Reactions of the Multiply Bonded Dirhenium Complexes n+ (X=Cl or Br, L-L=Ph2PCH2CH2PPh2 or Ph2PCH2CH2AsPh2; n=0 or 1) with Isocyanides and Nitriles. Reaction without Metal-Metal Bond Disruption

DOI: 10.1039/DT9860000055

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Journal of the Chemical Society, Dalton Transactions p. 55 - 60 (1986)

Update date:2022-08-02

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Authors:

Anderson, Lori Beth

Tetrick, Stephen M.

Walton, Richard A.

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Article abstract of DOI:10.1039/DT9860000055

The reaction of paramagnetic PF6 with RNC (X=Cl or Br, L-L=Ph2PCH2CH2PPh2 or Ph2PCH2CH2AsPh2, R=Prⁱ or Bu^t) proceeds with reduction of the dirhenium core to yield the diamagnetic complexes PF6.These iso

Full text of DOI:10.1039/DT9860000055

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