Crystal and Molecular Structure of a Dioxo-molybdenum Phosphorus-substituted Alkylidene resulting from the First Observed Aryl Migration from Molybdenum to Carbon

DOI: 10.1039/c39850001151

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1151 - 1152 (1985)

Update date:2022-09-26

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Authors:

Arzoumanian, Henri

Baldy, Andre

Lai, Richard

Metzger, Jacques

Peh, Marie-Louise Nkeng

Pierrot, Marcel

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Article abstract of DOI:10.1039/c39850001151

The reaction of Mo(O)2(mesityl)2 with Bu3PCH2 yields (mesityl)(O)2Mo=C(mesityl)PBu3, the first example of a dioxo-metal phosphorus-substituted carbene resulting from a double α-hydrogen abstraction and aryl migration from molybdenum to carbon within the co-ordination sphere of the metal.

Full text of DOI:10.1039/c39850001151

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