Amadori Rearrangement

M. Amadori, Atti Accad. Nazl. Lincei 2(6), 337 (1925), C.A. 20, 902 (1926); ibid. 9(6), 68, 226 (1929), C.A. 23, 3211, 3443 (1929).

Conversion of N-glycosides of aldoses to N-glycosides of the corresponding ketoses by acid or base catalysis:



J. E. Hodge, Advan. Carbohyd. Chem. 10, 169 (1955); R. U. Lemieux in Molecular Rearrangements Part 2, P. de Mayo, Ed. (Wiley-Interscience, New York, 1964) p 753. 13C-NMR studies: W. Funcke, Ann. 1978, 2099. Review: K. Maruoka, H. Yamamoto, Comp. Org. Syn. 6, 789-791 (1991).