Conjugate additions of alkylchromium reagents mediated by chromium(III) chloride/manganese

DOI: 10.1016/S0040-4039(98)80021-X

Source and publish data:

Tetrahedron Letters p. 67 - 70 (1999)

Update date:2022-07-29

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Authors:

Auge, Jacques

Gil, Richard

Kalsey, Sophie

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Article abstract of DOI:10.1016/S0040-4039(98)80021-X

Benzyl and glycosylchromium reagents generated from the corresponding halides and the couple Cr(III)/Mn were added to activated alkenes to afford Michael adducts. The influence of a ligand around the chromium atom as well as the use of a catalytic amount of chromium chloride were investigated.

Full text of DOI:10.1016/S0040-4039(98)80021-X

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