Reactions of 3-phenylglycidic esters. V. Reaction of methyl 3-(4-methoxyphenyl)glycidate with 2-nitroaniline and synthesis of 1,5-benzodiazepine derivatives

DOI: 10.1248/cpb.33.2348

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2348 - 2358 (1985)

Update date:2022-09-26

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Authors:

Hashiyama

Inoue Inoue

Takeda Takeda

et al. et al.

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Article abstract of DOI:10.1248/cpb.33.2348

Stereochemical aspects of the oxirane-ring opening of methyl trans-3-(4-methoxyphenyl)-glycidate (1) with 2-nitroaniline (5) were investigated. ZnI₂ showed good catalytic activity in this reaction, giving the cis-opening product (6a) predominan

Full text of DOI:10.1248/cpb.33.2348

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