The Nickel Promoted 1,3-Migration of an sp2 Center: Ring Expansion of a Vinylcyclobutene

DOI: 10.1021/jo00361a031

Source and publish data:

Journal of Organic Chemistry p. 2098 - 2102 (1986)

Update date:2022-08-03

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Authors:

DiFrancesco, Dale

Pinhas, Allan R.

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Article abstract of DOI:10.1021/jo00361a031

The nickel tetracarbonyl promoted rearrangement if dimethyl 3-vinyl-1,2-dichlorocyclobutane-1,2-dicarboxylate (1) to dimethyl 1,4-cyclohexadiene-1,2-dicarboxylate (2) proceeds in two distinct steps involving dimethyl 3-vinylcyclobutene-1,2-dicarboxylate (

Full text of DOI:10.1021/jo00361a031

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