1,2-Carbonyl Migration along the Allylic Framework: Synthesis of Alkenylnaphthoquinones

DOI: 10.1039/c39880001382

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Journal of the Chemical Society. Chemical communications p. 1382 - 1383 (1988)

Update date:2022-08-04

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Authors:

Mahidol, Chulabhorn

Pinyopronpanit, Yongyut

Radviroongit, Shuleewan

Thebtaranonth, Chachanat

Thebtaranonth, Yodhathai

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Article abstract of DOI:10.1039/c39880001382

Instead of undergoing a cyclopentenone annulation, the allylmalonate anion derived from the dicarboxylate (7) rearranges to vinylsuccinate (5), an application of which has led to a convenient synthesis of vinylnaphthoquinones (10).

Full text of DOI:10.1039/c39880001382

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