59090-57-2

Basic information

• Product Name: [1,1'-biphenyl]-4-yl(phenyl)sulfane
• Synonyms: [1,1'-biphenyl]-4-yl(phenyl)sulfane
• CAS NO: 59090-57-2
• Molecular Weight: 262.375
• Mol File: 59090-57-2.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: [1,1'-biphenyl]-4-yl(phenyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: [1,1'-biphenyl]-4-yl(phenyl)sulfane(59090-57-2)
• EPA Substance Registry System: [1,1'-biphenyl]-4-yl(phenyl)sulfane(59090-57-2)

Safety Data

• Hazardous Substances Data: 59090-57-2(Hazardous Substances Data)

Usage

General Description

[1,1'-biphenyl]-4-yl(phenyl)sulfane, also known as diphenyl(phenylthio)biphenyl, is a chemical compound composed of a biphenyl group with a phenylsulfanyl substituent attached to one of the phenyl rings. It is commonly used in organic synthesis and as a building block in the production of various organic compounds. [1,1'-biphenyl]-4-yl(phenyl)sulfane has been studied for its potential applications in materials science, particularly in the development of organic electronics and optoelectronic devices. It is important to handle and dispose of this chemical with care, as it may pose hazards to human health and the environment if not managed properly.

Upstream product

• 19262-78-3 biphenyldiazonium 
• 108-98-5 thiophenol 
• 1192-40-1 copper(I) thiophenolate 
• 2051-62-9 4'-biphenyl chloride 
• 66003-78-9 triphenylsulfonium trifluoromethanesulfonate 
• 75-05-8 acetonitrile 
• 92-52-4 biphenyl 
• 882-33-7 diphenyldisulfane 
• 591-50-4 iodobenzene 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 1591-31-7 4-iodo-biphenyl 
• 14002-51-8 4-biphenyl-carboxylic acid chloride 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 98-80-6 phenylboronic acid 

Downstream Products

• 1357466-08-0 [4-(4-biphenylylthio)phenyl]-4-biphenylylphenylsulfonium methanesulfonate 
• 1357466-07-9 [4-(4-biphenylylthio)phenyl]-(4-biphenylyl)phenylsulfonium hexafluorophosphate 
• 1215851-50-5 [4-(4-biphenylylthio)phenyl]-4-biphenylylphenylsulfonium tris(pentafluoroethyl)trifluorophosphate 
• 1357467-32-3 [4-(4-biphenylylthio)phenyl]-4-biphenylylphenylsulfonium tetrakis(pentafluorophenyl)borate 
• 1240786-54-2 [4-(4-biphenylthio)phenyl]-4-biphenylphenylsulfonium triflate 
• 21213-15-0 4-[(phenyl)sulfinyl]biphenyl 
• 1230-51-9 4-(phenylsulfonyl)biphenyl 

Relevant articles and documents

Aryl thioether compound and preparation method thereof

The invention discloses an aryl thioether compound and a synthesis method thereof, wherein an aryl carboxylic acid and a mercaptan (phenol) are used as main raw materials, and a nickel catalyst is prepared. Under the action of the phosphine ligand and the additive, the aryl carboxylic acid and the thiol (phenol) react in an organic solvent, and after the reaction is finished, the corresponding aryl thioether is obtained. The method has the advantages of low cost, high yield, simple and convenient operation, no pollution and the like, and has potential industrial application prospects. The method provides a cheap and green way for preparation of aryl thioether compounds.

DABCO-promoted Diaryl Thioether Formation by Metal-catalyzed Coupling of Sodium Sulfinates and Aryl Iodides

A scalable catalytic synthesis method using commodity chemicals for constructing diaryl thioethers directly from sodium arylsulfinates and iodoarenes is reported in this study. In the presence of CuO or other copper salts such as Cu(OAc)2 as well as palladium catalysts, DABCO demonstrated to be essential to promote this transformation. Various iodoarenes and aryl sulfinates were examined and demonstrated the viability of this method. The mechanistic study showed that radical reactions occurred, while DABCO N-oxide radical can be observed by mass spectrometry. A plausible catalytic mechanism involving DABCO is also discussed, suggesting synergistic reduction of sulfinate by Cu(II) and DABCO is the key step of this coupling reaction. (Figure presented.).

Controlled Ni-catalyzed mono- and double-decarbonylations of α-ketothioesters

A method for Ni-catalyzed controlled decarbonylation of α-ketothioesters is described. Mono- and double-decarbonylations, which gave thioesters and thioethers, respectively, were selectively achieved by changing the ligand. A fundamental study of Ni-catalyzed decarbonylation of α-ketothioesters is presented.