
Tetrahedron p. 2451 - 2464 (1985)
Update date:2022-08-02
Topics:
Abell, A. D.
Massy-Westropp, R. A.
Some benzylic-type acetals possessing the 2,8-dioxabicyclo(3.2.1)octane ring system are cleaved in a regioselective manner when treated with lithium in ammonia.The results from various reductions implicate coordination of lithium as a significant factor involved in reduction mechanisms.
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