600-05-5

Basic information

• Product Name: 2,3-Dibromopropionic acid
• Synonyms: 2,3-dibromo-propanoicaci;2,3-dibromo-propionicaci;2.3-DiBromop[d]ropionicacid;Propionic acid, 2,3-dibromo-;ALPHA,BETA-DIBROMOPROPIONIC ACID;2,3-DIBROMOPROPIONIC ACID;2,3-DIBROMOPROPANOIC ACID;RARECHEM AL BO 1239
• CAS NO: 600-05-5
• Molecular Formula: C₃H₄Br₂O₂
• Molecular Weight: 231.87
• EINECS: 209-981-1
• Product Categories: Organic acids;500 Series Drinking Water Methods;Alpha Sort;BromoVolatiles/ Semivolatiles;Chemical Class;D;DAlphabetic;DIA - DICEPA;Halogenated;Method 552;C1 to C5;Carbonyl Compounds;Carboxylic Acids
• Mol File: 600-05-5.mol

Chemical Properties

• Melting Point: 64-66 °C(lit.)
• Boiling Point: 160 °C20 mm Hg(lit.)
• Flash Point: -33℃
• Appearance: white to beige-grey crystalline powder or chunks
• Density: 2.0803 (rough estimate)
• Vapor Pressure: 0.00179mmHg at 25°C
• Refractive Index: 1.5220 (estimate)
• Storage Temp.: 2-8°C
• PKA: pK1:2.33 (25°C)
• Water Solubility: very faint turbidity
• BRN: 1721428
• CAS DataBase Reference: 2,3-Dibromopropionic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-Dibromopropionic acid(600-05-5)
• EPA Substance Registry System: 2,3-Dibromopropionic acid(600-05-5)

Safety Data

• Hazard Codes: C,Xi,F
• Statements: 34-40-36/37/38-38-11
• Safety Statements: 26-36/37/39-45-36-16-24-9
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• RTECS: UF0660000
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 600-05-5(Hazardous Substances Data)

Usage

Uses

Used in Chemical Analysis:
2,3-Dibromopropionic acid is used as a surrogate standard in the chemical shift imaging process during the analysis of multiple samples by multiplex sample NMR methodology. It serves as a reference compound to ensure accurate and reliable results in the analysis.
Used in Water Quality Assessment:
In the field of environmental chemistry, 2,3-Dibromopropionic acid is utilized as a surrogate standard for the extraction and determination of haloacetic acid in drinking water. This application aids in assessing the quality and safety of drinking water supplies.
Used in Gas Chromatography:
2,3-Dibromopropionic acid may also be employed as a surrogate standard for the quantification of haloacids in water samples using gas chromatography techniques. This application is crucial for accurate measurement and analysis of potentially harmful substances in water sources.

InChI:InChI=1/C3H4Br2O2/c4-1-2(5)3(6)7/h2H,1H2,(H,6,7)/p-1/t2-/m0/s1

Upstream product

• 107790-74-9 2-methyl-3-(trimethylgermyl)propanoic acid 
• 2583-25-7 allylmalonic acid 
• 96-13-9 2,3-Dibromopropan-1-ol 
• 7697-37-2 nitric acid 
• 5221-17-0 2,3-dibromopropanal 
• 594-48-9 2,2-dibromopropionic acid 
• 10035-10-6 hydrogen bromide 
• 10443-65-9 2-bromo-2-propenoic acid 
• 7664-93-9 sulfuric acid 
• 7726-95-6 bromine 
• 79-10-7 acrylic acid 
• 802294-64-0 propionic acid 
• 107-13-1 acrylonitrile 

Downstream Products

• 431-21-0 1,2-Dibromo-3,3,3-trifluoropropane 
• 51100-37-9 bis-(2,3-dibromo-1,1-difluoro-propyl) ether 
• 473-81-4 glyceric acid 
• 10443-65-9 2-bromo-2-propenoic acid 
• 127-17-3 2-oxo-propionic acid 
• 24237-89-6 3-(phenylsulfonyl)acrylic acid 
• 176502-69-5 (+/-)-N-benzyl aziridine carboxylate t-butyl ester 
• 103-88-8 4-bromoacetanilide 
• 121388-33-8 2,3-dibromo-propionic acid cyclohexyl ester 
• 79-10-7 acrylic acid 
• 18791-02-1 2,3-dibromo-propionyl chloride 
• 6220-25-3 1,2-dimercaptopropionic acid 
• 17617-04-8 (+/-)-isocysteine 
• 473-81-4 (S)-glyceric acid 

Relevant articles and documents

A 2, 3 - two bromine propionyl chlorides production process (by machine translation)

The present invention relates to the field of producing chemical products, especially 2, 3 - two bromine propionyl chlorides production field. 2. 3 - two bromine propionyl chlorides is an important chemical raw materials. Currently in production have different production process. The process flow includes: 1, addition; 2, distillation. (by machine translation)

An economical and convenient synthesis of vinyl sulfones

A general process for the efficient synthesis of vinyl sulfones has been developed using commercially available sulfinic acid sodium salts and dibromides. A variety of phenyl and methyl vinyl sulfones have been formed in good yields, in the absence of any catalyst. Georg Thieme Verlag Stuttgart.

Kinetic study of the Ce(III)-, Mn(II)-, or ferroin-catalyzed belousov-zhabotinsky reaction with allylmalonic acid

In a stirred batch experiment and under aerobic conditions, ferroin (Fe(phen)32+) behaves differently from Ce(III) or Mn(II) ion as a catalyst for the Belousov-Zhabotinsky (BZ) reaction with allylmalonic acid (AMA). The effects of bromate ion, AMA, metal-ion catalyst, and sulfuric acid on the oscillating pattern were investigated. The kinetics of the reaction of AMA with Ce(IV), Mn(III), or Fe(phen)33+ ion was studied under aerobic or anaerobic conditions. The order of reactivity of metal ions toward reaction with AMA is Fe(phen)33+ > Mn(III) > Ce(IV) under aerobic conditions whereas it is Mn(III) > Ce(IV) > Fe(phen)33+ under anaerobic conditions. Under aerobic or anaerobic conditions, the order of reactivity of RCH(CO2H)2 (R = H (MA), Me (MeMA), Et (EtMA), allyl (AMA), n-Bu (BuMA), Ph (PhMA), and Br (BrMA)) is PhMA > MA > BrMA > AMA > MeMA > EtMA > BuMA toward reaction with Ce(IV) ion and it is MA > PhMA > BrMA > MeMA > AMA > EtMA > BuMA toward reaction with Mn(III) ion. Under aerobic conditions, the order of reactivity of RCH(CO2H)2 toward reaction with Fe(phen)33+ ion is PhMA > BrMA > (MeMA, AMA) > (BuMA, EtMA) > MA. The experiment results are rationalized.

Reaction of (α-halogenoalkyl)thiiranes with nucleophilic reagents I. Reaction with morpholine

By means of deuterated compounds it was established that (chloromethyl)thiirane reacts with morpholine by a mechanism involving initial opening of the thiirane ring followed by recyclization.In the case of (bromomethyl)thiirane direct substitution of the bromine begins to compete with this mechanism. 2-Methyl-2-(chloromethyl)thiirane, 2,2-dimethyl-3-(chloromethyl)thiirane, and the diastereomeric (1-chloroethyl)thiiranes were synthesized, and their reactivity toward morpholine was studied.

Process for the preparation of 2,3-dibromopropionyl chloride

An improved process for the preparation of 2,3-dibromopropionyl chloride, which comprises brominating acrylic acid, adding iron powder or an iron salt to the resultant melt, chlorinating the dibromopropionic acid obtained, and removing the volatile components. The 2,3-dibromopropionyl chloride is obtained in high yield and purity and is an intermediate for synthesising in particular reactive dyes.

Synthesis and properties of germa-γ-lactones

Trialkylgermylpropanoic acids treated with 1 mole of bromine afford the monobromopropanoic acids, which are converted into the corresponding germa-γ-lactones in good yields by hydrolysis.The physical, chemical, and biological properties of these compounds are described.