Journal of Organic Chemistry p. 2977 - 2981 (1986)
Update date:2022-07-30
Topics:
Tam, Wilson
Oxazolidinones are prepared from the palladium-catalyzed carbonylation of β-aminoethanols under mild conditions.With N-alkyl-substituted substrates, conditions for double carbon monoxide incorporation to give morpholinediones have been discovered.Cyclic carbonates can be prepared from the carbonylation of diols.The carbonylation of N-phenyl-1-aminopropane-2,3-diol can give either the carbonate or oxazolidinone as the major product depending on the reaction conditions.
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