Angewandte Chemie - International Edition p. 2035 - 2038 (2008)
Update date:2022-07-30
Topics:
Morita, Yasushi
Ueda, Akira
Nishida, Shinsuke
Fukui, Kozo
Ise, Tomoaki
Shiomi, Daisuke
Sato, Kazunobu
Takui, Takeji
Nakasuji, Kazuhiro
(Figure Presented) A well-rounded radical: A stable corannulene-based neutral radical with curved p conjugation was synthesized, and the crystal structure was determined. Unbalanced delocalized electronic spin on the three-dimensional p surface of the corannulene moiety (see spin-density distribution) demonstrates a sizable intermolecular exchange interaction and curved aromaticity.
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