Carbon-to-Nitrogen Rearrangement in N-(Arylsulfonoxy)amines as a Route to Azacyclic Compounds

DOI: 10.1021/jo00249a034

Source and publish data:

Journal of Organic Chemistry p. 3316 - 3321 (1988)

Update date:2022-08-05

Topics:

Authors:

Hoffman, Robert V.

Buntain, Gregory A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00249a034

A series of cyclic amines 1-10 was converted to the N-((p-nitrophenyl)sulfonoxy)amine derivatives with (p-nitrophenyl)sulfonyl peroxide.These compounds rearranged to ring-expanded cyclic imines in fair to good yields.Conversion of the amine to its hydroxy

Full text of DOI:10.1021/jo00249a034

Products guided by the article

Product name:3-Azabicyclo[3.2.1]octane,2-methyl-(6CI)

Cas No:101251-91-6

R&D Labs maybe for 101251-91-6

Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China
Taizhou YOJOY Chemical Co., Ltd.

Contact:13857143241

Address:Yangfu Industrial Park, Xianju, Zhejiang, P. R. China
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
Shanghai Sungo Technology Chemical Co., Ltd

Contact:0086-21-51385579

Address:Room2010, F/20, Tonghua Plaza, NO 345 Jinxiang Road, Jinqiao Export Processing Zone, Shanghai, 201206 P.R.CHINA
NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,

Relevant to this article

Polystyrene-supported organocatalysts for α-selenenylation and Michael reactions: A common post-modification approach for catalytic differentiation

Doi:10.1016/j.catcom.2011.08.040
(2011)
Allenone-Mediated Racemization/Epimerization-Free Peptide Bond Formation and Its Application in Peptide Synthesis

Doi:10.1021/jacs.1c04614
(2021)
Alkyne-aldehyde reductive C-C coupling through ruthenium-catalyzed transfer hydrogenation: Direct regio- and stereoselective carbonyl vinylation to form trisubstituted allylic alcohols in the absence of premetallated reagents

Doi:10.1002/chem.201101554
(2011)
Exploring sequence requirements for C₃/C₄ carboxylate recognition in the Pseudomonas aeruginosa cephalosporinase: Insights into plasticity of the AmpC β-lactamase

Doi:10.1002/pro.612
(2011)
2+ ion">An organoselenium-based highly sensitive and selective fluorescent "turn-On" probe for the Hg²⁺ ion

Doi:10.1021/ic2023902
(2012)
Skeletal alkylcarbonation (SAC) reactions as a simple design for cluster-carbon insertion and cross-coupling: High-yield access to substituted tricarbollides from 6,9-dicarba-arachno-decaborane(14)

Doi:10.1002/chem.201102016
(2011)

Article Doi