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Disilane,1-chloro-1,1,2,2,2-pentamethyl-

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Name

Disilane,1-chloro-1,1,2,2,2-pentamethyl-

EINECS 216-330-5
CAS No. 1560-28-7 Density 0.86 g/cm3
PSA 0.00000 LogP 2.84690
Solubility N/A Melting Point <0°C
Formula C5H15ClSi2 Boiling Point 134.3 °C at 760 mmHg
Molecular Weight 166.798 Flash Point 23.9 °C
Transport Information N/A Appearance N/A
Safety 16-26-36/37/39-45 Risk Codes 11-14-34
Molecular Structure Molecular Structure of 1560-28-7 (CHLOROPENTAMETHYLDISILANE) Hazard Symbols FlammableF, CorrosiveC
Synonyms

Disilane,chloropentamethyl- (6CI,7CI,8CI,9CI);Chlorodimethyl(trimethylsilyl)silane;Chloropentamethyldisilane;Monochloropentamethyl disilane;Pentamethylchlorodisilane;

Article Data 25

Disilane,1-chloro-1,1,2,2,2-pentamethyl- Specification

The Disilane,1-chloro-1,1,2,2,2-pentamethyl- is an organic compound with the formula C5H15ClSi2. The IUPAC name of this chemical is Chloro-dimethyl-trimethylsilylsilane. With the CAS registry number 1560-28-7, it is also named as Disilane, chloropentamethyl-. The product's categories are Precursors by Metal; Vapor Deposition Precursors. Besides, it should be stored in a dry, well-ventilated, lightproof place.

Physical properties about Disilane,1-chloro-1,1,2,2,2-pentamethyl- are: (1)ACD/LogP: 3.51; (2)ACD/LogD (pH 5.5): 3.51; (3)ACD/LogD (pH 7.4): 3.51; (4)ACD/BCF (pH 5.5): 273.3; (5)ACD/BCF (pH 7.4): 273.3; (6)ACD/KOC (pH 5.5): 1930.85; (7)ACD/KOC (pH 7.4): 1930.85; (8)#Freely Rotating Bonds: 1; (9)Index of Refraction: 1.404; (10)Molar Refractivity: 47.49 cm3; (11)Molar Volume: 193.9 cm3; (12)Polarizability: 18.82×10-24 cm3; (13)Surface Tension: 15.9 dyne/cm; (14)Density: 0.86 g/cm3; (15)Flash Point: 23.9 °C; (16)Enthalpy of Vaporization: 35.64 kJ/mol; (17)Boiling Point: 134.3 °C at 760 mmHg; (18)Vapour Pressure: 10 mmHg at 25 °C.

Preparation: this chemical can be prepared by Hexamethyl-disilane. This reaction will need reagents AcCl; AlCl3 and solvent CH2Cl2. The reaction time is 1 hours with reaction temperature of 0 °C. The yield is about 65%.

Uses of Disilane,1-chloro-1,1,2,2,2-pentamethyl-: it can be used to produce Ethoxy-pentamethyl-disilane at temperature of 0 °C. It will need reagent Et3N and solvent petroleum ether with reaction time of 3 hours. The yield is about 71%.

When you are using this chemical, please be cautious about it as the following:
It is highly Flammable. It reacts violently with water. And it causes burns. When you are using it, keep away from sources of ignition - No smoking, and wear suitable gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/C5H15ClSi2/c1-7(2,3)8(4,5)6/h1-5H3
(2)InChIKey: GJCAUTWJWBFMFU-UHFFFAOYAD
(3)Std. InChI: InChI=1S/C5H15ClSi2/c1-7(2,3)8(4,5)6/h1-5H3
(4)Std. InChIKey: GJCAUTWJWBFMFU-UHFFFAOYSA-N

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