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762-84-5

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762-84-5 Usage

Uses

It finds its application in the synthesis of amides using the Ritter reaction with bismuth triflate catalysis.

Synthesis Reference(s)

Journal of the American Chemical Society, 108, p. 3528, 1986 DOI: 10.1021/ja00272a069The Journal of Organic Chemistry, 45, p. 165, 1980 DOI: 10.1021/jo01289a034Synthetic Communications, 12, p. 1003, 1982 DOI: 10.1080/00397918208061940

Check Digit Verification of cas no

The CAS Registry Mumber 762-84-5 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 7,6 and 2 respectively; the second part has 2 digits, 8 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 762-84:
(5*7)+(4*6)+(3*2)+(2*8)+(1*4)=85
85 % 10 = 5
So 762-84-5 is a valid CAS Registry Number.
InChI:InChI=1/C6H13NO/c1-5(8)7-6(2,3)4/h1-4H3,(H,7,8)

762-84-5 Well-known Company Product Price

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  • Alfa Aesar

  • (L08505)  N-tert-Butylacetamide, 98%   

  • 762-84-5

  • 10g

  • 537.0CNY

  • Detail
  • Alfa Aesar

  • (L08505)  N-tert-Butylacetamide, 98%   

  • 762-84-5

  • 50g

  • 2057.0CNY

  • Detail

762-84-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name N-tert-Butylacetamide

1.2 Other means of identification

Product number -
Other names Acetamide, N-(1,1-dimethylethyl)-

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:762-84-5 SDS

762-84-5Relevant articles and documents

Homogeneous Catalytic Photochemical Functionalization of Alkanes by Polyoxometalatas

Renneke, Roman F.,Hill, Craig L.

, p. 3528 - 3529 (1986)

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Surface ligands enhance the catalytic activity of supported Au nanoparticles for the aerobic α-oxidation of amines to amides

Chatterjee, Puranjan,Kanbur, Uddhav,Manzano, J. Sebastián,Sadow, Aaron D.,Slowing, Igor I.,Wang, Hsin

, p. 1922 - 1933 (2022/04/07)

The catalytic aerobic α-oxidation of amines in water is an atom economic and green alternative to current methods of amide synthesis. The reaction uses O2 as terminal oxidant, avoids hazardous reactants and gives water as the only byproduct. Here we report that the catalytic activity of silica-supported Au nanoparticles for the aerobic α-oxidation of amines can be improved by tethering pyridyl ligands to the support. In contrast, immobilization of thiol groups on the material gives activities comparable to Au supported on bare silica. Our studies indicate that the ligands affect the electronic properties of the Au nanoparticles and thereby determine their ability to activate O2 and mediate C-H cleavage in the amine substrate. The reaction likely proceeds via an Au catalyzed β-hydride elimination enabled by backdonation from electron-rich metal to the orbital. O2, which is also activated on electron-rich Au, acts as a scavenger to remove H from the metal surface and regenerate the active sites. The mechanistic understanding of the catalytic conversion led to a new approach for forming C-C bonds α to the N atoms of amines.

Preparation method of acetamide compound

-

Paragraph 0035-0047, (2021/05/19)

The invention discloses a preparation method of an acetamide compound, the preparation method comprises the following steps: reacting tetracarbonyl dichloride rhodium, 1, 3-bis (diphenylphosphine) propane, tungsten carbonyl, sodium phosphate, sodium iodide, water, a nitro compound and dimethyl carbonate at 120 DEG C for 24 hours, and after the reaction is completed, performing post-treatment to obtain the acetamide compound. According to the preparation method, dimethyl carbonate serves as a C1 source and also serves as a green solvent, operation is easy, reaction starting raw materials are low in price and easy to obtain, the tolerance range of substrate functional groups is wide, and reaction efficiency is high. Various acetamide compounds can be synthesized according to actual needs, so that the practicability of the method is widened while the operation is convenient.

New half-sandwich (η6-p-cymene)ruthenium(II) complexes with benzothiazole hydrazone Schiff base ligand: Synthesis, structural characterization and catalysis in transamidation of carboxamide with primary amines

Vijayapritha, Subbarayan,Viswanathamurthi, Periasamy

supporting information, (2020/10/18)

Few half-sandwich (η6-p-cymene) ruthenium(II) complexes supported by benzothiazole hydrazone Schiff bases were synthesized. The new complexes possess the general formulae [Ru(η6-p-cymene)(L)Cl] (1-3) (L = salicyl((2-(benzothiazol-2-yl)hydrazono)methylphenol) (SAL-HBT), 2-((2-(benzothiazol-2-yl)hydrazono)methyl)-6 methoxyphenol) (VAN-HBT) or naphtyl-2-((2-(benzothiazol-2-yl)hydrazono)methyl phenol) (NAP-HBT). All compounds were fully studied by analytical, spectroscopic techniques (IR, NMR) and also by mass spectrometry. The solid state structure of the complex 3 reveals the coordination of p-cymene moieties with ruthenium(II) in a three-legged piano-stool geometry along with benzothiazole hydrazone Schiff base ligand in a monobasic bidentate fashion. The catalytic properties of the complexes were screened in transamidation of primary amide with amines after optimization with respect to solvent, substituents, time and catalyst loading. The results show that the complex 3 is the most efficient catalyst for the transamidation of carboxamides with amines.

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