Journal of the Chemical Society, Dalton Transactions p. 655 - 657 (1981)
Update date:2022-07-31
Topics:
Uson, Rafael
Laguna, Antonio
Vicente, Jose
Garcia, Javier
Jones, Peter G.
Sheldrick, George M.
The addition of 1,10-phenanthroline, o-phenylenebis(dimethylarsine), or triphenylstibine to pentafluorophenyl-(tetrahydrothiophen)gold(I) leads respectively to a=10.340(3), b=10.982(3), c=17.612(5) Angstroem, α=75.45(2), β=82.35(2), γ=87.23(2) deg, Z=2, R=0.043 for 5 558 unique observed reflections.The Au-As bond lengths range from 2.462 to 2.478 Angstroem.The two independent anions are exactly linear at Au.
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