Preparation of Three- and Four-co-ordinate Gold(I) Complexes; Crystal Structure of Bisgold(I) Bis(pentafluorophenyl)aurate(I)

DOI: 10.1039/DT9810000655

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 655 - 657 (1981)

Update date:2022-07-31

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Authors:

Uson, Rafael

Laguna, Antonio

Vicente, Jose

Garcia, Javier

Jones, Peter G.

Sheldrick, George M.

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Article abstract of DOI:10.1039/DT9810000655

The addition of 1,10-phenanthroline, o-phenylenebis(dimethylarsine), or triphenylstibine to pentafluorophenyl-(tetrahydrothiophen)gold(I) leads respectively to , , and , the pdma derivative being the first four-co-ordinate gold(I) complex whose structure has been fully determined by X-ray diffraction; space group P1, a=10.340(3), b=10.982(3), c=17.612(5) Angstroem, α=75.45(2), β=82.35(2), γ=87.23(2) deg, Z=2, R=0.043 for 5 558 unique observed reflections.The Au-As bond lengths range from 2.462 to 2.478 Angstroem.The two independent anions are exactly linear at Au.

Full text of DOI:10.1039/DT9810000655

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