Carbon-to-Nitrogen Rearrangement in N-(Arylsulfonoxy)amines as a Route to Azacyclic Compounds

DOI: 10.1021/jo00249a034

Source and publish data:

Journal of Organic Chemistry p. 3316 - 3321 (1988)

Update date:2022-08-05

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Authors:

Hoffman, Robert V.

Buntain, Gregory A.

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Article abstract of DOI:10.1021/jo00249a034

A series of cyclic amines 1-10 was converted to the N-((p-nitrophenyl)sulfonoxy)amine derivatives with (p-nitrophenyl)sulfonyl peroxide.These compounds rearranged to ring-expanded cyclic imines in fair to good yields.Conversion of the amine to its hydroxy

Full text of DOI:10.1021/jo00249a034

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