Organometallics p. 1591 - 1595 (2008)
Update date:2022-07-29
Topics:
Caldwell, Helen
Pregosin, Paul S.
The salts [Ru(Cp*)(CH3CN)(N,N)](PF6), 6 (N,N = bipyridine, 4,4′-dimethylbipyridine, and phenanthroline), react with allyl carbonates to afford new complexes that contain tethered ligands derived from deprotonation of one Cp* methyl group. The new Ru tetrametiryl Cp complexes contain a CH2-CHRCH=CH2 fragment (R = H or Ph), which coordinates to the metal via the double bond. The salts 6 isomerize the branched carbonate PhCH(OCO2But)CH=CH2 to the linear isomer.
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(2008)
