethylidene diacetate

ethylene glycol diacetate
111-55-7,27252-83-1

ethylene glycol diacetate

ethyl acetate
141-78-6

ethyl acetate

Conditions
Conditions Yield
With hydrogen; ruthenium trichloride; tetra-n-butylphosphonium acetate; at 220 ℃; under 326800 Torr; Product distribution; Thermodynamic data; var. of catalyst, ΔG500;
di-μ-tetrachlorobis(ethylene)dipalladium

di-μ-tetrachlorobis(ethylene)dipalladium

acetic acid
64-19-7,77671-22-8

acetic acid

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

ethylidene diacetate
542-10-9

ethylidene diacetate

ethylene glycol diacetate
111-55-7,27252-83-1

ethylene glycol diacetate

ethylene glycol
107-21-1

ethylene glycol

Conditions
Conditions Yield
With sodium nitrate; water;
29%
35%
ethene
74-85-1

ethene

vinyl acetate
108-05-4,9003-20-7

vinyl acetate

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

ethylidene diacetate
542-10-9

ethylidene diacetate

ethylene glycol diacetate
111-55-7,27252-83-1

ethylene glycol diacetate

ethylene glycol
107-21-1

ethylene glycol

acetaldehyde
75-07-0,9002-91-9

acetaldehyde

Conditions
Conditions Yield
With sodium nitrate; oxygen; sodium chloride; palladium dichloride; In acetic acid; for 1h; Product distribution; Ambient temperature; presence of sodiun acetate; various pressure: 0.1 to 1.0 MPa; various temperature: 50 to 95 deg C;
2-methyl-1,3-dioxolane
497-26-7

2-methyl-1,3-dioxolane

2-chloro-1-acetoxyethane
542-58-5

2-chloro-1-acetoxyethane

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

Conditions
Conditions Yield
With tetrachloromethane; dihydrogen peroxide; at 100 ℃; for 0.333333h;
0.36 mol
0.50 mol
With water; Iodine monochloride; at 0 ℃; for 0.05h;
7 % Spectr.
26 % Spectr.
ethylene glycol
107-21-1

ethylene glycol

acetic acid
64-19-7,77671-22-8

acetic acid

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

Conditions
Conditions Yield
With HY-Zeolite; In chloroform; for 2h; Heating;
90%
With sulfuric acid; sodium hydrogencarbonate; In water; Product distribution / selectivity;
86%
With sulfuric acid; at 25 ℃; for 24h;
60.6%
With sulfuric acid; at 20 ℃; for 72h; Molecular sieve; Inert atmosphere;
56%
at 200 ℃;
With copper(II) sulfate;
Amberlist 15; at 20 ℃; for 96h; Product distribution / selectivity;
With Poly(VMPS)-PW; at 115 ℃; for 3h; Neat (no solvent);
With sulfuric acid; at 20 ℃; for 16h;
ethylene glycol
107-21-1

ethylene glycol

acetyl chloride
75-36-5

acetyl chloride

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

Conditions
Conditions Yield
In 1,4-dioxane; at 120 ℃; for 2h;
42%
N-Acetyltryptamine
1016-47-3

N-Acetyltryptamine

ethylene glycol
107-21-1

ethylene glycol

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

tryptamine hydochloride
343-94-2

tryptamine hydochloride

Conditions
Conditions Yield
N-Acetyltryptamine; With triphenyl phosphite; chlorine; triethylamine; In dichloromethane; at -30 ℃;
ethylene glycol; In dichloromethane; at -30 - 20 ℃;
With water;
81%
N-cyclohexylacetamide
1124-53-4

N-cyclohexylacetamide

ethylene glycol
107-21-1

ethylene glycol

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

cyclohexylamine
108-91-8,157973-60-9

cyclohexylamine

Conditions
Conditions Yield
N-cyclohexylacetamide; With triphenyl phosphite; chlorine; triethylamine; In dichloromethane; at -30 ℃;
ethylene glycol; In dichloromethane; at -30 - 20 ℃;
With water;
76%
N-(1-phenylethyl)acetamide
23602-17-7

N-(1-phenylethyl)acetamide

ethylene glycol
107-21-1

ethylene glycol

2,2-dimethyl-1-methylpropylamine
3850-30-4

2,2-dimethyl-1-methylpropylamine

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

Conditions
Conditions Yield
N-(1-phenylethyl)acetamide; With triphenyl phosphite; chlorine; triethylamine; In dichloromethane; at -30 ℃;
ethylene glycol; In dichloromethane; at -30 - 20 ℃;
With water;
73%
(S)-N-acetyl-1-phenylethylamine
19144-86-6,6284-14-6

(S)-N-acetyl-1-phenylethylamine

ethylene glycol
107-21-1

ethylene glycol

2-hydroxyethyl acetate
542-59-6

2-hydroxyethyl acetate

(<i>S</i>)-1-phenyl-ethylamine
2627-86-3

(S)-1-phenyl-ethylamine

Conditions
Conditions Yield
(S)-N-acetyl-1-phenylethylamine; With triphenyl phosphite; chlorine; triethylamine; In dichloromethane; at -30 ℃;
ethylene glycol; In dichloromethane; at -30 - 20 ℃;
With water;
70%

Global suppliers and manufacturers

Global( 28) Suppliers
  • Company Name
  • Business Type
  • Contact Tel
  • Emails
  • Main Products
  • Country
  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • Chemwill Asia Co., Ltd.
  • Business Type:Manufacturers
  • Contact Tel:021-51086038
  • Emails:sales@chemwill.com
  • Main Products:56
  • Country:China (Mainland)
  • GIHI CHEMICALS CO.,LIMITED
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-571-86217390
  • Emails:info@gihichem.com
  • Main Products:66
  • Country:China (Mainland)
  • Kono Chem Co.,Ltd
  • Business Type:Other
  • Contact Tel:86-29-86107037-8015
  • Emails:info@konochemical.com
  • Main Products:82
  • Country:China (Mainland)
  • Finetech Industry Limited
  • Business Type:Trading Company
  • Contact Tel:86-27-87465837
  • Emails:sales@finetechnology-ind.com
  • Main Products:29
  • Country:China (Mainland)
  • Antimex Chemical Limied
  • Business Type:Lab/Research institutions
  • Contact Tel:0086-21-50563169
  • Emails:anthony@antimex.com
  • Main Products:163
  • Country:China (Mainland)
  • Skyrun Industrial Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:0086-576-84610586
  • Emails:sales@chinaskyrun.com
  • Main Products:18
  • Country:China (Mainland)
  • Hangzhou Keyingchem Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-571-85378921
  • Emails:market@keyingchem.com
  • Main Products:105
  • Country:China (Mainland)
  • Huayang chemical Co., LTD
  • Business Type:Trading Company
  • Contact Tel:+86-18653358619
  • Emails:366816162@qq.com
  • Main Products:50
  • Country:China (Mainland)
close
Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 542-59-6
Post Buying Request Now
close
Remarks: The blank with*must be completed