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7783-99-5

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7783-99-5 Usage

Chemical Properties

powder

Uses

Different sources of media describe the Uses of 7783-99-5 differently. You can refer to the following data:
1. For preparation of standard NaNO2 solution for water analysis; preparation of aliphatic nitro-compounds; as reagent for primary, secondary, and tertiary alcohols.
2. Silver nitrite is used in the silver plating process, hair dye, inks, permanent marker pens and determination of chloride ions in water and drilling fluids. It is used as Tollen?s reagent and used in the formation of aniline and nitro compounds in victor mayer reactions.

Purification Methods

Crystallise the salt from hot conductivity water (70mL/g) in the dark. Dry it in the dark under vacuum. [Glemser & Sauer in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 1048 1963.]

Check Digit Verification of cas no

The CAS Registry Mumber 7783-99-5 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 7,7,8 and 3 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 7783-99:
(6*7)+(5*7)+(4*8)+(3*3)+(2*9)+(1*9)=145
145 % 10 = 5
So 7783-99-5 is a valid CAS Registry Number.
InChI:InChI=1/Ag.HNO2/c;2-1-3/h;(H,2,3)/q+1;/p-1

7783-99-5 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
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  • Detail
  • Alfa Aesar

  • (11418)  Silver nitrite, 99% (metals basis)   

  • 7783-99-5

  • 10g

  • 959.0CNY

  • Detail
  • Alfa Aesar

  • (11418)  Silver nitrite, 99% (metals basis)   

  • 7783-99-5

  • 50g

  • 4543.0CNY

  • Detail
  • Aldrich

  • (545015)  Silvernitrite  99.98% trace metals basis

  • 7783-99-5

  • 545015-5G

  • 879.84CNY

  • Detail
  • Aldrich

  • (545015)  Silvernitrite  99.98% trace metals basis

  • 7783-99-5

  • 545015-25G

  • 3,038.49CNY

  • Detail
  • Aldrich

  • (227188)  Silvernitrite  99%

  • 7783-99-5

  • 227188-10G

  • 552.24CNY

  • Detail
  • Aldrich

  • (227188)  Silvernitrite  99%

  • 7783-99-5

  • 227188-50G

  • 2,029.95CNY

  • Detail

7783-99-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name silver,nitrite

1.2 Other means of identification

Product number -
Other names silver nitrite

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:7783-99-5 SDS

7783-99-5Relevant articles and documents

Suzuki, T.

, p. 726 - 732 (1910)

Jeffery, F. H.

, p. 16 - 20 (1919)

Two novel lineal d10 metal-organic frameworks with a ditopic flexible linker: Structures, blue luminescence and thermal stability

Brito, Iván,Vallejos, Javier,Cárdenas, Alejandro,López-Rodríguez, Matías,Bolte, Michael,Llanos, Jaime

, p. 897 - 901 (2011)

Two novel supramolecular Ag(I) complexes, {[AgL]NO3}n (1), and {[AgL]CF3SO3}n (2), (L) = ethane-1,2-diyl bis(pyridine-3-carboxylate) have been prepared by self-assembly of Ag(I) salts with ethane-1,2-diyl bis(pyridine-3-carboxylate) (L) in THF/H2O system. The IR, TGA and elemental analysis have been recorded and both complexes were structurally characterized by X-ray crystallography confirming that complexes (1) and (2) are one-dimensional coordination polymers with lineal and helical chain motifs respectively. Solid emission spectra at room temperature of (1) and (2) show interesting blue phosphorescence with maximum intensity at 414 and 411 nm respectively, which are assigned to (LLCT) transition.

Evidence for dissociative photosubstitution reactions of [Ru(trpy)(bpy)(NCCH3)]2+. Crystal and molecular structure of [Ru(trpy)(bpy)(py)](PF6)2·(CH3) 2CO

Hecker, Clark R.,Fanwick, Phillip E.,McMillin, David R.

, p. 659 - 666 (2008/10/08)

In acetonitrile and in the presence of appropriate nucleophiles, the complex [Ru(trpy)(bpy)(NCCH3)]2+ undergoes a ligand substitution reaction when irradiated into the metal-to-ligand absorption band system. (The symbol trpy denotes 2,2′:6′,2″-terpyridine, and bpy denotes 2,2′-bipyridine.) At 25°C quantum yields for displacement of the acetonitrile ligand are 0.0013 (1), 0.0013 (1), and 0.0026 (5) for 1.0 M solutions of pyridine, 4-phenylpyridine, and 2-methylpyridine, respectively. No photochemistry is observed for the osmium(II) analogue, and all findings can be understood in terms of a dissociative reaction mechanism involving a reactive 3d-d state. The 3d-d state is accessed from a 3CT state, which is emissive below ca. 180 K. From measurements of the temperature dependence of the emission lifetime, the barrier to population of the 3d-d state is approximately 1500 cm-1. Finally, the crystal structure of [Ru(trpy)(bpy)(py)](PF6)2·(CH3) 2CO has been determined with a diffractometer. The compound crystallizes with two independent formula units in a triclinic unit cell. The space group is P1, and there are four formulas per unit cell (Z = 4) with a = 13.150 (1) A?, b = 14.927 (1) A?, c = 19.771 (2) A?, α = 102.840 (9)°, β = 91.655 (8)°, and γ = 103.371 (8)°. The structure was solved by the full-matrix least-squares method, and after the final stage of refinement, R = 0.055. There is evidence of interligand steric strain within the coordination sphere, and the bpy ligand is coordinated asymmetrically with a difference in Ru-N bond lengths of about 0.04 A?. The internal strain probably explains why we have been unable to prepare the 2-methylpyridine analogue by standard methods.

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