REGIOSELECTIVE BOND CLEAVAGE AND COORDINATION EFFECTS IN THE REDUCTION OF SOME ACETALS WITH LITHIUM IN AMMONIA

DOI: 10.1016/S0040-4020(01)96640-2

Source and publish data:

Tetrahedron p. 2451 - 2464 (1985)

Update date:2022-08-02

Topics:

Authors:

Abell, A. D.

Massy-Westropp, R. A.

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Article abstract of DOI:10.1016/S0040-4020(01)96640-2

Some benzylic-type acetals possessing the 2,8-dioxabicyclo(3.2.1)octane ring system are cleaved in a regioselective manner when treated with lithium in ammonia.The results from various reductions implicate coordination of lithium as a significant factor involved in reduction mechanisms.

Full text of DOI:10.1016/S0040-4020(01)96640-2

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