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Basic Information
CAS No.: 563-43-9
Name: ETHYLALUMINUM DICHLORIDE
Article Data: 27
Molecular Structure:
Molecular Structure of 563-43-9 (ETHYLALUMINUM DICHLORIDE)
Formula: C2H5AlCl2
Molecular Weight: 126.949
Synonyms: Ethylaluminumdichloride (6CI);Dichloroethylaluminum;Dichloromonoethylaluminum;Ethylaluminium dichloride;Ethyldichloroaluminum;
EINECS: 209-248-6
Density: 0.927 g/cm3
Melting Point: 32°C(lit.)
Boiling Point: 68-70 °C
Flash Point: 40 °F
Solubility: Soluble in acetone. Miscible with alcohol, chloroform, ether. Reacts with water.
Appearance: Clear colorless to yellow solution
Hazard Symbols: FlammableF,ToxicT,DangerousN,CorrosiveC
Risk Codes: 11-15-23/24/25-34-14-67-65-62-51/53-48/20-14/15-17
Safety: 16-26-36/37/39-45-62-61-43-27
Transport Information: UN 3399
PSA: 0.00000
LogP: 2.35290
Synthetic route
75-00-3

chloroethane

563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
With aluminium und anschliessend mit AlCl3;
With aluminium trichloride; aluminium
diethyl aluminium chloride

diethyl aluminium chloride

AlCl3

AlCl3

563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
at 180 - 190℃;
75-00-3

chloroethane

aluminium

aluminium

A

563-43-9

ethylaluminum dichloride

B

diethyl aluminium chloride

diethyl aluminium chloride

Conditions
ConditionsYield
With iodine bei Ausschluss von Feuchtigkeit und Sauerstoff;
With aluminium trichloride bei Ausschluss von Feuchtigkeit und Sauerstoff;
75-00-3

chloroethane

copper containing aluminium

copper containing aluminium

A

563-43-9

ethylaluminum dichloride

B

diethyl aluminium chloride

diethyl aluminium chloride

Conditions
ConditionsYield
With iodine bei Ausschluss von Feuchtigkeit und Sauerstoff;
With aluminium trichloride bei Ausschluss von Feuchtigkeit und Sauerstoff;
95465-40-0

gem-1,1-bis(dichloroalumino)ethane

74-85-1

ethene

7429-90-5

aluminium

A

563-43-9

ethylaluminum dichloride

B

96-10-6

diethylaluminium chloride

Conditions
ConditionsYield
In n-heptane byproducts: (CH2CHCHCH2CH(CH3))x; High Pressure; (Ar); to a soln. of Al-compound and Al added ethylene (20 bar pressure) under stirring at 100-150°C for 16 h; distd. in vacuo at 50°C; elem. anal.;
95465-40-0

gem-1,1-bis(dichloroalumino)ethane

74-85-1

ethene

563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In n-heptane byproducts: (CH2CHCHCH2CH(CH3))x; High Pressure; (Ar); to a soln. of Al-compound added ethylene (20 bar pressure) under stirring at 100°C for 24 h; distd. in vacuo at 50°C; elem. anal.;
7446-70-0

aluminium trichloride

100-99-2

triisobutylaluminum

A

563-43-9

ethylaluminum dichloride

B

1779-25-5

diisobutylaluminum chloride

Conditions
ConditionsYield
In diethyl ether; toluene all manipulations under dry, O2 free N2 atm.; AlCl3 dissolved in Et2O, soln. of iso-Bu3Al in toluene added at -78°C, allowed to warm to room temp., stirred and refluxed for for 3, stirred at room temp. for 48 h h;

bis(tetrachloroaluminato)(η(6)-benzene)titanium(II)

96-10-6

diethylaluminium chloride

A

(η6-benzene)Ti(AlCl4)(AlCl3Et)

B

563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In benzene Addn. of Et2AlCl to benzene soln. of Ti-compd. at 50°C.; Electronic absorption spectroscopy.;
7647-01-0

hydrogenchloride

96-10-6

diethylaluminium chloride

563-43-9

ethylaluminum dichloride

Conditions
ConditionsYield
In toluene byproducts: C2H6; (Ar); using Schlenk techniques; addn. of HCl saturated toluene to react. mixt. with Et2AlCl;

(η6-benzene)titanium(II)(AlCl2Et2)(AlCl3Et)

A

titanium chloride

B

563-43-9

ethylaluminum dichloride

C

96-10-6

diethylaluminium chloride

Conditions
ConditionsYield
In benzene Decompn. of Ti-compd.; Slow pptn. of TiCl2 from the soln. on a time scale of days-to-months obsd. by elecronic absorption spectroscopy.;
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Consensus Reports

Reported in EPA TSCA Inventory.

Standards and Recommendations

ACGIH TLV: TWA 2 mg(Al)/m3

Specification

The Dichloro(ethyl)alumane, with the CAS registry number 563-43-9, is also known as Aluminum, dichloroethyl-. It belongs to the product categories of Organometallics; Al (Alminum) Compounds; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Synthetic Organic Chemistry; Titanium Alkoxides, etc. (Homogeneous Catalysts); Typical Metal Compounds; Chemical Synthesis; Organoaluminum; Organometallic Reagents. Its EINECS registry number is 209-248-6. This chemical's molecular formula is C2H5AlCl2 and molecular weight is 126.948638. Its IUPAC name is called dichloro(ethyl)alumane. This chemical is clear colorless to yellow solution.

Physical properties of Dichloro(ethyl)alumane: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 0; (4)Exact Mass: 125.958369; (5)MonoIsotopic Mass: 125.958369; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 5; (8)Formal Charge: 0; (9)Complexity: 21.6; (10)Covalently-Bonded Unit Count: 1.

Preparation: this chemical can be prepared by chloroethane and Al. This reaction will need chloroethane.

 

Uses of Dichloro(ethyl)alumane: it can be used to produce 1-phenyl-propan-1-one at temperature of 20 °C. This reaction will need reagent CH2Cl2 with reaction time of 3 hours. The yield is about 73%.

When you are using this chemical, please be cautious about it as the following:
This chemical may catch fire in contact with air and only need brief contact with an ignition source which has a very low flash point or evolve highly flammable gases in contact with water. It is toxic by inhalation, in contact with skin and if swallowed. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC[Al](Cl)Cl
(2)InChI: InChI=1S/C2H5.Al.2ClH/c1-2;;;/h1H2,2H3;;2*1H/q;+2;;/p-2
(3)InChIKey: UAIZDWNSWGTKFZ-UHFFFAOYSA-L