766-77-8Relevant articles and documents
Platinum Catalysed Regioselective ortho-Silylation of Benzylideneamines via Intramolecular C-H Activation
Williams, Neil A.,Uchimaru, Yuko,Tanaka, Masato
, p. 1129 - 1130 (1995)
The Pt-P(OCH2)3CEt complex catalyses the ortho-silylation of benzylideneamines with disilanes via intramolecular C-H activation; both mono- and bis-silylated products are obtained.
Hydrogenolysis of Polysilanes Catalyzed by Low-Valent Nickel Complexes
Comas-Vives, Aleix,Eiler, Frederik,Grützmacher, Hansj?rg,Pribanic, Bruno,Trincado, Monica,Vogt, Matthias
supporting information, p. 15603 - 15609 (2020/04/29)
The dehydrogenation of organosilanes (RxSiH4?x) under the formation of Si?Si bonds is an intensively investigated process leading to oligo- or polysilanes. The reverse reaction is little studied. To date, the hydrogenolysis of Si?Si bonds requires very harsh conditions and is very unselective, leading to multiple side products. Herein, we describe a new catalytic hydrogenation of oligo- and polysilanes that is highly selective and proceeds under mild conditions. New low-valent nickel hydride complexes are used as catalysts and secondary silanes, RR′SiH2, are obtained as products in high purity.
Catalytic Reduction of Alkoxysilanes with Borane Using a Metallocene-Type Yttrium Complex
Aoyagi, Keiya,Matsumoto, Kazuhiro,Shimada, Shigeru,Sato, Kazuhiko,Nakajima, Yumiko
supporting information, p. 210 - 212 (2019/02/01)
The catalytic reduction of alkoxysilanes with the borane HBpin (pin = pinacolato) was achieved using a metallocene-type yttrium complex as a catalyst precursor. Mechanistic study supported the pivotal role of the rigid metallocene structure of the catalyst, which bears two bulky n5-C5Me4SiMe3 ligands, in suppressing the coordination of the side product MeOBpin that is generated during the reaction.