Angewandte Chemie - International Edition p. 205 - 208 (2008)
Update date:2022-08-04
Topics:
Burns, Noah Z.
Baran, Phil S.
(Chemical Equation Presented) Not what it seemed: Careful reinvestigation of the classic Chichibabin pyridine synthesis has provided evidence against a spontaneous tetramerization pathway in the biosynthesis of the haouamine alkaloids. A simple enantioselective synthesis of haouamine A has illuminated its absolute configuration and points towards a phenylalanine-based biosynthesis.
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