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Basic Information
CAS No.: 96-10-6
Name: DIETHYLALUMINUM CHLORIDE
Molecular Structure:
Molecular Structure of 96-10-6 (DIETHYLALUMINUM CHLORIDE)
Formula: C4H10AlCl
Molecular Weight: 120.558
Synonyms: Aluminum,dichlorotetraethyldi- (7CI);Diethylaluminum chloride (6CI);Chlorodiethylaluminum;Diethylaluminum monochloride;Diethylchloroaluminum;
EINECS: 202-477-2
Density: 0.887g/mLat 25°C
Melting Point: -85°C
Boiling Point: 125°C 50mm
Flash Point: ?9°F
Solubility: reac H2O [CRC10]
Appearance: colorless liquid
Hazard Symbols: FlammableF,CorrosiveC,DangerousN
Risk Codes: 14-17-34-67-65-62-51/53-48/20-14/15-11-63
Safety: 36/37/39-45-62-61-43-26
Transport Information: UN 3394 4.2/PG 1
PSA: 0.00000
LogP: 2.63730
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Chemistry

DIETHYLALUMINUM CHLORIDE (96-10-6) appears clear liquid.
There are some properties of DIETHYLALUMINUM CHLORIDE (96-10-6)  listed in the following.
Molecular Formula:C4H10AlCl
Molecular Weight:120.56 .
EINECS:202-477-2
Density:0.887 g/mL at 25 °C
Melting Point:-74 C
Boiling Point:208 C
Flash Point:9 °F
Solubility:decomposes
Risk Codes:14-17-34
liansport Information:95kgs

Uses

Diethylaluminum chloride(96-10-6) is used as a catalyst in Ziegler-Natta polimerization process for vinyl, olefin, diene polymerizations and linear oligomerization and cyclization of unsaturated hydrocarbons.
Diethylaluminum chloride(96-10-6)  is also used as an alkylation catalyst.

Toxicity Data With Reference

1.   

ihl-rat LC50:11 g/m3

   85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1215.
DIETHYLALUMINUM CHLORIDE (96-10-6) has the Hazard Symbols of 4.2 (Packing group; I) UN NO.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Reaction with chlorine azide may form an explosive product. When heated to decomposition DIETHYLALUMINUM CHLORIDE (96-10-6) emits toxic fumes of Cl−. See also ALUMINUM COMPOUNDS and CHLORIDES.

Standards and Recommendations

ACGIH TLV: TWA 2 mg(Al)/m3