REGIO- AND DIASTEREOSELECTIVE ALDOL REACTION OF 1,2-CYCLOHEXANEDIONE DIANIONS WITH ALDEHYDES

DOI: 10.1246/cl.1985.1471

Source and publish data:

Chemistry Letters p. 1471 - 1474 (1985)

Update date:2022-07-30

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Authors:

Utaka, Masanori

Hojo, Makoto

Takeda, Akira

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Article abstract of DOI:10.1246/cl.1985.1471

The aldol reaction of 1,2-cyclohexanedione dianions with various aldehydes afforded threo and erythro aldols in a ratio of 82:18->99:1 in 60-85percent yields.A diastereoselective synthesis of racemic corynomycolic acid was achieved by using the reaction.

Full text of DOI:10.1246/cl.1985.1471

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