Tetrahedron Letters p. 2131 - 2134 (1985)
Update date:2022-08-04
Topics:
Bonini, Bianca F.
Foresti, Elisabetta
Maccagnani, Gaetano
Mazzanti, Germana
Sabatino, Piera
Zani, Paolo
Conjugated nitrosoalkenes, generated in situ via dehydrobromination of α-bromoketoximes, undergo an easy <4+2>-cycloaddition with thiocarbonyl compounds to give very high yields of the new heterocycles 4H-1,5,2-oxathiazines.The thermolysis and the behaviour to oxidation of these adducts were tested.
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