Journal of the American Chemical Society p. 9226 - 9229 (2015)
Update date:2022-08-03
Topics:
Choi, Gilbert J.
Knowles, Robert R.
Here we describe a dual catalyst system comprised of an iridium photocatalyst and weak phosphate base that is capable of both selectively homolyzing the N-H bonds of N-arylamides (bond dissociation free energies ～ 100 kcal/mol) via concerted proton-couple
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