Carbon-to-Nitrogen Rearrangement in N-(Arylsulfonoxy)amines as a Route to Azacyclic Compounds

DOI: 10.1021/jo00249a034

Source and publish data:

Journal of Organic Chemistry p. 3316 - 3321 (1988)

Update date:2022-08-05

Topics:

Authors:

Hoffman, Robert V.

Buntain, Gregory A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00249a034

A series of cyclic amines 1-10 was converted to the N-((p-nitrophenyl)sulfonoxy)amine derivatives with (p-nitrophenyl)sulfonyl peroxide.These compounds rearranged to ring-expanded cyclic imines in fair to good yields.Conversion of the amine to its hydroxy

Full text of DOI:10.1021/jo00249a034

Products guided by the article

Product name:3-Azabicyclo[3.2.1]octane,2-methyl-(6CI)

Cas No:101251-91-6

R&D Labs maybe for 101251-91-6

Tianjin Jiuri New Materials Co., Ltd.

Contact:+86-22-58889220

Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.
Zhengzhou Yuanli Biological Technology Co., Ltd.

Contact:+86-371-67897870/67897895

Address:No. 38, Qingyang Street, Zhengzhou, Henan, China
Advanced Biotech

Contact:+1-973-357-0577

Address:10 Taft Rd.
Tangshan Wisdom Trading Co.,Ltd

Contact:86 315 2222979

Address:No.41 BeiXinXi Road, Yangguang building 1-1102 , Tangshan, Hebei, China
Shanghai Sunwise Chemical Co., Ltd

website:http://www.sunwisechem.com

Contact:86-021-33883180

Address:Room 10E, Building G, Westlink Center, No. 2337 Gudai Road, Minhang District, Shanghai, China PC: 201100

Relevant to this article

Polystyrene-supported organocatalysts for α-selenenylation and Michael reactions: A common post-modification approach for catalytic differentiation

Doi:10.1016/j.catcom.2011.08.040
(2011)
Allenone-Mediated Racemization/Epimerization-Free Peptide Bond Formation and Its Application in Peptide Synthesis

Doi:10.1021/jacs.1c04614
(2021)
Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: Direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents

Doi:10.1002/chem.201101554
(2011)
Exploring sequence requirements for C₃/C₄ carboxylate recognition in the Pseudomonas aeruginosa cephalosporinase: Insights into plasticity of the AmpC β-lactamase

Doi:10.1002/pro.612
(2011)
2+ ion">An organoselenium-based highly sensitive and selective fluorescent "turn-On" probe for the Hg²⁺ ion

Doi:10.1021/ic2023902
(2012)
Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: High-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)

Doi:10.1002/chem.201102016
(2011)

Article Doi