Crystal and Molecular Structure of a Dioxo-molybdenum Phosphorus-substituted Alkylidene resulting from the First Observed Aryl Migration from Molybdenum to Carbon

DOI: 10.1039/c39850001151

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1151 - 1152 (1985)

Update date:2022-09-26

Topics:

Authors:

Arzoumanian, Henri

Baldy, Andre

Lai, Richard

Metzger, Jacques

Peh, Marie-Louise Nkeng

Pierrot, Marcel

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001151

The reaction of Mo(O)2(mesityl)2 with Bu3PCH2 yields (mesityl)(O)2Mo=C(mesityl)PBu3, the first example of a dioxo-metal phosphorus-substituted carbene resulting from a double α-hydrogen abstraction and aryl migration from molybdenum to carbon within the co-ordination sphere of the metal.

Full text of DOI:10.1039/c39850001151

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Mo(O)2(C₆H₂(CH₃)3)(CP(C₄H₉)3(C₆H₂(CH₃)3))

Cas No:101342-37-4

R&D Labs maybe for 101342-37-4

Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China
Kaiping Genuine Biochemical Pharmaceutical Co.,Ltd.

Contact:+86-750-2881198

Address:No.1, Xinke Road, Shatang Town, Kaiping, Guangdong Province, P.R.China
Ningbo Tide Imp. & Exp. Co., Ltd.

Contact:+86-571-8993 7933; +86-571-8993 6453

Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.

Contact:15967177856

Address:Genglou Industrial Development Area
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA

Relevant to this article

Intramolecular ring-opening reactions of 1-(2-methoxyphenyl)-6- oxabicyclo[3.2.0]heptanes: spirocyclic dihydrobenzofurans from fused bicyclic oxetanes

Doi:10.1055/s-2007-990921
(2008)
The efficient copper(I) (hexabenzyl)tren catalyst and dendritic analogues for green "click" reactions between azides and alkynes in organic solvent and in water: Positive dendritic effects and monometallic mechanism

Doi:10.1002/adsc.201100449
(2011)
Indole-2-amide based biochemical antagonist of Dishevelled PDZ domain interaction down-regulates Dishevelled-driven Tcf transcriptional activity

Doi:10.1016/j.bmcl.2007.12.039
(2008)
Doi:10.1021/ja01554a045
(1958)
Concise and Additive-Free Click Reactions between Amines and CF₃SO₃CF₃

Doi:10.1002/chem.201901865
(2019)
Assembly of π conjugated phosphole azahelicene derivatives into chiral coordination complexes: An experimental and theoretical study

Doi:10.1002/chem.200903234
(2010)

Article Doi