937-41-7

Basic information

• Product Name: PHENYL ACRYLATE
• Synonyms: 2-propenoicacid,phenylester;PHENYL ACRYLATE;Phenylacrylate,97%;acrylic acid phenyl ester;PHENYLACRYLATE PHENYL ACRYLATE;phenyl prop-2-enoate;Phenyl acrylate, 98+%;Phenyl 2-propenoate
• CAS NO: 937-41-7
• Molecular Formula: C₉H₈O₂
• Molecular Weight: 148.16
• EINECS: 213-329-1
• Product Categories: monomer
• Mol File: 937-41-7.mol

Chemical Properties

• Boiling Point: 89-90°C 12mm
• Flash Point: 89-90°C/12mm
• Appearance: /
• Density: 1,076 g/cm3
• Vapor Pressure: 0.0596mmHg at 25°C
• Refractive Index: 1.5210
• Storage Temp.: 2-8°C
• Water Solubility: Insoluble in water.
• BRN: 2041124
• CAS DataBase Reference: PHENYL ACRYLATE(CAS DataBase Reference)
• NIST Chemistry Reference: PHENYL ACRYLATE(937-41-7)
• EPA Substance Registry System: PHENYL ACRYLATE(937-41-7)

Safety Data

• Statements: 36/37/38-51/53
• Safety Statements: 26-36/37/39
• RIDADR: UN3082
• TSCA: Yes
• HazardClass: 9
• PackingGroup: III
• Hazardous Substances Data: 937-41-7(Hazardous Substances Data)

Usage

Uses

Used in Chemical Synthesis:
PHENYL ACRYLATE is used as a chemical intermediate for the synthesis of various compounds. It is particularly used in the production of 2-(hydroxy-phenyl-methyl)-acrylic acid phenyl ester, which is formed by its reaction with benzaldehyde.
Used in Polymer Industry:
PHENYL ACRYLATE is used as a monomer in the polymer industry for the production of various polymers. Its reactive nature allows it to be copolymerized with other monomers to form polymers with specific properties.
Used in Pharmaceutical Industry:
PHENYL ACRYLATE is used as a starting material in the synthesis of certain pharmaceutical compounds. Its ability to react with other compounds makes it a valuable component in the development of new drugs.
Used in Coatings Industry:
PHENYL ACRYLATE is used in the coatings industry for the production of various types of coatings, such as automotive coatings, wood coatings, and metal coatings. Its reactive nature allows it to be incorporated into the formulation of coatings to improve their properties.
Used in Adhesive Industry:
PHENYL ACRYLATE is used in the adhesive industry for the production of various types of adhesives. Its ability to react with other compounds makes it a valuable component in the development of new adhesive formulations.

InChI:InChI=1/C9H8O2/c1-2-9(10)11-8-6-4-3-5-7-8/h2-7H,1H2

Upstream product

• 27850-43-7 3-bromopropionic acid phenyl ester 
• 1864-94-4 phenyl formate 
• 108-95-2 phenol 
• 1033462-77-9 tert-butyl acryloyl carbonate 
• 2051-76-5 acrylic acid anhydride 
• 102-09-0 bis(phenyl) carbonate 
• 79-10-7 acrylic acid 
• 124654-80-4 phenyl 2,3-dibromopropanoate 
• 13045-88-0 (prop-1-yn-1-yloxy)benzene 
• 108-05-4 vinyl acetate 
• 107-02-8 acrolein 
• 144261-51-8 3-phenyl-3-hydroxy-2-methylene-propanoic acid phenyl ester 
• 108885-08-1 (1S)-(7,7-dimethyl-2-oxobicyclo[2.2.1]hept-1-yl)methane sulfonic acid phenyl ester 
• 164594-13-2 Phenyl[2-(trimethylsilyl)phenyl]iodonium trifluoromethanesulfonate 

Downstream Products

• 62131-51-5 phenyl 3-morpholinopropionate 

Relevant articles and documents

Development of n-type semiconductor based on cyclopentene- or cyclohexene-fused [C60]-fullerene derivatives

Properties of cyclopentene- or cyclohexene-fused [C60]-fullerene derivatives as the acceptor in photovoltaic cells have been investigated by use of poly(3-hexylthiophene) (P3HT) as the model donor polymer. Several cyclopentene- or cyclohexene-fused [C60]-fullerene derivatives show high power conversion efficiency (PCE). The highest PCE was obtained for 3′,6′-dihydro-4′-phenoxycarbonyl-6′-methylbenzo[1,9][5,6](C60-Ih)fullerene (3.2%); this is superior to that of [C60]-PCBM with the P3HT polymer under the same experimental conditions. PCE of the OPV devices with alkyl-substituted cyclohexene-fused [C60]-fullerenes depended on the alkyl substituent on the cyclohexene ring; compounds with substituents of odd-number alkyl groups showed better PCE than those compounds possessing even-number alkyl groups.

Synthesis and evaluation of a novel hydrophobically associating polymer based on acrylamide for enhanced oil recovery

A novel polymerizable hydrophobic monomer 1-(4-dodecyloxy-phenyl)-propenone (DPP) was synthesized by esterification, Frise rearrangement and Williamson etherification; then, the obtained DPP was copolymerized with 2-(acrylamido)-dodecanesulfonic acid (AMC12S) and acrylamide (AM) initiated by a redox initiation system in an aqueous medium to enhance oil recovery (EOR). AM/AMC12S/DPP (PADP) was characterized by FT-IR, 1H NMR spectroscopy, environmental scanning electron microscopy (ESEM), DSC-TG, fluorescent probe, core flood test, etc. Results of ESEM and fluorescent probe indicate that hydrophobic microdomains and associating threedimensional networks were formed in the aqueous solution of PADP. Results of DSC-TG demonstrated that long carbon chains, aromatic groups and sulfonic groups were incorporated into the PADP polymer, which can lead to a significant increase of the rigidity of molecular chains. Performance evaluation of experiments showed superior properties in regard to temperature-tolerance, shear-tolerance and salt-tolerance. In the Sandpack Flooding Test, PADP brine solution showed a significant increase in EOR at 65°C because of its high thickening capability. All these features indicate that PADP has a potential application in EOR at harsh conditions.

Acid- And base-switched palladium-catalyzed γ-C(sp3)-H alkylation and alkenylation of neopentylamine

The functionalization of remote unactivated C(sp3)-H and the reaction selectivity are among the core pursuits for transition-metal catalytic system development. Herein, we report Pd-catalyzed γ-C(sp3)-H-selective alkylation and alkenylation with removable 7-azaindole as a directing group. Acid and base were found to be the decisive regulators for the selective alkylation and alkenylation, respectively, on the same single substrate under otherwise the same reaction conditions. Various acrylates were compatible for the formation of C(sp3)-C(sp3) and C(sp3)-C(sp2) bonds. The alkenylation protocol could be further extended to acrylates with natural product units and α,β-unsaturated ketones. The preliminary synthetic manipulation of the alkylation and alkenylation products demonstrates the potential of this strategy for structurally diverse aliphatic chain extension and functionalization. Mechanistic experimental studies showed that the acidic and basic catalytic transformations shared the same six-membered dimer palladacycle.

Palladium-catalyzed regioselective synthesis of B(4,5)-or B(4)-substituted: O-carboranes containing α,β-unsaturated carbonyls

With the help of a carboxylic acid directing group, Pd-catalyzed regioselective synthesis of B(4,5)-or B(4)-substituted o-carboranes containing α,β-unsaturated carbonyls has been reported. The-COOH, removed during the course of the reaction, is responsible for controlling the regioselectivity. The desired products could be obtained in moderate to good yields.

Palladium-catalyzed remote C-H functionalization of 2-aminopyrimidines

A straightforward strategy was developed for the arylation and olefination at the C5-position of the N-(alkyl)pyrimidin-2-amine core with readily available aryl halides and alkenes, respectively. This approach was highly regioselective, and the transformation was achieved based on two different (Pd(ii)/Pd(iv)) and (Pd(0)/Pd(ii)) catalytic cycles.

METHOD FOR PRODUCING (METH) ACRYLATE

PROBLEM TO BE SOLVED: To provide a production method for obtaining (meth) acrylate in high yields, by preventing a large amount of waste from produced from by-products, like the conventional art. SOLUTION: A method for producing (meth) acrylate includes the reaction between a compound represented by the following formula (I) and an aryl alcohol. Preferably, the reaction occurs in the presence of a catalyst of at least one metal compound selected from first Group metal compounds and second Group metal compounds. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT

CARBOXYLIC ACID ESTER PRODUCTION METHOD

Provided is a production method whereby corresponding carboxylic acid esters can be obtained from a variety of carboxylic acids at a high yield, even under conditions using a simple reaction operation and little catalyst and even if the amount of substrate used is theoretical. A production method for carboxylic acid ester, whereby a prescribed diester dicarbonate, carboxylic acid, and alcohol are reacted in the presence of at least one type of magnesium compound and at least one type of alkali metal compound.

Kinetic studies of conjugate addition of amines to allenic and acrylic esters and their correlation with antibacterial activities against Staphylococcus aureus

Abstract: Kinetic reactivities of various allenic and acrylic esters in conjugate addition reactions with various amines were investigated. Competition experiments showed that amines reacted selectively with allenic esters, which was also confirmed by quantitative determination of the rate constants. The antibacterial activity against Staphylococcus aureus of allenic and acrylic ester derivatives were also determined. Allenic esters were found to exhibit a higher antibacterial activity than its acrylic counterparts. A correlation between the kinetic property and the antibacterial activity suggested that a conjugate addition may involve in the antibacterial mechanism of these unsaturated esters. Graphical abstract: [Figure not available: see fulltext.].

METHOD FOR PRODUCING CARBOXYLIC ACID ANHYDRIDE AND METHOD FOR PRODUCING CARBOXYLIC ACID ESTER

Provided is a production method whereby corresponding carboxylic acid anhydrides and carboxylic acid esters can be obtained at high yield from various carboxylic acids even without a solvent and near room temperature. A method for producing a carboxylic acid anhydride represented by formula (II), the method comprising reacting a compound represented by formula (I) and a carboxylic acid in the presence of a Group II metal compound having an ionic ligand containing an oxygen atom. A method for producing a carboxylic acid ester, the method comprising reacting a carboxylic acid anhydride produced by the aforementioned method and an alcohol. In formula (I), R1 represents a C1-20 hydrocarbon group. In formula (II), R2 represents a C1-20 hydrocarbon group.

PHENYL (METH)ACRYLATE PRODUCTION METHOD AND PHENYL (METH)ACRYLATE COMPOSITION

Provided is a method that can produce phenyl(meth)acrylate inexpensively and at high yields. The phenyl(meth)acrylate production method of the present invention reacts (meth)acrylic acid with carbonic acid diphenyl. Further, the phenyl(meth)acyrlate composition of the present invention contains 90-99.999 wt % phenyl(meth)acrylate and 0.001-10% carbonic acid diphenyl. Or, the phenyl(meth)acrylate composition of the present invention contains 90-99.999 wt % phenyl(meth)acrylate and 0.001-10 wt % of a specified compound.