TWO COMPLEMENTARY METHODS FOR INTRODUCTION OF gem-DIMETHYL GROUP IN HEXOPYRANOSIDE RING

DOI: 10.1246/cl.1985.965

Source and publish data:

Chemistry Letters p. 965 - 968 (1985)

Update date:2022-08-02

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Authors:

Hashimoto, Hironobu

Kawauchi, Nobuya

Yoshimura, Juji

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Article abstract of DOI:10.1246/cl.1985.965

Hexopyranosides having a gem-dimethyl group in the pyranose ring were synthesized by reductive cleavage of spiro-cyclopropane derivatives and by addition of methyl cuprates to methyl-branched enolone derivatives.

Full text of DOI:10.1246/cl.1985.965

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