Syntheses of Organofunctional Siloxanes containing Metal-ligating Sidechains

DOI: 10.1039/DT9850002191

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2191 - 2194 (1985)

Update date:2022-09-26

Topics: Purification and characterization

Authors:

Brisdon, Brian J.

Watts, Andrew M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9850002191

A range of tri-, tetra-, and penta-siloxanes of general formula Me3SiOnSiMe3 (R=vinyl, n=1-3; R=an alkyl chain terminated by the potential metal-ligating entities CH=CH2, Ph, CN, cyclohexenyl, pyridine, and PPh2, n=1 or 2) have been synthesised from commercially avilable dichlorosilanes by one of three procedures.The products are air-stable oils with the exception of the pyridine- and phosphine-functionalised compounds which react vigorously with oxygen, and the spectroscopic properties of corresponding organofunctional siloxanes are very similar showing little dependence on n.

Full text of DOI:10.1039/DT9850002191

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:C₂₂H₃₇O₂PSi₃

Cas No:101667-55-4

R&D Labs maybe for 101667-55-4

Shanghai united Scientific Co.,Ltd.

Contact:+86-21-53535353

Address:28F No.900 huaihai Road Shanghai China
PharmOrgsyn

Contact:+86-21-38228826

Address:Room 505 Building 2, No 3377 Kangxin Highway, Shanghai, Republic China
Jiangxi Province Bethel Pharmaceutical Co., Ltd.

Contact:+86-795-259 3456 ，+86-15957688008 13566650571

Address:Huangjindui Chemical Park， Shanggao County ，Yichun city，Jiangxi Province
Phantom-pharma

Contact:

Address:
Shanghai FWD Chemicals ltd

website:http://www.fwdchem.com

Contact:86-21-54450828

Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai

Relevant to this article

Fluorous effects in amide-based receptors for anions

Doi:10.1021/jo9000788
(2009)
Doi:10.1021/ja01636a034
(1954)
Asymmetric Ni-catalyzed conjugate allylation of activated enones

Doi:10.1021/ja710922h
(2008)
Doi:10.1021/jo01067a050
(1961)
Synthesis and biological evaluation of novel 8-aminomethylated oroxylin A analogues as α-glucosidase inhibitors

Doi:10.1016/j.bmcl.2008.01.055
(2008)
beta-Cycloylpropionitriles; reduction to 2-cyclyl-delta2-pyrrolines and

Doi:10.1039/jr9480000186
(1948)

Article Doi